High-accuracy room temperature planar absolute radiometer based on vertically aligned carbon nanotubes.

We have developed a planar absolute radiometer for room temperature (PARRoT) that will replace the legacy C-series calorimeter as the free-space continuous-wave laser power detector standard at the National Institute of Standards and Technology (NIST). This instrument will lower the combined relative expanded measurement uncertainty (k = 2) from 0.84 % to 0.13 %. PARRoT's performance was validated by comparing its response against a transfer standard silicon trap detector traceable to NIST's primary standard laser optimized cryogenic radiometer (LOCR) and against the C-series calorimeter. On average, these comparisons agreed to better than 0.008 % and 0.05 %, respectively.

Optical phase contrast imaging for absolute, quantitative measurements of ultrasonic fields with frequencies up to 20 MHz.

The technique of phase contrast imaging, combined with tomographic reconstructions, can rapidly measure ultrasonic fields propagating in water, including ultrasonic fields with complex wavefront shapes, which are difficult to characterize with standard hydrophone measurements. Furthermore, the technique can measure the absolute pressure amplitudes of ultrasonic fields without requiring a pressure calibration. Absolute pressure measurements have been previously demonstrated using optical imaging methods for ultrasonic frequencies below 2.5 MHz. The present work demonstrates that phase contrast imaging can accurately measure ultrasonic fields with frequencies up to 20 MHz and pressure amplitudes near 10 kPa. Accurate measurements at high ultrasonic frequencies are performed by tailoring the measurement conditions to limit optical diffraction as guided by a simple dimensionless parameter. In some situations, differences between high frequency measurements made with the phase contrast method and a calibrated hydrophone become apparent, and the reasons for these differences are discussed. Extending optical imaging measurements to high ultrasonic frequencies could facilitate quantitative applications of ultrasound measurements in nondestructive testing and medical therapeutics and diagnostics such as photoacoustic imaging.

Dual-comb photoacoustic spectroscopy.

Spectrally resolved photoacoustic imaging is promising for label-free imaging in optically scattering materials. However, this technique often requires acquisition of a separate image at each wavelength of interest. This reduces imaging speeds and causes errors if the sample changes in time between images acquired at different wavelengths. We demonstrate a solution to this problem by using dual-comb spectroscopy for photoacoustic measurements. This approach enables a photoacoustic measurement at thousands of wavelengths simultaneously. In this technique, two optical-frequency combs are interfered on a sample and the resulting pressure wave is measured with an ultrasound transducer. This acoustic signal is processed in the frequency-domain to obtain an optical absorption spectrum. For a proof-of-concept demonstration, we measure photoacoustic signals from polymer films. The absorption spectra obtained from these measurements agree with those measured using a spectrophotometer. Improving the signal-to-noise ratio of the dual-comb photoacoustic spectrometer could enable high-speed spectrally resolved photoacoustic imaging.

High-resolution, high-contrast mid-infrared imaging of fresh biological samples with ultraviolet-localized photoacoustic microscopy.

Mid-infrared (MIR) microscopy provides rich chemical and structural information about biological samples, without staining. Conventionally, the long MIR wavelength severely limits the lateral resolution owing to optical diffraction; moreover, the strong MIR absorption of water ubiquitous in fresh biological samples results in high background and low contrast. To overcome these limitations, we propose a method that employs photoacoustic detection highly localized with a pulsed ultraviolet (UV) laser on the basis of the Grüneisen relaxation effect. For cultured cells, our method achieves water-background suppressed MIR imaging of lipids and proteins at UV resolution, at least an order of magnitude finer than the MIR diffraction limits. Label-free histology using this method is also demonstrated in thick brain slices. Our approach provides convenient high-resolution and high-contrast MIR imaging, which can benefit diagnosis of fresh biological samples.

Spectral, spatial, and survivability evaluation of a flash-dried plasma-etched nanotube spray coating.

We demonstrate improved manufacturability of spectrally flat detectors for visible to mid-infrared wavelengths by characterizing a carbon nanotube spray coating compatible with lithium tantalate and other thermal sensors. Compared against previous spray coatings, it demonstrated the highest responsivity yet attained due to both higher absorptivity and thermal diffusivity, while also being matured to a commercially available product. It demonstrated spectral nonuniformity from 300 nm to 12 µm less than 1% with uncertainty (k=2) under 0.4%. The spatial nonuniformity of the assembled sensor was less than 0.5% over the central half (4 mm) of the absorber. As with previous developments employing isotropic carbon nanotube coatings, the absorber surface was sufficiently robust to withstand cleaning by compressed air blast and survived repeated vacuum cycling without measurable impact upon responsivity.