Temporal and spatial changes of Pb in soils in Cuihu wetland, Beijing, China.

Protecting soil from Pb contamination has been a programme for a long time in China. However, research on lead pollution in wetlands remains rare. To understand the characteristics of Pb pollution in Beijing and the sources of contamination of different soil samples in wetlands, we collected samples during all four seasons from two soil horizons and analyzed their Pb concentrations and Pb isotope ratios. The average concentrations of Pb varied from 65.44 mg/kg in spring to 106.11 mg/kg in winter. Concentrations in autumn were significantly lower than those in spring and summer and were notably different between A and B Horizons (59.42 and 71.47 mg/kg, respectively). The Pb isotopic compositions show that Pb pollution results from a mixing of geogenic and anthropogenic materials. The ratios of 206Pb/207Pb and 206Pb/208Pb evidenced that coal combustion and vehicle exhaust are the main sources of lead contamination in the two horizons. These results will help in reducing lead contamination in soil by knowing the temporal and spatial variations and sources of lead in Beijing.

The PM removal process of wetland plant leaves with different rainfall intensities and duration.

Today, particulate-matter (PM) pollution has become one of the most severe air-pollution problems. As the most commonly used method in daily life, phytoremediation can use plant organs (such as leaves) as biological filters for pollutants to repair the atmosphere. At the same time, rainfall can remove PM from plant-leaf surfaces and enable them to adsorb PM again. By simulating natural rainfall, the rainfall characteristics are quantified as rainfall intensity and rainfall duration, and we use the washout-weighing method to obtain the amount of PM removed from the leaf surface. Then, use a scanner to scan the leaves after rain to get their images, and use Image J software to process the images to obtain leaf area. Finally, the amount of PM removed by rain per unit leaf area can be calculated. It will be used to explore the impact of different rainfall intensity and duration on the removal of PM from the leaf surface of wetland plants. The results showed that under three rainfall intensities used in this experiment, the removal of PM from plant-leaf surfaces all increased with an increase in rainfall duration. When the particle size is 10-100-µm, and the rainfall intensity is 30 mm/h, the removal amount of plant particles tested in this experiment is the largest. With increased rainfall duration, the removal of PM from plant-leaf surfaces increased sharply at first, then slowly, and finally tended to be stable. The removal efficiency of PM on the blade surface is most apparent at the early stage of rainfall, and then gradually weakens. Among the four wetland plants tested in this experiment, in the range of 10-100-µm, the number of PM on the leaf surface of Scirpus validus is the largest, and the optimum rainfall intensity is 30 mm/h; in the range of 2.5-10-µm, the number of PM on the leaf surface of Typha orientalis is the largest, and the optimal rainfall intensity is 30 mm/h; in the range of 0.45-2.5-µm, the number of PM on the leaf surface of Iris wilsonii is the largest, and the optimal rainfall intensity is 15 mm/h. Wetland species with high particle accumulation capacity can provide references for vegetation restoration of degraded wetland plants and plant cultivation in constructed wetlands. At the same time, the best rainfall intensity and duration for removing particulate matter on the surface of plant leaves were obtained through experiments, which provided a reference for the design of automatic plant irrigation systems and dust removers in different scenarios.

Understanding PM2.5 concentration and removal efficiency variation in urban forest park-Observation at human breathing height.

To increase our knowledge of PM2.5 concentrations near the surface in a forest park in Beijing, an observational study measured the concentration and composition of PM2.5 in Beijing Olympic Forest Park from 2014 to 2015. This study analyzed the meteorological factors and removal efficiency at 1.5 m above the ground (human breathing height) over the day in the forest. The results showed that the average concentrations of PM2.5 near the surface peaked at 07:00-09:30 and reached their lowest at 12:00-15:00. Besides, the results showed that the annual concentration of PM2.5 in the forest was highest during winter, followed by spring and fall, and was lowest during summer. The main chemical components of PM2.5 near the surface in the forest were SO4 2- and NO3 -, which accounted for 68.72% of all water-soluble ions that we observed. The concentration of PM2.5 in the forest had a significant positive correlation with relative humidity and a significant negative correlation with temperature. The removal efficiency near the surface showed no significant variation through the day or year. In the forest, the highest removal efficiency occurred between 07:00 and 09:30 in summer, while the lowest occurred between 09:30 and 12:00 in winter.

