Dispersion modeling of particulate matter containing hexavalent chromium during high winds in southern Iraq.

The aim of this paper is to describe a scientific methodology (i.e., the combination of different well-established modeling techniques) and its application to a real case scenario of contaminated dust emissions in high winds. This scenario addresses potential air pollution problems at the water treatment plant (WTP) at Qarmat-Ali, Basra, Iraq, during 2003. Workplace practices at the WTP before 2003 resulted in sodium dichromate contamination in the area. Looting at the site in early 2003 also contributed to this contamination. Individuals who were assigned to provide security at the site in 2003 have claimed adverse health effects caused by exposure to dust containing hexavalent chromium [Cr(VI)]. This report presents our modeling study with respect to these claims in relation to (1) amount of Cr(VI) present in the soil, (2) wind erosion episodes, and (3) possible long-term (e.g., annual average) Cr(VI) concentrations inhaled by different people while at the site. Our modeling approach included (1) the analysis of Cr(VI) soil measurements to assess the degree of contamination in different areas of the plant at different times; (2) the use of DUSTRAN model equations to calculate the emission rate of particulate matter (PM) less than 10 µm in diameter (PM10) during high-wind episodes; (3) the use of the U.S. Environmental Protection Agency (EPA) AERMOD modeling system to estimate Cr(VI) concentrations at the site; and (4) the calculation of modeling results in the form of both contour lines of average Cr(VI) concentrations at the site, and specific concentration values for selected individuals, based upon their recollection of their visits to the site.

Air pollution from a large steel factory: polycyclic aromatic hydrocarbon emissions from coke-oven batteries.

A systematic investigation of solid and gaseous atmospheric emissions from some coke-oven batteries of one of Europe's largest integrated steel factory (Taranto, Italy) has been carried out. In air monitoring samples, polycyclic aromatic hydrocarbons (PAHs) were consistently detected at concentrations largely exceeding threshold limit values. By means of PAHs speciation profile and benzo(a)pyrene (BaP) equivalent dispersion modeling from diffuse sources, the study indicated that serious health risks exist not only in working areas, but also in a densely populated residential district near the factory.