Fabrication of novel bio-adsorbent and its application for the removal of Cu(II) from aqueous solution.

As eco-friendly adsorption material, hydroxyapatite (Ca5(PO4)3OH, HA) has been extensively applied to the removal of heavy metal ions. However, separating and recovering of HA powder after the adsorption process limits their application. Alginate-based composite beads (HCA) encapsulated with HA and cellulose were designed to remove Cu(II) from aqueous solution. Fourier-transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), scanning electron microscopy (SEM), and X-ray photoelectron spectroscopy (XPS) were used for characteristic analysis. An extensive discussion in terms of HCA adsorption capacity, effect of various Cu(II) concentration, and analysis of the involved mechanisms of Cu(II) removal on the biosorption. HCA beads showed that the maximum adsorption capacity for Cu(II) of 64.14 mg/g at pH = 5 with 8 h contact time. The Langmuir adsorption isotherm and second-order kinetic model gave the closest fit. HCA beads display good regeneration ability after four cycles and offer potentiality for practical application.

Dual-functional calcium alginate hydrogel beads for disinfection control and removal of dyes in water.

For the decontamination of both pathogenic microorganism and toxic dye from wastewater, new type of materials should be exploited to fabricate more cost-effective, eco-friendly biosorbent. Herein, a promising hydrogel beads based on the incorporation of nano­silver/diatomite into calcium alginate (named as Ag-DE@CAH) was designed to disinfect water and remove methylene blue (MB). Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), Scanning electron microscopy (SEM), and Transmission electron microscopy (TEM), etc. were utilized for characterization analysis. Compared with nano­silver/diatomite (Ag-DE), the novel Ag-DE@CAH beads displayed a better sustained release profile for Ag+, and it noteworthy that the concentration of Ag+ in aqueous media is below the limit of the World Health Organization (WHO) standard (100 ppb) for a 30-days release experiment. It was found that Ag-DE@CAH beads exhibited better disinfection ability towards Escherichia coli (E. coli) than Staphylococcus aureus (S. aureus), and the maximum adsorption capacities of Ag-DE@CAH for MB was 128.21 mg/g. In addition, the as-prepared Ag-DE@CAH beads showed superior and reusable performance in the process of adsorption experiments for MB. Overall, the study indicates that the materials with both excellent disinfection and adsorption properties have potential application prospects for water purification.