The size and distribution of tidal creeks affects salt marsh restoration.

Salt marshes are changeable and important ecosystems that currently face various threats, including global climate change and human activities. The influence of these factors can result in the degradation of salt marshes. Tidal creeks, which are an important source of nutrients and other substances for salt marsh vegetation, play an important role in the health of salt marshes. In this study, the morphological characteristics of tidal creeks and the characteristics of two typical plants, Suaeda glauca (SG) and Phragmites communis (PC), in the Yellow River Delta, China were investigated to determine the effect of tidal creeks on these plants. Aerial photography and field measurements of tidal creeks were carried out from May to July 2018 in the study area. At the same time, nine line-intercepts were set in the vertical direction of tidal creeks to investigate plants. The results showed that different grades of tidal creek exerted no significant influence on the growth of either S. glauca or P. communis. However, unlike grade, the size of a creek and the distance from it had marked effects on these plants. The cross-sectional area of a tidal creek had a significant positive impact on the density of S. glauca (r = 0.39, p = 0.02). For P. communis, the depth of a tidal creek had a strong correlation with this species' density (r = 0.51, p = 0.04) and height (r = 0.63, p = 0.01). Meanwhile, there was a negative relationship between the distance from tidal creeks and the height of S. glauca (r = -0.52, p = 0.02). Conversely, the height (r = 0 0.90, p = 0.00) and density (r = 0.62, p = 0.01) of P. communis were positively affected by its vertical distance from tidal creeks. We found that the subtidal zone near a tidal creek was more conducive to the recovery and growth of S. glauca, and that areas further away from a tidal creek, located in the intertidal and subtidal zones, were more conducive to the recovery and growth of P. communis. The parameters associated with tidal creeks in the subtidal zone (cross sectional area 4.55 m2, distance 0-10 m) were beneficial for the growth of S. glauca. For P. communis, relevant features in the intertidal and subtidal zones (depth 0.40-0.45 m, distance 20-60 m) are useful. Our results suggest that attention should be paid to the effects of size and distribution of tidal creeks during the process of salt marsh restoration. This work also provides practical guidance for the restoration of native salt marshes in China.

The blocking effect of atmospheric particles by forest and wetland at different air quality grades in Beijing China.

To understand the effect of forests and wetlands on air quality, the PM10 and PM2.5 concentration and meteorological data were collected in the forest and wetland in the Beijing Olympic Forest Park in China from May 2106 to May 2017. The blocking rates of forest and wetland to PMs were calculated under different air quality grades which were divided into six levels base on a technical regulation. And we have got three main conclusions. (1) The diurnal variations of PMs were different in the forest and wetland. It showed a first decrease and then an increase in the forest; the lowest value (PM10 = 40.00 µg/m3, PM2.5 = 5.37 µg/m3) was at approximately 12:00. In the wetlands, the lowest values were recorded at 16:00 (PM10 = 39.63 µg/m3 and PM2.5 = 15.89 µg/m3). (2) Another result showed that the blocking in the forest were significantly higher than that at the wetlands (P < .05), and the blocking effects were much better under lower air quality grades. The blocking rate of PM10 and PM2.5 was the highest when the air quality is excellent in the forest. When it comes to wetland, the highest blocking rate of PM10 appears at good air quality, and the highest of PM2.5 was at serious polluted. (3) In addition, there was negative correlation between PM concentrations and temperature, whereas the correlation between PM concentrations and relative humidity is positive. However, the correlation between blocking and meteorological parameters is weak.

