Effect of torrefaction on fuel properties of biopellets.

The study aimed to determine the effects of torrefaction on the fuel properties of pellets. Therefore, firstly, torrefaction parameters of rose (Rosa Damascena Mill.) oil distillation solid waste and red pine sawdust were determined through the torrefaction optimization process in terms of temperature and holding time. Then, using the selected torrefaction parameters, 14 different raw and torrefied pellets containing RP, PS, and Turkish Elbistan Lignite were prepared in different weight ratios. Finally, the fuel properties of the prepared raw and torrefied pellets, namely dimensions, proximate analyses, higher heating values, tensile strength, durability, abrasive resistance, and water uptake resistances, were investigated. The findings demonstrated that the higher heating values and carbon content of raw biomass samples increased while their volatile matter content decreased. The use of lignite at high concentrations led to an increase in ash content and a decrease in the strength and durability of pellets, which should be emphasized. In addition, red pine sawdust was used in place of solid waste from rose oil distillation solid waste to produce pellets with greater strength. All pellet mixtures with torrefaction had higher heating values and energy densities despite the fact that their mass and energy efficiency had decreased. It was determined that torrefaction increased the pellets' resistance to absorbing water and gave them a more hydrophobic structure. Thus, it was determined that torrefaction could enhance the crucial fuel parameters of the biomass samples.

Phthalate ester levels in agricultural soils of greenhouses, their potential sources, the role of plastic cover material, and dietary exposure calculated from modeled concentrations in tomato.

Soil samples collected from 50 greenhouses (GHs) cultivated with tomatoes (plastic-covered:24, glass-covered:26), 5 open-area tomato growing farmlands, and 5 non-agricultural areas were analyzed in summer and winter seasons for 13 PAEs. The total concentrations (Σ13PAEs) in the GHs ranged from 212 to 2484 ng/g, wheeas the concentrations in open-area farm soils were between 240 and 1248 ng/g. Σ13PAE in non-agricultural areas was lower (35.0 - 585 ng/g). PAE exposure through the ingestion of tomatoes cultivated in GH soils and associated risks were estimated with Monte Carlo simulations after calculating the PAE concentrations in tomatoes using a partition-limited model. DEHP was estimated to have the highest concentrations in the tomatoes grown in both types of GHs. The mean carcinogenic risk caused by DEHP for tomato grown in plastic-covered GHs, glass-covered GHs, and open-area soils were 2.4 × 10-5, 1.7 × 10-5 and 1.1 × 10-5, respectively. Based on Positive Matrix Factorization results, plastic material usage in GHs (including plastic cover material source for plastic-GHs) was found to be the highest contributing source in both types of GHs. Microplastic analysis indicated that the ropes and irrigation pipes inside the GHs are important sources of PAE pollution. Pesticide application is the second highest contributing source.

PCDD/Fs, PAHs and HCl emissions from co-combustion of lignite and chicken manure in a circulating fluidized bed boiler with compact refractory casting.

Chicken manure (CM) should be used in energy production due to its high production potential for the waste-to-energy approach. Co-combustion of CM with lignites may be a good practice in terms of reducing its environmental impact and the need for fossil fuels. However, the level of organic pollutants originated from CM combustion is not clear. This study investigated the potential of CM to be combusted in a circulating fluidized bed boiler (CFBB) with a local lignite. Combustion and co-combustion tests of CM and Kale Lignite (L) were performed in the CFBB to measure PCDD/Fs, PAHs and HCl emissions. CM burned in the upper parts of the boiler due to its high volatile matter content and low density compared to coal. This caused the bed temperature to decrease with the increase in the amount of CM in the fuel mixture. It was also observed that the combustion efficiency increased as the share of CM in the fuel mixture increased. Total PCDD/F emissions increased with CM share in the fuel mixture. However, all are less than emission limit value (100 pg I-TEQ/m3). Co-combustion of CM with lignite at different ratios did not have a significant effect on HCl emissions. PAH emissions were found to increase with the increase of the CM share when the CM share was more than 50% by weight.

