Structure and properties of starch - BaSO4 composite obtained using mechanical activation techniques.

The aim of this study is to obtain and characterize starch films structurally modified by in situ precipitation of BaSO4 combined with mechanical activation of casting dispersion in a rotor-stator device. By the rheological method, it was found that the modification causes a decrease in the ability of casting dispersions to structure over time. Composite films with a filler content of 0 %-15 % (w/w) were characterized using optical and SEM microscopy, FT-IR spectroscopy, and tensile and moisture resistance testing data. The maximum increase in strength (by 70 %) and elongation at break (by 870 %) is achieved with a filler content of 5 % and 15 %, respectively. An increase in the filler content to 5 % causes an increase in starch recrystallization rate, but at concentrations above 5 % of BaSO4, it inhibits retrogradation. The films obtained by mechanical activation with optimized parameters were uniformly translucent, had lower water vapor permeability than films made from starch alone, had high flexibility, and did not warp or shrink. The developed high-performance, environmentally friendly method can be recommended for the large-scale production of starch-based composite materials.

Effect of mechanical activation on starch crosslinking with citric acid.

The aim of this research was to investigate the influence of mechanical activation in a rotor-stator device on starch crosslinking with citric acid and the properties of the films obtained by the casting method. Two methods of preparation of the casting hydrogels were used: involving the introduction of chemical reagents before and after the mechanical activation. The films from the initial and mechanically activated hydrogels were characterized using optical and AFM microscopy, X-ray diffraction and FTIR-spectroscopy. The di-esterification degree, opacity, tensile properties and moisture resistance of the films were also studied. Mechanical activation of the starch hydrogels made it possible to make the films smoother and more transparent and to increase their tensile strength and moisture resistance. Pre-activation of the hydrogels without reagents showed better film performance than activation in the presence of citric acid.

Gelation in solutions of low deacetylated chitosan initiated by high shear stresses.

A new process of mechanically initiated formation of chitosan physical hydrogels in aqueous solution, without a cross-linking agent, was studied. Physical hydrogel is formed by mechanical activation of solutions of chitosan with a low deacetylation degree (58%) in situ in a rotor-stator device for 10 s. The formation of 3D gel structure has been proven by rotational viscometry and dynamic rheometry methods. Gelation is caused by the action of high shear stresses initiating the formation of hydrophobic associates from residual chitinous blocks. In comparison with the films from untreated chitosan, the films obtained by drying hydrogel have a lower degree of crystallinity and a higher sorption capacity towards water vapor and Cu2+ ions, as well as the ability to retain up to 5000% of water during re-swelling without destruction.