ABSTRACT
(Au nanorod)-(metal sulfide) core-shell structures are synthesized by employing Au nanorods as the starting reactants and metal thiobenzoates as the metal sulfide precursors in the presence of Ag(+) ions. The gas-sensing property of the prepared (Au nanorod)-CdS sensor exhibit a significantly enhanced response and higher sensitivity in comparison with a CdS sensor.
ABSTRACT
Composite material PANI/KIT-6, with polyaniline (PANI) chains encapsulated in the 3-D interconnected pore channels of mesoporous silica, KIT-6, has been synthesized via a gas-phase method. The composite formation and the presence of PANI inside the pore channels of KIT-6 were evidenced by Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), small-angle X-ray scatter (SAXS), transmission electron microscopy (TEM), and N(2) adsorption-desorption isotherms. The PANI/KIT-6 composite showed good electrical conductivity (2.4x10(-3) S/cm) due to the formation of 3-D networks of PANI inside the 3-D interconnected channels of KIT-6. The resistance of PANI/KIT-6 composite at different relative humidities (RH) was investigated. An essentially linear relationship between the relative resistance of the composite and the relative humidity of the environment was found from 11.3% to 97.3% RH.