Evaluation of levels and sources of microplastics and phthalic acid esters and their relationships in the atmosphere of highly industrialized and urbanized Gebze, Türkiye.

The presence of microplastics (MPs) in the atmosphere and their relationship with other pollutants have been gaining attention due to both their ubiquity and threatening human health. As well phthalic acid esters (PAEs) regarding as plasticizers for being added in plastic materials are key role for plastic pollution. In this study, the concentrations and sources of airborne MPs together with major PAEs and their relationships were investigated for four seasons. MP particles <20 µm, constituting the majority of the samples, were successfully revealed by NR fluorescent analysis. As a result of the µATR-FTIR analyzes, it was seen that besides different polymer derivatives, dye-pigment types, some minerals and compounds, and abundant semi-synthetic fibers and natural fibers were also present. MPs concentration were found in the range of 7207-21,042 MP/m3 in summer, 7245-32,950 MP/m3 in autumn, 4035-58,270 MP/m3 in winter and 7275-37,094 MP/m3 in spring. For the same period, the concentrations of PAEs ranged from 9.24 to 115.21 ng/m3 with an average value of 38.08 ± 7.92 ng/m3. PMF was also applied and four factors were extracted. Factor 1, accounts 52.26 % and 23.27 % of the total PAEs and MPs variances, was attributed to PVC sources. Factor 2, explaining 64.98 % of the total MPs variance had the highest loading of MPs and moderate loadings of relatively low molecular weight of PAEs, was attributed to plastics and personal care products. Factor 3, explaining the 28.31 % of the total PAEs variance was laden with BBP, DnBP, DiBP and DEP and was attributed to various plastic input during the sampling campaign coming from the industrial activities. The last factor accounts for 11.65 % of the total PAEs variance and was dominated by DMEP and it was linked to a source of the activities performed in the laboratories of the university.

Investigation on thermal degradation kinetics and mechanisms of chicken manure, lignite, and their blends by TGA.

In this study, thermogravimetric analysis (TGA) was performed under the air environment for four different heating rates (10, 20, 30, and 40 °C min-1) in order to find out thermal degradation and mechanisms of the chicken manure, a Turkish lignite, and their blends (25 lignite + 75 manure, 50 lignite + 50 manure, and 75 lignite + 25 manure). To calculate thermal kinetics and responsible solid-state mechanisms of the samples, the Flynn-Wall-Ozawa and Coats-Redfern methods were applied. Significant differences between Turkish lignite and chicken manure samples were observed in terms of thermal kinetics and mechanisms. D1 and D4 mechanisms were found to be the responsible mechanisms for the main oxidation region of the lignite and chicken manure/blends, respectively. A similar decreasing trend for the calculated activation energies and pre-exponential constants was observed with increasing biomass content in the manure blends from 25 to 75% by both Flynn-Wall-Ozawa and Coats-Redfern methods. Furthermore, biomass content has an effect on the mechanisms of chicken manure blends during the combustion. D3 was found to be the responsible solid-state mechanism for the third regions (pre-combustion of the manure) of the chicken manure samples. However, D1 and D2 mechanisms were found to be responsible mechanisms for the blends.

Polybrominated diphenyl ethers (PBDEs) pollution in soil of a highly industrialized region (Dilovasi) in Turkey: concentrations, spatial and temporal variations and possible sources.

In this study, polybrominated diphenyl ethers (PBDEs) levels in soil were studied for a whole year in highly industrialized region of Turkey (Dilovasi) at 23 sampling sites. Σ8PBDE concentrations were between 0.15 and 286 µg kg-1 and the overall average concentration was 14.45 ± 25.07 µg kg-1 (average ± SD). BDE-209 was the most abundant compound. PBDEs concentrations decreased spatially as follows: industrial/urban > urban > suburban > rural. However, there was not any significant seasonal trend except for some industrial/urban sites. In the region, calm weather conditions prevailed during the sampling periods, enhancing the impact of the industrial emissions on nearby soil concentrations by atmospheric deposition without being diluted by winds. All congeners had significant but weak correlations with soil organic matter content indicating the impact of nearby sources rather than soil properties on soil PBDEs concentrations at the sampling sites. Positive matrix factorization method was also used for the apportionment of the PBDEs sources in Dilovasi soil. Industrial activities (i.e., iron-steel production, metallurgical processes, and recycling of plastics), traffic, and residential areas were found to be the primary sources of the measured PBDEs in the soil.

