Surface engineering of zinc plate by self-growth three-dimensional-interconnected zinc silicate nanosheets effectively guiding the deposition of zinc ion for aqueous Zn metal battery.

Among battery technologies, aqueous zinc ion batteries (AZIBs) have hit between the eyes in the next generation of extensive energy storage devices due to their outstanding superiority. The main problem that currently restricts the development of AZIBs is how to obtain stable Zn anodes. In this study, taking the improvement of a series of problems caused by the physically attached artificial interfacial layer on Zn anode as a starting point, a nanosheet morphology of ZnSiO3 (denoted as ZnSi) is constructed by self-growth on Zn foil (Zn@ZnSi) by a simple hydrothermal reaction. The ZnSi nano-interfacial layer effectively slices the surface of the Zn foil into individual microscopic interfacial layers, constructing abundant pores. The nanosheets of Zn@ZnSi construct rich nanoscale Zn2+ transport channels, which provide higher electron and ion transport paths, thus achieving the effect of effectively homogenizing the electric field distribution and decreasing the local current density. Thanks to its inherent and structural properties, the Zn@ZnSi anode has a high specific capacity and good cycling stability compared with the Zn electrode. The lifetime of the Zn@ZnSi//Zn@ZnSi symmetric cell is much higher than that of the Zn//Zn symmetric cell at 1 mA cm-2. The capacity of the Zn@ZnSi//NH4V4O10 full cell can still reach 98 mAh g-1 after 1000 cycles at 1 A/g. The low-cost and scalable synthesis of ZnSi nano-interfacial layer on Zn is expected to provide new perspectives on interfacial engineering for Zn anodic protection.

Highly efficient photocatalyst fabricated from the recycling of heavy metal ions in wastewater for dye degradation.

Water pollution and energy crisis are becoming global and strategic issues that people are closely concerned about. Green and energy-saving photocatalytic technology is developing rapidly in solving global energy crises and environmental pollution problems. Therefore, we propose the "kill two birds with one stone" strategy to design efficient photocatalysts for dye wastewater treatment by utilizing heavy metal ions in wastewater. The adsorption properties of Mordenite (MOR) were utilized to removal heavy metal ions (Cd2+ and Zn2+) from waste water, and the adsorbed heavy metal ions were dried and sulfurized to obtain CdS/ZnS/MOR(ZnCdM). Then, g-C3N4 was ultrasonically dispersed and composited with ZnCdM by self-assembly, 25 wt% ZnCdCM photocatalytic material was obtained with a degradation rate of 99.8% in 1.5 h for Rhodamine B(RhB). It was found that MOR can provid adequate support for active substances, and the surface of MOR with smaller sizes of CdS nanoparticles, ZnS nanoparticles and g-C3N4 nanosheets, which increased the specific surface area of the materials and improved the reactivity. The porous structure of MOR is favorable for the enrichment of RhB, and the electric field effect of MOR leads to the decrease of the photogenerated carrier complex rate in the semiconductor, which increases the catalytic efficiency. In addition, the double Z charge transfer mechanism formed by CdS, ZnS, g-C3N4 is favorable for separating photogenerated carriers. These synergistic effects improved the photocatalytic efficiency. This strategy will be a green and promising solution to water pollution and energy crisis.

Anion Structure Regulation of Cobalt Silicate Hydroxide Endowing Boosted Oxygen Evolution Reaction.

Transition metal silicates (TMSs) are attempted for the electrocatalyst of oxygen evolution reaction (OER) due to their special layered structure in recent years. However, defects such as low theoretical activity and conductivity limit their application. Researchers always prefer to composite TMSs with other functional materials to make up for their deficiency, but rarely focus on the effect of intrinsic structure adjustment on their catalytic activity, especially anion structure regulation. Herein, applying the method of interference hydrolysis and vacancy reserve, new silicate vacancies (anionic regulation) are introduced in cobalt silicate hydroxide (CoSi), named SV-CoSi, to enlarge the number and enhance the activity of catalytic sites. The overpotential of SV-CoSi declines to 301 mV at 10 mA cm-2 compared to 438 mV of CoSi. Source of such improvement is verified to be not only the increase of active sites, but also the positive effect on the intrinsic activity due to the enhancement of cobalt-oxygen covalence with the variation of anion structure by density functional theory (DFT) method. This work demonstrates that the feasible intrinsic anion structure regulation can improve OER performance of TMSs and provides an effective idea for the development of non-noble metal catalyst for OER.