Assessing the spatiotemporal characteristics of dry deposition flux in forests and wetlands.

Forests and wetlands, as two important ecosystems, play a crucial role in reducing the concentration of particulate matters. The main purpose of this study is to reveal the contribution of forest and wetland ecosystems to the reduction of particulate matter. We collected the concentration and meteorological data during the daytime in a forest and a wetland in the Olympic Park in Beijing. The main results are as follows: daily variation in the PM10 and PM2.5 concentration had the similar trend with the lowest value at midday and relatively high values in the morning and at nightfall. In the forest ecosystem, the trend of PM10 concentration at three heights followed the order: 6 m > 10 m > 1.5 m, while that of the PM2.5 followed the order 1.5 m > 10 m > 6 m. In the wetland, PM10 and PM2.5 concentrations at the three heights exhibited the same trend: 10 m > 1.5 m > 6 m. It is a comprehensive impact on concentration which may include vegetation collection rate, meteorological conditions and some kind of human activities. The PM deposition velocity of wetland was higher than that of forest, and showed the highest values in winter both in PM2.5 and PM10. The PM deposition flux in wetland was lower than forest only in autumn, and the value of deposition flux was higher than forest in other seasons. PM concentrations was positively correlated with relative humidity but negatively correlated with temperature and wind velocity.

Effect of the wetland environment on particulate matter and dry deposition.

In Beijing, particulate matter (PM) in the atmosphere, especially PM2.5 and PM10, have attracted public attention because of its adverse effects. A series of studies have investigated the sources and spatial-temporal variation of PM. Wetland has been reported to own the capacity of resolving air problem. To examine the characteristics of the particulate matter in wetlands, the diurnal variation of PM2.5 and PM10 concentrations with respect to two heights (i.e. 1.5 and 10 m, respectively) and three meteorological factors (i.e. wind speed, temperature, and relative humidity, respectively) was monitored in the Cuihu National Wetland Park in Beijing, and the dry deposition velocity and flux were analysed using the above-mentioned data. Results indicated that (1) As for diurnal variation, the PM concentration constantly decreased at 07:00-16:00 and gradually increased at 16:00-18:00. The maximum instantaneous concentration was observed at 07:00-10:00, while the minimum instantaneous concentration was observed at 13:00-16:00. (2) The annual concentration variation of PM followed the order of dry period > wet period > normal period. (3) The particulate concentrations at 10 m were always greater than those at 1.5 m. (4) The PM concentration was positively correlated to the relative humidity and negatively correlated to the temperature. Wind speed exhibited a complex effect on PM concentration. (5) The regulation of dry deposition efficiency followed the order of spring > winter > summer. (6) Wind speed strongly and positively affected the dry deposition velocity of PM10. The effects of temperature and relative humidity on dry deposition were uncertain.

Lead isotope trends and sources in the atmosphere at the artificial wetland.

With the rapid development of industry, studies on lead pollution in total suspended particulate matter (TSP) have received extensive attention. This paper analyzed the concentration and pollution sources of lead in the Cuihu Wetland in Beijing during the period of 2016-2017. The results show that the lead contents in TSP in the Cuihu Wetland were approximately equal in summer and spring, greater in winter, and greatest in autumn. The corresponding lead concentrations were 0.052, 0.053, 0.101, and 0.115 ng/m3, respectively. We compared the 206Pb/207Pb data with other materials to further understand the potential sources of atmospheric lead. The mean values of 206Pb/207Pb from spring to winter were 1.082, 1.098, 1.092, and 1.078, respectively. We found that the lead sources may be associated with coal burning, brake and tire wear, and vehicle exhaust emissions. We also calculated the enrichment factor values for the four seasons, and the values were all much greater than 10, indicating that the lead pollution is closely related to human activities.

Particle removal in polluted cities: Insights from the wash-off process dynamics for different wetland plants.

