Stimuli-Responsive Langmuir Films Composed of Nanoparticles Decorated with Poly(N-isopropyl acrylamide) (PNIPAM) at the Air/Water Interface.

The nanotechnology shift from static toward stimuli-responsive systems is gaining momentum. We study adaptive and responsive Langmuir films at the air/water interface to facilitate the creation of two-dimensional (2D) complex systems. We verify the possibility of controlling the assembly of relatively large entities, i.e., nanoparticles with diameter around 90 nm, by inducing conformational changes within an about 5 nm poly(N-isopropyl acrylamide) (PNIPAM) capping layer. The system performs reversible switching between uniform and nonuniform states. The densely packed and uniform state is observed at a higher temperature, i.e., opposite to most phase transitions, where more ordered phases appear at lower temperatures. The induced nanoparticles' conformational changes result in different properties of the interfacial monolayer, including various types of aggregation. The analysis of surface pressure at different temperatures and upon temperature changes, surface potential measurements, surface rheology experiments, Brewster angle microscopy (BAM), and scanning electron microscopy (SEM) observations are accompanied by calculations to discuss the principles of the nanoparticles' self-assembly. Those findings provide guidelines for designing other adaptive 2D systems, such as programable membranes or optical interfacial devices.

Adaptive 2D and Pseudo-2D Systems: Molecular, Polymeric, and Colloidal Building Blocks for Tailored Complexity.

Two-dimensional and pseudo-2D systems come in various forms. Membranes separating protocells from the environment were necessary for life to occur. Later, compartmentalization allowed for the development of more complex cellular structures. Nowadays, 2D materials (e.g., graphene, molybdenum disulfide) are revolutionizing the smart materials industry. Surface engineering allows for novel functionalities, as only a limited number of bulk materials have the desired surface properties. This is realized via physical treatment (e.g., plasma treatment, rubbing), chemical modifications, thin film deposition (using both chemical and physical methods), doping and formulation of composites, or coating. However, artificial systems are usually static. Nature creates dynamic and responsive structures, which facilitates the formation of complex systems. The challenge of nanotechnology, physical chemistry, and materials science is to develop artificial adaptive systems. Dynamic 2D and pseudo-2D designs are needed for future developments of life-like materials and networked chemical systems in which the sequences of the stimuli would control the consecutive stages of the given process. This is crucial to achieving versatility, improved performance, energy efficiency, and sustainability. Here, we review the advancements in studies on adaptive, responsive, dynamic, and out-of-equilibrium 2D and pseudo-2D systems composed of molecules, polymers, and nano/microparticles.

Heteroaggregation of virions and microplastics reduces the number of active bacteriophages in aqueous environments.

The objective of this study is to explore the effects of microplastics on the viability of the bacteriophages in an aqueous environment. Bacteriophages (phages), that is, viruses of bacteria, are essential in homeostasis. It is estimated that phages cause up to 40% of the death of all bacteria daily. Any factor affecting phage activity is vital for the whole food chain and the ecology of numerous niches. We hypothesize that the number of active phages decreases due to the virions' adsorption on microplastic particles or by the released leachables from additives used in the production of plastic, for example, stabilizers, plasticizers, colorants, and reinforcements. We exposed three diverse phages, namely, T4 (tailed), MS2 (icosahedral), and M13 (filamentous), to 1 mg/mL suspension of 12 industrial-grade plastics [acrylonitrile butadiene styrene, high-impact polystyrene, poly-ε-caproamide, polycarbonate, polyethylene, polyethylene terephthalate, poly(methyl methacrylate), polypropylene, polystyrene, polytetrafluoroethylene, polyurethane, and polyvinyl chloride] shredded to obtain microparticles of radius ranging from 2 to 50 µm. The effect of leachables was measured upon exposure of phages not to particles themselves but to the buffer preincubated with microplastics. A double-overlay plaque counting method was used to assess phage titers. We employed a classical linear regression model to verify which physicochemical parameters (65 variables were tested) govern the decrease of phage titers. The key finding is that adsorption mechanisms result in up to complete scavenging of virions, whereas leachables deactivate up to 50% of phages. This study reveals microplastic pollution's plausible and unforeseen ecotoxicological effect causing phage deactivation. Moreover, phage transmission through adsorption can alter the balance of the food chain in the new environment. The effect depends mainly on the zeta potentials of the polymers and the phage type.

Optical Properties of a Tapered Optical Fiber Coated with Alkanes Doped with Fe3O4 Nanoparticles.

The presented research shows the possibilities of creating in-line magnetic sensors based on the detection of changes of light propagation parameters, especially polarization, obtained by mixing Fe3O4 nanoparticles with hexadecane (higher alkane) surrounding a biconical optical fiber taper. The fiber optic taper allows to directly influence light parameters inside the taper without the necessity to lead the beam out of the structure. The mixture of hexadecane and Fe3O4 nanoparticles forms a special cladding surrounding a fiber taper which can be controlled by external factors such as the magnetic field. Described studies show changes of transmission (power, loss) and polarization properties like azimuth, and ellipticity, depending on the location of the mixture on sections of tapered optical fiber. The taper was made of a standard single-mode telecommunication fiber, stretched out to a length of 20.0 ± 0.5 mm and the diameter of the tapers is around 15.0 ± 0.3 µm, with the loss lower than 0.5 dB @ 1550 nm. Such a taper causes the beam to leak out of the waist structure and allows the addition of the external beam-controlling cladding material. The presented research can be used to build polarization switches or optical sensor. The results show that it can be a new way to control the propagation parameters of a light beam using tapered optical fiber and magnetic mixture.