Concerning for the solvent-polarity-dependent conformational equilibrium and ESIPT mechanism in Pz3HC system: A novel insight.

In this report, we propose a new insight into the interaction between the solvent-polarity-dependent conformational equilibrium and excited state intramolecular proton transfer (ESIPT) behavior of Pz3HC system in four different polar solvents (polarity order: ACN > THF > TOL > CYC). Using quantum chemistry method, we first announce a coexistence mechanism between Pz3HC-1 and Pz3HC-3 in the ground state in four solvents based on the Boltzmann distribution. In particular, Pz3HC-1 is the principal configuration in non-polar solvent, but Pz3HC-3 is the principal configuration in polar solvent. In addition, the simulated fluorescence spectra interprets the negative solvatochromism effect of Pz3HC-1 and Pz3HC-3 in four solvents. The evidence from intramolecular hydrogen bonding (IHB) parameters and electronic perspective collectively confirms the light-induced IHB enhancement and intramolecular charge transfer (ICT) properties in Pz3HC-1 and Pz3HC-3, which raises the likelihood of the ESIPT process. Combining the calculation of potential energy curve (PEC) and intrinsic reaction coordinate (IRC), we demonstrate that the ESIPT ease of Pz3HC-1 in different polar solvents obeys the order of CYC > TOL > THF > ACN, while the order of ESIPT ease in Pz3HC-3 is opposite. Notably, the ESIPT process of Pz3HC-3 in CYC solvent is accompanied by the twisted intramolecular charge transfer (TICT) process. In addition, we also reveal that the enol* and keto* fluorescence peaks of Pz3HC-3 in CYC solvent are quenched by ISC and TICT process, respectively. Our work not only provides a satisfactory explanation of the novel dynamics mechanism for Pz3HC system, but also brings light to the design and application of new sensing molecules in the future.

One-step hydrothermal synthesis of vanadium dioxide/carbon core-shell composite with improved ammonium ion storage for aqueous ammonium-ion battery.

Aqueous nonmetallic ion batteries have garnered significant interest due to their cost-effectiveness, environmental sustainability, and inherent safety features. Specifically, ammonium ion (NH4+) as a charge carrier has garnered more and more attention recently. However, one of the persistent challenges is enhancing the electrochemical properties of vanadium dioxide (VO2) with a tunnel structure, which serves as a highly efficient NH4+ (de)intercalation host material. Herein, a novel architecture, wherein carbon-coated VO2 nanobelts (VO2@C) with a core-shell structure are engineered to augment NH4+ storage capabilities of VO2. In detail, VO2@C is synthesized via the glucose reduction of vanadium pentoxide under hydrothermal conditions. Experimental results manifest that the introduction of the carbon layer on VO2 nanobelts can enhance mass transfer, ion transport and electrochemical kinetics, thereby culminating in the improved NH4+ storage efficiency. VO2@C core-shell composite exhibits a remarkable specific capacity of ∼300 mAh/g at 0.1 A/g, which is superior to that of VO2 (∼238 mAh/g) and various other electrode materials used for NH4+ storage. The NH4+ storage mechanism can be elucidated by the reversible NH4+ (de)intercalation within the tunnel of VO2, facilitated by the dynamic formation and dissociation of hydrogen bonds. Furthermore, when integrated into a full battery with polyaniline (PANI) cathode, the VO2@C//PANI full battery demonstrates robust electrochemical performances, including a specific capacity of ∼185 mAh·g-1 at 0.2 A·g-1, remarkable durability of 93 % retention after 1500 cycles, as well as high energy density of 58 Wh·kg-1 at 5354 W·kg-1. This work provides a pioneering approach to design and explore composite materials for efficient NH4+ storage, offering significant implications for future battery technology enhancements.

