1.
Synlett
; 29(2): 181-184, 2018 Jan.
Article
in English
| MEDLINE
| ID: mdl-31068740
ABSTRACT
Metalloamination-alkylation of representative N,N-dimethyl-hydrazinoalkenes has been shown to be effectively catalyzed by CuBr-SMe2, CuCN, and Cul. The current method obviates the use of stoichiometric CuCN(LiCl)2 as a promoter for the electrophilic functionalization event.
2.
J Org Chem
; 81(21): 10160-10164, 2016 11 04.
Article
in English
| MEDLINE
| ID: mdl-27454875
ABSTRACT
Diethylzinc-mediated metalloamination/cyclization of unsaturated N,N-dimethylhydrazines has been extended to the use of 1,2-disubstituted alkenes as N-Zn migratory insertion acceptors. Representative 2-arylethenes and vinylcyclopropanes readily serve as reaction participants in metalloamination/cyclization-allylation cascades.