Spatio-temporal variations of atmospheric and soil polybrominated diphenyl ethers (PBDEs) in highly industrialized region of Dilovasi.

Polybrominated diphenyl ethers (PBDEs) were investigated in ambient air of a highly industrialized region at 23 different sampling sites for 12 months. Total concentrations of 8 PBDE congeners (Σ8PBDE) were found to be between 5.73 and 520 pg m-3 (94.7 ±â€¯78.9; average ±â€¯SD) and BDE-209 was the predominant congener, followed by BDE-47 and/or BDE-99. Their contributions to Σ8PBDE were 71 ±â€¯13, 9 ±â€¯4% and 8 ±â€¯4%; respectively. Compared to previous studies around the world, high concentrations detected in Dilovasi demonstrated the severity of atmospheric PBDE pollution in the area. For all sampling sites, average PBDE concentration obtained in summer (118.5 ±â€¯98.7 pg m-3) was higher than one found in winter period (79.7 ±â€¯59.1 pg m-3) and this seasonal difference was more obvious in industrial/urban sites (p < 0.05), probably due to enhanced volatilization from ongoing PBDE sources such as waste incineration and iron-steel plants. The soil-air exchange tendencies of PBDEs did not show substantial differences between the sampling periods with small variations for each congener. All congeners either tend to deposit to soil or to be within the equilibrium range for all seasons. This reflects the impact of local ongoing sources rather than temperature on the direction of soil-air exchange of PBDEs in this region. Specific congener ratios such as BDE-47/-99 and -99/-100 confirmed the impact of local sources rather than long-range transport on PBDE congeners in the study area. According to the Positive Matrix Factorization (PMF) results, the BDE-209 content of the first factor was found to be 91.7% and this factor was attributed to the deca-BDE technical formulations. The second factor was highly rich with both BDE-183 (%61) and BDE-28 (%52) and identified as octa-BDE technical products. The last factor was highly loaded with BDE-99, BDE-47, BDE-100, BDE-154 and BDE-153 and has been determined as the penta-BDE commercial formulations.

Source apportionment and carcinogenic risk assessment of passive air sampler-derived PAHs and PCBs in a heavily industrialized region.

Cancer has become the primary reason of deaths in Dilovasi probably due to its location with unique topography under the influence of heavy industrialization and traffic. In this study, possible sources and carcinogenic health risks of PAHs and PCBs were investigated in Dilovasi region by Positive Matrix Factorization (PMF) and the USEPA approach, respectively. PAHs and PCBs were measured monthly for a whole year at 23 sampling sites using PUF disk passive samplers. Average ambient air concentrations were found as 285±431ng/m3 and 4152±6072pg/m3, for Σ15PAH and Σ41PCB, respectively. PAH concentrations increased with decreasing temperature especially at urban sites, indicating the impact of residential heating in addition to industrial activities and traffic. On the other hand, PCB concentrations mostly increased with temperature probably due to enhanced volatilization from their sources. Possible sources of PAHs were found as emissions of diesel and gasoline vehicles, biomass and coal combustion, iron and steel industry, and unburned petroleum/petroleum products, whereas iron-steel production, coal and biomass burning, technical PCB mixtures, and industrial emissions were identified for PCBs. The mean carcinogenic risk associated with inhalation exposure to PAHs and PCBs were estimated to be >10-6 and >10-5, respectively, at all sampling points, while the 95th percentile was >10-5 at 15 of 23 and >10-4 at 8 of 23 sampling locations, respectively. Probabilistic assessment showed, especially for PCBs, that a majority of Dilovasi population face significant health risks. The higher risks due to PCBs further indicated that PCBs and possibly other pollutants originating from the same sources such as PBDEs and PCNs may be an important issue for the region.