Topochemical behavior of ferrocene embedded in V2O5·nH2O with weak hydrogen bonding enhancing ammonium-ion storage.

Aqueous ammonium ion batteries (AAIBs) are garnering increasing attention due to their utilization of abundant resources, cost-effectiveness, safety, and unique energy storage mechanism. The pursuit of high-performance cathode materials has become a pressing issue. In this study, we propose and synthesize ferrocene-embedded hydrated vanadium pentoxide (Fer/VOH) for implementation in AAIBs. The inclusion of ferrocene serves to expand the interlayer spacing, mitigate interlayer forces, and introduce the electron-rich environment characteristic of ferrocene. This augmentation facilitates the creation of additional oxygen vacancies, substantially enhancing the capacity and efficiency of ammonium ion storage. Notably, our investigation reveals that the incorporation of ferrocene attenuates the hydrogen bonding interactions associated with ammonium ions, rendering them more amenable to the interlayer embedding and release processes. Building upon these advantages, Fer/VOH exhibits a specific capacity of 313 mAh/g at a current density of 0.2 A/g, representing the highest reported performance among vanadium oxides utilized in AAIBs to date. Even after 2000 charge/discharge cycles at a current density of 2 A/g, Fer/VOH maintains a reversible specific capacity of 89 mAh/g, with a capacity retention rate of 54.8%. This study confirms the viability of Fer/VOH as a cathode material for AAIBs and offers a novel approach to enhancing the electrical conductivity and diminishing the hydrogen bonding forces in vanadium oxide intercalation through the embedding of electron-rich species and positronic groups.

Mild steam treatment: Enhancing the rehydration performance of instant rice noodles by changing the physicochemical properties and gel structure of rice starch.

The "instant" quality of instant rice noodles is significantly affected by slow rehydration during cooking. This happens as a result of the native rice starch's low ability to gelatinize as well as the high shear and pressure utilized in industries during the widely used extrusion molding process. In order to address this issue, the rice flour was pretreated with mild steam (MS) technology. The results revealed that the rehydration qualities of the rice noodles that were extruded from the steam-treated flour significantly improved. There was a reduction of 25.5% in the rehydration time, from 443 to 330 s. The MS-treated rice starch's peak viscosity increased to 4503 from 4044 mPa/s. Decreases in gelatinization enthalpy (ΔH) and short-range ordering also suggest a reduction in difficulty in accomplishing starch gelatinization. Scanning electron microscopy studies showed particle aggregation increased as the treatment duration lasted longer. In conclusion, our findings indicate that we successfully addressed the issue of slow rehydration in instant rice noodles while presenting a novel approach for their manufacturing in the manufacturing sector.

Photophysical Properties of (E)-1-(4-(Diethyla-mino)-2-hydroxybenzylidene)-4,4-dimethylthiosemicarbazide Compound and Its Triple Fluorescence Emission Mechanism: A Theoretical Perspective.

In view of the application prospects in biomedicine of (E)-1-(4-(diethyla-mino)-2-hydroxybenzylidene)-4,4-dimethylthiosemicarbazide (DAHTS), the behavior of excited-state dynamics and photophysical properties were studied using the density functional theory/time-dependent density functional theory method. A series of studies indicated that the intramolecular hydrogen-bond (IHB) intensity of DAHTS was enhanced after photoexcitation. This was conducive to promoting the excited-state intramolecular proton-transfer (ESIPT) process. Combining the analysis of the IHB and hole-electron, it revealed that the molecule underwent both the ESIPT process and the twisted charge-transfer (TICT) process. Relying on exploration of the potential energy surface, it was proposed that the different competitive mechanisms between the ESIPT and TICT processes were regulated by solvent polarity. In acetonitrile (ACN) solvent, the ESIPT process occurred first, and the TICT process occurred later. In contrast, in the CYH solvent, the molecule first underwent the TICT process and then the ESIPT process. Furthermore, we raised the possibility that the TICT behavior was the cause of weak fluorescence emission for the DAHTS in CYH and ACN solvents. By the dimer correlation analysis, the corresponding components of triple fluorescence emission were clearly assigned, corresponding to the monomer, dimer, and ESIPT isomer in turn. Our work precisely elucidated the photophysical mechanism of DAHTS and the attribution of the triple fluorescence emission components, which provided valuable guidance for the development and regulation of bioactive fluorescence probes with multiband and multicolor emission characteristics.

