Bamboo cellulose-derived activated carbon aerogel with controllable mesoporous structure as an effective adsorbent for tetracycline hydrochloride.

Activated carbon has been widespread applied in the removal of pollutants in wastewater. However, many biomass-derived activated carbon suffer from the challenge of controllable pore size regulation, hindering their efficient adsorption of pollutants. Herein, bamboo-derived activated carbon aerogel (BACA) has been successfully prepared through KOH high-temperature activation of cellulose aerogel which was prepared using cellulose extracted from bamboo. Bamboo cellulose aerogel provides sufficient reaction sites for KOH, which is conducive to the formation of a mass of mesoporous structures on the pore walls of the activated carbon aerogel. The optimal BACA adsorbent shows high specific surface area (2503.80 m2/g), and maximum adsorption capability for tetracycline hydrochloride (TCH) reaches 863.8 mg/g at 30 ℃. The removal efficiencies of TCH are 100% and 98.4% at 40 ℃ when the initial concentrations are 500 and 700 mg/L, respectively. Adsorption kinetics and isotherm indicate that the adsorption of BACA for TCH is monolayer adsorption based on chemical adsorption. Spontaneous and endothermic adsorption processes are proved by adsorption thermodynamic studies. Additionally, coexisting ions have insignificant effect on TCH adsorption, and the BACA sample displays excellent adsorption property for five reuse cycles with a removal efficiency of 80.95%, indicating the outstanding adsorption capacity of BACA in practical application. The excellent adsorption performance provides BACA with a promising perspective to remove TCH from wastewater, and the prepared method of BACA can be widely extended to other biomass materials.

Porous activated carbons derived from bamboo pulp black liquor for effective adsorption removal of tetracycline hydrochloride and malachite green from water.

As a kind of wastewater produced by papermaking industry, bamboo pulp black liquor (BPBL) discharged into water causes serious environmental problems. In this work, BPBL was successfully converted into porous carbon after activation with potassium hydroxide (KOH) through one-step carbonization, and adsorption properties of porous carbon derived from bamboo pulp black liquor (BLPC) for tetracycline hydrochloride (TCH) and malachite green (MG) were studied. The adsorption capacities of BLPC for TCH and MG are 1047 and 1277 mg/g, respectively, due to its large specific surface area of 1859.08 m2/g. Kinetics and isotherm data are well fitted to the pseudo-second-order rate model and Langmuir model, respectively. Adsorption experiments and characterizations reveal that the adsorption mechanism involved in TCH and MG adsorption on BLPC mainly depends on the synergistic effect of pore filling, H-bonding, π-π interactions and weak electrostatic interactions. In addition, BLPC shows excellent photothermal properties, and the adsorption capacity of TCH and MG on BLPC can reach 584 and 847 mg/g under the irradiation of near infrared lamp for 50 min, respectively. The synthesized BLPC with high adsorption efficiency, good recovery ability, improved adsorption under near-infrared irradiation can be a promising and effective adsorbent for TCH or MG or other pollutes.