Atmospheric concentrations, distributions and air-soil exchange tendencies of PAHs and PCBs in a heavily industrialized area in Kocaeli, Turkey.

Dilovasi is one of the heavily industrialized areas in Turkey with serious environmental problems. In this study, the atmospheric concentration of PAHs and PCBs were measured for a whole year at 23 sites. The average ambient air Σ15PAH and Σ41PCB concentrations were found as 285 ± 431 ng m-3 and 4152 ± 6072 pg m-3, respectively. PAH concentrations increased with decreasing temperature especially in urban areas, indicating the impact of residential heating. However, PCB concentrations mostly increased with temperature probably due to enhanced volatilization from their sources. The gradient obtained for PCBs, rural < suburban < urban < industrial/urban, is more clear than those obtained for PAHs. The average Σ15PAH and Σ41PCB soil concentrations were found as 992 ± 1323 and 18.8 ± 32.0 µg kg-1, respectively. PCB soil concentrations did not show significant temporal variations while PAH concentrations were variable especially for urban areas. The volatilization tendencies of low and medium molecular weight PAHs from soil to air were higher in industrial-urban areas than rural sites, showing that soil was a secondary source for PAHs. Fugacity ratios of PCBs were mostly <1.0 for the whole sampling period. Although the source/sink tendency of soil for some PCBs depends on their volatility, considering the whole data, PCBs were generally deposited to soil.

PAHs and PCBs in an Eastern Mediterranean megacity, Istanbul: Their spatial and temporal distributions, air-soil exchange and toxicological effects.

Istanbul, one of the mega cities in the world located between Asia and Europe, has suffered from severe air pollution problems due to rapid population growth, traffic and industry. Atmospheric levels of PAHs and PCBs were investigated in Istanbul at 22 sampling sites during four different sampling periods using PUF disk passive air samplers and spatial and temporal variations of these chemicals were determined. Soil samples were also taken at the air sampling sites. At all sites, the average ambient air Σ15PAH and Σ41PCB concentrations were found as 85.6 ± 68.3 ng m-3 and 246 ± 122 pg m-3, respectively. Phenanthrene and anthracene were the predominant PAHs and low molecular weight congeners dominated the PCBs. The PAH concentrations were higher especially at urban sites close to highways. However, the PCBs showed moderately uniform spatial variations. Except four sites, the PAH concentrations were increased with decreasing temperatures during the sampling period, indicating the contributions of combustion sources for residential heating, while PCB concentrations were mostly increased with the temperature, probably due to enhanced volatilization at higher temperatures from their sources. The results of the Factor Analysis represented the impact of traffic, petroleum, coal/biomass and natural gas combustion and medical waste incineration plants on ambient air concentrations. A similar spatial distribution trend was observed in the soil samples. Fugacity ratio results indicated that the source/sink tendency of soil for PAHs and PCBs depends on their volatility and temperature; soil generally acts as a source for lighter PAHs and PCBs particularly in higher temperatures while atmospheric deposition is a main source for higher molecular weight compounds in local soils. Toxicological effect studies also revealed the severity of air and soil pollution especially in terms of PAHs in Istanbul.

Improvement of uptake rate equations depending on meteorological conditions for 25 volatile organic compounds.

Stainless steel passive (diffusive) sampling tubes manufactured by Gradko International Ltd. (UK) were filled with Chromosorb 106 (Supelco) and evaluated to determine the uptake rates of 31 VOCs over six months under different meteorological conditions in a suburban area of Ankara, Turkey. The URs have been calculated, and dependence on such meteorological parameters as temperature, relative humidity and wind speed has been established for the 31 VOCs. The URs of the 31 VOCs measured in this study showed a statistically significant decreasing trend with rising temperature; and weaker, but again statistically significant, increasing trends with increasing relative humidity and wind speed. This study has demonstrated that the URs of VOCs are affected by meteorological parameters, and this dependence should be taken into account when attempting to generate reliable data through passive sampling. A multiple linear regression equation in which temperature, relative humidity and wind speed were used as independent variables was generated for 25 of the 31 tested VOCs.