Asymmetric total synthesis strategies of halichlorine and pinnaic acid.

Halichlorine and pinnaic acid are structurally related natural alkaloids isolated from different marine organisms. These two marine alkaloids bearing a 6-azaspiro[4.5]decane skeleton demonstrate a wide range of biological effects. It is this kind of unique structure and potentially valuable biological activity that have prompted strong synthetic interest, making it a research focus in recent years. Since the first total synthesis of halichlorine and pinnaic acid completed by Danishefsky's group, many groups have reported their outstanding synthesis methods especially the asymmetric synthesis strategies. This review summarizes the asymmetric synthesis strategies of halichlorine and pinnaic acid using a 6-azaspiro[4.5]decane skeleton as the key intermediate, which can provide some guidance for related work.

Improving cement production process with data-augmented sequence to sequence-Wasserstein generative adversarial networks model for accurate prediction of f-CaO.

This paper proposes a method to address the issue of insufficient capture of temporal dependencies in cement production processes, which is based on a data-augmented Seq2Seq-WGAN (Sequence to Sequence-Wasserstein Generate Adversarial Network) model. Considering the existence of various temporal scales in cement production processes, we use WGAN to generate a large amount of f-CaO label data and employ Seq2Seq to solve the problem of unequal length input-output sequences. We use the unlabeled relevant variable data as the input to the encoder of the Seq2Seq-WGAN model and use the generated labels as the input to the decoder, thus fully exploring the temporal dependency relationships between input and output variables. We use the hidden vector containing the temporal characteristics of cement produced by the encoder as the initial state of the gate recurrent unit in the decoder to achieve accurate prediction of key points and continuous time. The experimental results show that the Seq2Seq-WGAN model can achieve accurate prediction of continuous time series of free calcium and offer direction for subsequent production planning. This method has high practicality and application prospects, and can provide strong support for the production scheduling of the cement industry.

Paying Comprehensive Attention to the Temperature-Dependent Dual-Channel Excited-State Intramolecular Proton Transfer Mechanism of Fluorescence Ratio Probe BZ-DAM.

The mechanism of fluorescence detection of diethyl chlorophosphate (DCP) based on 2-substituted benzothiazole (BZ-DAM) was studied by a theoretical calculation method. It should not be ignored that both the BZ-DAM and the detection product BZ-CHO have two excited-state intramolecular proton transfer (ESIPT) channels. Density functional theory (DFT) and time-dependent DFT (TDDFT) theory were used to study the photophysical mechanism of two compounds in two channels in (acetonitrile) ACN solvent, and the temperature dependence of the two channels was given. Channel 1 is more likely to exist at low temperatures and channel 2 is more likely to exist at high temperatures. By theoretical analysis of the constructed potential energy curve, the hydrogen bond energy and electron-hole analysis, we confirmed that both molecules undergo ESIPT and intramolecular charge transfer (ICT) processes in channel 1 and ESIPT and twisted intramolecular charge transfer (TICT) coupling processes in channel 2. The formation of product BZ-CHO molecules led to a significant fluorescence blue-shift phenomenon and inhibited the ICT process, which confirmed that BZ-DAM could be used as a fluorescence probe for fluorescence detection. We sincerely hope that this work will not only help to clarify the excited-state dynamics behavior of the BZ-DAM probe but also provide a new idea for designing and optimizing a new chemical dosimeter.

