1.
RSC Adv
; 11(19): 11495-11499, 2021 Mar 16.
Article
in English
| MEDLINE
| ID: mdl-35423605
ABSTRACT
A water-mediated proton-conducting Eu(iii)-MOF has been synthesized, which provides a stable proton transport channel that was confirmed by theoretical calculation. The investigation of proton conduction shows that the conductivity of Eu(iii)-MOF obtained at 353 K and 98% RH is 3.5 × 10-3 S cm-1, comparable to most of the Ln(iii)-MOF based proton conductors.
2.
Chem Commun (Camb)
; 55(12): 1762-1765, 2019 Feb 05.
Article
in English
| MEDLINE
| ID: mdl-30664140
ABSTRACT
An unprecedented Tb(iii) polycarboxylate, {[Tb4(TTHA)2(H2O)4]·7H2O}n (1), has been synthesized. It possesses an efficient proton transfer pathway formed by water molecules and carboxyl groups, which exhibits proton conductivity over 10-2 S cm-1 at 295-358 K and 98% relative humidity.