Electric-Field-Controlled Cold Dipolar Collisions between Trapped CH_{3}F Molecules.

Reaching high densities is a key step toward cold-collision experiments with polyatomic molecules. We use a cryofuge to load up to 2×10^{7} CH_{3}F molecules into a boxlike electric trap, achieving densities up to 10^{7}/cm^{3} at temperatures around 350 mK where the elastic dipolar cross section exceeds 7×10^{-12} cm^{2}. We measure inelastic rate constants below 4×10^{-8} cm^{3}/s and control these by tuning a homogeneous electric field that covers a large fraction of the trap volume. Comparison to ab initio calculations gives excellent agreement with dipolar relaxation. Our techniques and findings are generic and immediately relevant for other cold-molecule collision experiments.

Continuous centrifuge decelerator for polar molecules.

Producing large samples of slow molecules from thermal-velocity ensembles is a formidable challenge. Here we employ a centrifugal force to produce a continuous molecular beam with a high flux at near-zero velocities. We demonstrate deceleration of three electrically guided molecular species, CH3F, CF3H, and CF3CCH, with input velocities of up to 200 m s(-1) to obtain beams with velocities below 15 m s(-1) and intensities of several 10(9) mm(-2) s(-1). The centrifuge decelerator is easy to operate and can, in principle, slow down any guidable particle. It has the potential to become a standard technique for continuous deceleration of molecules.

Storage and adiabatic cooling of polar molecules in a microstructured trap.

We present a versatile electric trap for the exploration of a wide range of quantum phenomena in the interaction between polar molecules. The trap combines tunable fields, homogeneous over most of the trap volume, with steep gradient fields at the trap boundary. An initial sample of up to 10(8), CH(3)F molecules is trapped for as long as 60 s, with a 1/e storage time of 12 s. Adiabatic cooling down to 120 mK is achieved by slowly expanding the trap volume. The trap combines all ingredients for opto-electrical cooling, which, together with the extraordinarily long storage times, brings field-controlled quantum-mechanical collision and reaction experiments within reach.

Calculating the fine structure of a Fabry-Perot resonator using spheroidal wave functions.

A new set of vector solutions to Maxwell's equations based on solutions to the wave equation in spheroidal coordinates allows laser beams to be described beyond the paraxial approximation. Using these solutions allows us to calculate the complete first-order corrections in the short-wavelength limit to eigenmodes and eigenfrequencies in a Fabry-Perot resonator with perfectly conducting mirrors. Experimentally relevant effects are predicted. Modes which are degenerate according to the paraxial approximation are split according to their total angular momentum. This includes a splitting due to coupling between orbital angular momentum and spin angular momentum.