La-doped NiWO4 coupled with reduced graphene oxide for effective electrochemical determination of diphenylamine.

Diphenylamine (DPA) is a harmful pesticide widely used to control post-harvest scald of fruits. In this study, rapid and sensitive determination of DPA was realized by the development of an effective electrochemical sensor, which was fabricated by coupling La-doped NiWO4 nanoparticles (La/NiWO4) with reduced graphene oxide (rGO), and the obtained rGO/La/NiWO4 nanocomposite was modified on glassy carbon electrodes (GCEs). The morphologies, structures and compositions were well characterized, and the effects of La doping and the introduction of rGO on the crystal structure and electrochemical performance were discussed. The incorporation of both La and rGO was found to enhance the active surface area and improve conductivity, resulting in the enhanced electrocatalytic performance of rGO/La/NiWO4/GCE, including a wide linear range (0.01-500 µM), a low detection limit (0.0058 µM) and high sensitivity (1.778 µA µM-1 cm-2). The fabricated sensor was further used for DPA detection in fresh apple extract to evaluate its practicality and demonstrated excellent recoveries ranging from 99.52 to 104.70%.

Experimental Study on the Influence of Pore Structure and Group Evolution on Spontaneous Combustion Characteristics of Coal Samples of Different Sizes During Immersion.

To study the influence of water immersion on the evolution of the groups and spontaneous combustion characteristics of coal samples with different sizes, raw coal from the Fengshuigou Coal Mine operated by Pingzhuang Coal Company in Inner Mongolia was studied. The infrared structural parameters, combustion characteristic parameters, and oxidation reaction kinetics parameters of D1-D5 water immersion coal samples were tested, and the mechanism of spontaneous combustion during the oxidation of submerged crushed coal was investigated. The results were as follows. The water immersion process promoted the re-development of coal pore structure, and the micropore volume and average pore diameter were 1.87-2.58 and 1.02-1.13 times those of raw coal, respectively. The smaller the coal sample sizes, the more significant the change. At the same time, the water immersion process increased the contact point between the active group and oxygen in the coal, and the C=O, C-O, and -CH3/-CH2- groups in coal were further promoted to react with oxygen to generate -OH functional groups and improve the reactivity of coal. The characteristic temperature of water immersion coal was affected by the temperature rise rate, coal sample size, coal voidage, and other factors. Compared with the raw coal, the average activation energy of the water immersion coal with different sizes decreased by 12.4-19.7%, and the apparent activation energy of the coal sample with a size of 60-120 mesh was the lowest on the whole. In addition, the apparent activation energy in the low-temperature oxidation stage was significantly different.

Phosphate-modified cobalt silicate hydroxide with improved oxygen evolution reaction.

Oxygen Evolution Reaction (OER) has gained significant attention due to its crucial role in renewable energy systems. The quest for efficient and low-cost OER catalysts remains a challenge of significant interest and importance. In this work, phosphate-incorporated cobalt silicate hydroxide (denoted as CoSi-P) is reported as a potential electrocatalyst for OER. The researchers first synthesized hollow spheres of cobalt silicate hydroxide Co3(Si2O5)2(OH)2 (denoted as CoSi) using SiO2 spheres as a template through a facile hydrothermal method. Phosphate (PO43-) was then introduced to layered CoSi, leading to the reconstruction of the hollow spheres into sheet-like architectures. As expected, the resulting CoSi-P electrocatalyst demonstrated low overpotential (309 mV at 10 mA·cm-2), large electrochemical active surface area (ECSA), and low Tafel slope. These parameters outperform CoSi hollow spheres and cobaltous phosphate (denoted as CoPO). Moreover, the catalytic performance achieved at 10 mA cm-2 is comparable or even better than that of most transition metal silicates/oxides/hydroxides. The findings indicate that the incorporation of phosphate into the structure of CoSi can enhance its OER performance. This study not only provides a non-noble metal catalyst CoSi-P but also demonstrates that the incorporation of phosphates into transition metal silicates (TMSs) offers a promising strategy for the design of robust, high-efficiency, and low-cost OER catalysts.