Particulate matter (PM) in the atmosphere is a threat to human health. Wetland plants were confirmed to accumulate particles on the leaf surface; at the same time, rainfall could wash-off particles and accelerate the whole removal process, however, the dynamic processes occurring during rainfall events on wetland plants remain unclear. In order to provide sustainable strategies for authorities to take measures, we need to figure out how to reduce PM on leave surface by artificial rainfall efficiently. Four wetland species (Scirpus validus, Typha orientalis, Phragmites australis, and Iris wilsonii) were selected to examine for leave surface accumulation and simulate the experiment. We estimated the wash-off ability of rainfalls with three different intensities (15, 30, and 60 mm h-1) and determined the proportions of different PM size-fractions washed by the rains. The results showed that particles accumulated on the surface could be washed off efficiently (78% ∼ 89%) by the simulated rainfalls. The removal rates were high in the first 30 min and large particles comprised a large proportion of the removed particles. The rainfall with the intensity of 30 mm h-1 removed the most particles among three different rainfall intensities. When the rainfall intensity increased, fine particles (PM2.5) could be washed off more easily. Moreover, with a thinner wax layer, fine particles on wetland plants' leaf surfaces might be more easily removed by the rains. While wash off the plants, spraying rains with the intensity of 30 mm h-1 for about 30 min every time (high intensity with shorter time) may be particle removal efficiency.

Influence of fungi and bag mesh size on litter decomposition and water quality.

Litter decomposition is a complex process that is influenced by many different physical, chemical, and biological processes. Environmental variables and leaf litter quality (e.g., nutrient content) are important factors that play a significant role in regulating litter decomposition. In this study, the effects of adding fungi and using different mesh size litter bags on litter (Populus tomentosa Carr. and Salix matsudana Koidz.) decomposition rates and water quality were investigated, and investigate the combination of these factors influences leaf litter decomposition. Dissolved oxygen (DO), chemical oxygen demand (COD), total phosphorus (TP), and ammonia-nitrogen (NH3-N) were measured during the 112-day experiment. The salix leaf litter (k = 0.045) displayed faster decomposition rates than those of populous leaf litter (k = 0.026). Litter decomposition was initially slow and then accelerated; and by the end of the experiment, the decomposition rate was significantly higher (p = 0.012, p < 0.05) when fungi were added to the treatment process compared to the blank, and litter bags with different mesh sizes did not influence the decomposition rate. The variations in the decomposition rates and nutrient content were influenced by litter quality and a number of environmental factors. The decomposition rate was most influenced by internal factors related to litter quality, including the N/P and C/P ratios of the litter. By quantifying the interact effect of environment and litter nutrient dynamic, to figure out the revetment plant litter decomposition process in a wetland system in biological physical and chemical aspects, which can help us in making the variables that determine decomposition rates important for assessing wetland function.

Comparison of dry and wet deposition of particulate matter in near-surface waters during summer.

Atmospheric particulate matter (PM) deposition which involves both dry and wet processes is an important means of controlling air pollution. To investigate the characteristics of dry and wet deposition in wetlands, PM concentrations and meteorological conditions were monitored during summer at heights of 1.5 m, 6 m and 10 m above ground level at Cuihu Wetland (Beijing, China) in order to assess the efficiency of PM2.5 (particles with an aerodynamic size of <2.5 µm) and PM10 (particles with an aerodynamic size of <10 µm) removal. The results showed: Daily concentrations of PM, dry deposition velocities and fluxes changed with the same variation trend. The daily average deposition velocity for PM10 (3.19 ± 1.18 cm·s-1) was almost 10 times that of PM2.5 (0.32 ± 0.33 cm·s-1). For PM2.5, the following dry deposition fluxes were recorded: 10 m (0.170 ± 0.463 µg·m-2·s-1) > 6 m (0.007 ± 0.003 µg·m-2·s-1) > 1.5 m (0.005 ± 0.002 µg·m-2·s-1). And the following deposition fluxes for PM10 were recorded: 10 m (2.163 ± 2.941 µg·m-2·s-1) > 1.5 m (1.565 ± 0.872 µg·m-2·s-1) > 6 m (0.987 ± 0.595 µg·m-2·s-1). In the case of wet deposition, the relative deposition fluxes for PM2.5 and PM10 were 1.5 m > 10 m > 6 m, i.e. there was very little difference between the fluxes for PM2.5 (0.688 ± 0.069 µg·m-2·s-1) and for PM10 (0.904 ± 0.103 µg·m-2·s-1). It was also noted that rainfall intensity and PM diameter influenced wet deposition efficiency. Dry deposition (63%) was more tilted towards removing PM10 than was the case for wet deposition (37%). In terms of PM2.5 removal, wet deposition (92%) was found to be more efficient.

