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A zinc(II) metal-organic framework based on triazole and dicarboxylate ligands for selective adsorption of hexane isomers.
Ling, Yun; Chen, Zhen-Xia; Zhai, Fu-Peng; Zhou, Ya-Ming; Weng, Lin-Hong; Zhao, Dong-Yuan.
Chem Commun (Camb) ; 47(25): 7197-9, 2011 Jul 07.
Article in English | MEDLINE | ID: mdl-21625720

ABSTRACT

A three-dimensional (3D) metal-organic framework {[Zn(2)(HBDC)(2)(dmtrz)(2)]·guest}(n) with pcu net has been solvothermally synthesized, which shows selective adsorption of linear and monobranched hexane isomers over a dibranched one.


Subject(s)
Dicarboxylic Acids/chemistry , Hexanes/chemistry , Organometallic Compounds/chemistry , Triazoles/chemistry , Zinc/chemistry , Adsorption , Isomerism , Ligands , Models, Molecular , Molecular Conformation
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