Vanadate ion promoting the transformation of α-phase molybdenum trioxide (α-MoO3) to h-phase MoO3 (h-MoO3) for boosted Zn-ion storage.

Molybdenum trioxide (MoO3) has been widely studied in the energy storage field due to its various phase states and unique structural advantages. Among them, lamellar α-phase MoO3 (α-MoO3) and tunnel-like h-phase MoO3 (h-MoO3) have attracted much attention. In this study, we demonstrate that vanadate ion (VO3-) can transform α-MoO3 (a thermodynamically stable phase) to h-MoO3 (a metastable phase) by altering the connection of [MoO6] octahedra configurations. h-MoO3 with VO3- inserted (referred to as h-MoO3-V) as the cathode material for aqueous zinc ion batteries (AZIBs) exhibits excellent Zn2+ storage performances. The improvement in electrochemical properties is attributed to the open tunneling structure of the h-MoO3-V, which offers more active sites for Zn2+ (de)intercalation and diffusion. As expected, the Zn//h-MoO3-V battery delivers specific capacity of 250 mAh·g-1 at 0.1 A·g-1 and rate capability (73% retention from 0.1 to 1 A·g-1, 80 cycles), well exceeding those of Zn//h-MoO3 and Zn//α-MoO3 batteries. This study demonstrates that the tunneling structure of h-MoO3 can be modulated by VO3- to enhance the electrochemical properties for AZIBs. Furthermore, it provides valuable insights for the synthesis, development and future applications of h-MoO3.

Facile production of low-viscosity mung bean starch through cold plasma treatment: Improvement of film formability.

Mung bean starch (MBS) has a strong potential to be used as food packages. However, preparing tough and uniform MBS films via industrial casting remains challenging due to the high viscosity of MBS slurry. Herein, MBS was modified by using dielectric barrier discharge cold plasma (CP) in an attempt to decrease its viscosity and improve the film-forming properties. Results indicated that CP with an applied power of 120 W for 5 min decreased the peaking viscosity of MBS slurry from 2936.5 to 466.3 cP. Moreover, CP treatment simultaneously modified the crystallinity (20.2%-16.7%), amylose content (30.5%-44.3%), and short-range orders (1.04-0.85). CP also broke the protective envelope of MBS granules. Further, the film-forming properties of MBS were investigated. It was observed that CP-modified MBS film casts exhibited uniform morphology, higher tensile strength (6.6-9.6 MPa), and improved thermal stability (89.0-100.8°C) compared with the untreated MBS film. The study indicates that the CP can be used as a green and facile technology to improve the properties of MBS films resulting in an efficient food packing material.

ABA and SA Participate in the Regulation of Terpenoid Metabolic Flux Induced by Low-Temperature within Conyza blinii.

Under dry-hot valley climates, Conyza blinii (also known as Jin Long Dan Cao), suffers from nocturnal low-temperature stress (LTS) during winter. Here, to investigate the biological significance of terpenoid metabolism during LTS adaptation, the growth state and terpenoid content of C. blinii under different LTS were detected, and analyzed with the changes in phytohormone. When subjected to LTS, the results demonstrated that the growth activity of C. blinii was severely suppressed, while the metabolism activity was smoothly stimulated. Meanwhile, the fluctuation in phytohormone content exhibited three different physiological stages, which are considered the stress response, signal amplification, and stress adaptation. Furthermore, drastic changes occurred in the distribution and accumulation of terpenoids, such as blinin (diterpenoids from MEP) accumulating specifically in leaves and oleanolic acid (triterpenoids from MVA) accumulating evenly and globally. The gene expression of MEP and MVA signal transduction pathways also changes under LTS. In addition, a pharmacological study showed that it may be the ABA-SA crosstalk driven by the LTS signal, that balances the metabolic flux in the MVA and MEP pathways in an individual manner. In summary, this study reveals the different standpoints of ABA and SA, and provides a research foundation for the optimization of the regulation of terpenoid metabolic flux within C. blinii.