Sabina chinensis and Liriodendron chinense improve air quality in Beijing, China.

Urban forests have been shown to be efficient for reducing air pollutants especially for particulate matters (PMs). This study aims to reveal the PM blocking capacity of two common artificial landscape species, Sabina chinensis and Liriodendron chinense and to investigate spatial-temporal heterogeneities by estimating the vegetation collection velocity of coarse (PM10) and fine particles (PM2.5) during different seasons and heights. PM concentration and meteorological data were collected on both leeward and windward sides of trees during the daytime in both summers and winters from 2013 to 2015. Concentration and meteorological monitors were installed at three heights, bottom (1.5 m), middle (3.5 m), and top (5.5 m) of the canopy. The results showed: During daytime, the collection velocity changed and PM2.5 collection velocity was much higher than that of PM10. Furthermore, the maximum collection velocities of L. chinense and S. chinensis occurred at 14:00-16:00 both in summer and winter. Moreover, the collection velocity had a positive correlation with wind speed and temperature. The blocking capacities of L. chinense and S. chinensis varied from season to season, and the concentrations of particulate matter indicate the middle canopy of both species as the most effective part for TSP blocking. Furthermore, these two species are more effective blocking in PM2.5 than PM10. The blocking capacity of S. chinensis is generally better. The vegetation collection is the major process of PM removal near the ground and sedimentation was not taken into consideration near the ground.

Particle removal by vegetation: comparison in a forest and a wetland.

Vegetation collection is one of the most effective scavenging methods but relevant studies are limited. It can be described by some abstract parameters such as collection rates and deposition fluxes within the canopy. In order to estimate the dry deposition within the canopy of particular matters (PMs) in Beijing, a highly particle-polluted city, and reveal the PM pollution-removal abilities of plants in wetlands and forests, concentration and meteorological data were collected during the daytime in an artificial forest and a wetland in the Olympic Park in Beijing. The dry depositions within the canopy and vegetation collection rates were calculated by a well-developed model and validated by measured deposition fluxes in 11 random experiment days. The experiment year was divided into three plant growth stages based on canopy density, and the day was divided into four different times. Two heights, 10 and 1.5 m, were defined in the forest while in the wetland, 0.5 and 1.5 m were defined. The results showed that in Beijing, the most severe pollution by PMs occurs in the non-leaf stage (NS), and the full-leaf stage (FS) is the cleanest stage. In NS, namely winter, more fossil fuel was used for worms in Beijing and peripheral areas and this might be the reason for the serious pollution condition. Within the canopy, PM deposition fluxes in the wetland are more than those in the forest, but the vegetation collection rates of the forest are higher. The lower temperature conditions led to more dry deposition, and the larger canopy contributed to the higher collection rates. During the daytime, over the year, the deposition of PM10 in three plant growth stages is NS ≥ half-leaf stages (HS) ≥ FS, whereas the deposition of PM2.5 is NS ≥ FS ≥ HS, and during the daytime, the maximum deposition fluxes occur in 6:00-9:00 in the wetland while the minimum deposition values occur in 15:00-18:00. This phenomenon was related to the temporal variation of particle concentration.