Poplar tree (Populus balsamifera L.) as indicator of mercury emission from a point source.

The article provides original data on the ecological and geochemical characteristics of the distribution of Hg in the leaves and annual rings of balsam poplar (P. balsamifera L.) in the zone of influence of lithium production (Novosibirsk). In 2017 high Hg concentration (1300 ng/g) in the poplar leaves was recorded in the northeastern part of the city near the industrial facility of the lithium plant. The investigation showed a clear trend of increased Hg accumulation in the poplar leaves during the growing season. The maximum average Hg content was detected in the leaf litter in 2006 (1153-2425 ng/g). However, the average Hg content in the soil is 294 ng/g, which is significantly lower than the threshold limit value (2100 ng/g). Studies of changes in the content of Hg with the height of the crown of the tree revealed an increase in the upwind side of the emission source, the concentration of Hg in the leaves is on average 1.5 times higher than on the side of the "wind shadow". Hg in poplar leaves, leaf litter, and soils is mainly found in free and physically bonded forms - the most mobile, prone to increased migration, transformation and methylation under environmental conditions. According to the Hg content in the poplar cores, an increase in the Hg input near the source was established with the beginning of Li production - in the period 1967-1985 years (441 ng/g) with a subsequent decrease to 6 ng/g in 2000-2017.

Multicaloric effect in a multiferroic composite of Gd5(Si,Ge)4 microparticles embedded into a ferroelectric PVDF matrix.

The coupling between electric, magnetic and elastic features in multiferroic materials is an emerging field in materials science, with important applications on alternative solid-state cooling technologies, energy harvesting and sensors/actuators. In this direction, we developed a thorough investigation of a multiferroic composite, comprising magnetocaloric/magnetostrictive Gd[Formula: see text]Si[Formula: see text]Ge[Formula: see text] microparticles blended into a piezo- and pyroelectric poly(vinylidene) fluoride (PVDF) matrix. Using a simple solvent casting technique, the formation and stabilization of PVDF electroactive phases are improved when the filler content increases from 2 to 12 weight fraction (wt.%). This effect greatly contributes to the magnetoelectric (ME) coupling, with the ME coefficient [Formula: see text] increasing from 0.3 V/cm.Oe to 2.2 V/cm.Oe, by increasing the amount of magnetic material. In addition, magnetic measurements revealed that the ME-coupling has influenced the magnetocaloric effect via a contribution from the electroactive polymer and hence leading to a multicaloric effect. These results contribute to the development of multifunctional systems for novel technologies.

Induction of antibodies to morphine during chronic morphine treatment in rodents and opiate addicts.

The phenomenon of induction of antibodies to morphine in morphine-treated animals and opiate addicts was shown by means of ELISA. The reaction of the immune system to injections of a morphine solution had the characteristics of a primary immune response. Opiate addicts differed from normal controls in the level of antibodies to morphine of IgM class. Elevated levels of such antibodies could be detected in about 70-80% of addicts with regular longterm opiate use when the time since the last drug intake did not exceed 60 days. Antibodies to morphine could serve as indicators of chronic opiate use especially in periods long after the last drug intake.