Cold plasma treatment with alginate oligosaccharide improves the digestive stability and bioavailability of nutrient-delivered particles: An in vitro INFOGEST gastrointestinal study.

To improve the stability and bioavailability of the delivered hydrophobic nutrients, the zein-based delivery system was modified by alginate oligosaccharide (AOS), cold plasma (CP) treatments, and synergistically. The digestive behavior of each was investigated in an INFOGEST static in vitro digestion model. The results showed that AOS and CP treatments and their synergistic effects improved the dispersion and stability of the delivery system, leading to a more concentrated particle size distribution and higher particle surface charge. Both CP treatments and AOS increased the release rate of Curcumin (Cur) at small intestine (11.8 % to 20.5 % and 11.8 % to 24.64 %, respectively), and the synergistic effect was higher (11.8 % to 43.84 %). The wall material modified showed a higher encapsulation efficiency of Cur (52.83 % to 85.17 %). Cur release rate measurements showed that the wall material modified could have a positive effect on the slow release of Cur. SDS-page electrophoresis revealed that the slow release was due to the enhanced resistance of wall material to digestive fluids. Thus, treatment with AOS and CP treatments, and the synergism are suitable for modifying zein-based delivery systems for the encapsulation, stabilization, and slow release of hydrophobic nutrients during digestion in the field of functional foods.

Oriented Assembled Prussian Blue Analogue Framework for Confined Catalytic Decomposition of Ammonium Perchlorate.

The design of highly dispersed active sites of hollow materials and unique contact behavior with the components to be catalyzed provide infinite possibilities for exploring the limits of catalyst capacity. In this study, the synthesis strategy of highly open 3-dimensional frame structure Prussian blue analogues (CoFe-PBA) was explored through structure self-transformation, which was jointly guided by template mediated epitaxial growth, restricted assembly and directional assembly. Additionally, good application prospect of CoFe-PBA as combustion catalyst was discussed. The results show that unexpected thermal decomposition behavior can be achieved by limiting AP(ammonium perchlorate) to the framework of CoFe-PBA. The high temperature decomposition stage of AP can be advanced to 283.6 °C and the weight loss rate can reach 390.03% min-1 . In-situ monitoring shows that CoFe-PBA can accelerate the formation of NO and NO2 . The calculation of reaction kinetics proved that catalytic process was realized by increasing the nucleation factor. On this basis, the catalytic mechanism of CoFe-PBA on the thermal decomposition of AP was discussed, and the possible interaction process between AP and CoFe-PBA during heating was proposed. At the same time, another interesting functional behavior to prevent AP from caking was discussed.

VoxelTrack: Multi-Person 3D Human Pose Estimation and Tracking in the Wild.

We present VoxelTrack for multi-person 3D pose estimation and tracking from a few cameras which are separated by wide baselines. It employs a multi-branch network to jointly estimate 3D poses and re-identification (Re-ID) features for all people in the environment. In contrast to previous efforts which require to establish cross-view correspondence based on noisy 2D pose estimates, it directly estimates and tracks 3D poses from a 3D voxel-based representation constructed from multi-view images. We first discretize the 3D space by regular voxels and compute a feature vector for each voxel by averaging the body joint heatmaps that are inversely projected from all views. We estimate 3D poses from the voxel representation by predicting whether each voxel contains a particular body joint. Similarly, a Re-ID feature is computed for each voxel which is used to track the estimated 3D poses over time. The main advantage of the approach is that it avoids making any hard decisions based on individual images. The approach can robustly estimate and track 3D poses even when people are severely occluded in some cameras. It outperforms the state-of-the-art methods by a large margin on four public datasets including Shelf, Campus, Human3.6 M and CMU Panoptic.