Facile synthesis of chlorella-derived autogenous N-doped porous biochar for adsorption on tetracycline.

In this study, an autogenous N-doped biochar derived from Chlorella (CVAC) was prepared with NaOH as activator at 800 °C. The surface structural properties of CVAC and the adsorption performance of CVAC on tetracycline (TC) under different adsorption variables were analyzed and investigated using different characterization methods. The results showed that the specific surface area of CVAC was 491.16 m2 g-1 and the adsorption process was in accordance with Freundlich model and pseudo-second-order kinetic model. The maximum adsorption capacity of TC was 310.696 mg g-1 at pH 9 and 50 °C, and it was mainly physical adsorption. Furthermore, the cyclic adsorption-desorption behavior of CVAC using ethanol as eluent was evaluated and the feasibility of its long-term application was explored. CVAC also showed good cyclic performance. The variation of ΔG° and ΔH° confirmed that the adsorption of TC by CVAC was a spontaneous heat absorption process.

Highly efficient adsorption of Bisphenol A using NaHCO3/CO2 activated carbon composite derived from shrimp shell@cellulose.

In this study, the efficiency of activated carbon (AC) synthesized from the shrimp shell plus cellulose (SS@C) was optimized toward Bisphenol A (BPA) adsorption. Low-cost, renewable, and non-toxic shrimp shells mixed with cellulose were carbonized, followed by activation via CO2 and NaHCO3 to produce SS@C-AC. The results revealed that SS@C-AC samples were a porous composite with mesoporous structures comprising a relatively high specific surface area (935.20 m2/g) with a mean pore size of around 3.8 nm and mesoporous volume of 1.83E-02 cm3/g. The influences of initial concentrations, pH values, and adsorption on BPA were investigated systematically. Isotherm model and kinetics study of the adsorption of BPA on SS@C-AC exhibited that the obtained data were in agreement with the Langmuir adsorption isotherm model while there is no difference between PFO and PSO kinetic results for BPA concentrations in the range 25-100 mg/L. The impregnation ratio of 1.5 NaHCO3 and an activation time of 90 min at 800°C were the optimum conditions under which BPA removal of 81.78% was obtained.

Adsorption modeling, thermodynamics, and DFT simulation of tetracycline onto mesoporous and high-surface-area NaOH-activated macroalgae carbon.

Activated carbon (ENAC) was prepared by NaOH activation, using macroalgae (Enteromorpha clathrate) as raw material. The prepared activated carbon has a large surface area (1238.491 m2 g-1) and its total pore volume and average pore size are 0.6823 cm3g-1 and 2.2038 nm, respectively. The ENAC was characterized by SEM, FTIR, BET and XPS. The effects of contact time (0-960 min), initial tetracycline (TC) concentration (50-500 mg L-1), temperature (30-50 °C) and initial pH (2-11) on TC adsorption were evaluated. The adsorption isotherm and adsorption kinetics were discussed. Results showed that the adsorption isotherm was the Langmuir model, and the adsorption process can be described by the pseudo-second-order model. The N2 adsorption-desorption isotherm was type IV, indicating that the activated carbon had mesoporous structure. Thermodynamic analysis showed that the adsorption process was endothermic and spontaneous. The maximum adsorption capacity of TC was 381.584 mg g-1. Density functional theory (DFT) was used to simulate and analyze the adsorption process, and the influence of different types of N on the adsorption was expounded. The results showed that there are electrostatic interactions, π-π interactions and hydrogen bonding between the adsorbent and TC. These results indicated that the prepared ENAC had a great application prospect in the removal of antibiotics from aqueous solution.