A novel UV, moisture and magnetic field triple-response smart insulating material achieving highly targeted self-healing based on nano-functionalized microcapsules.

During the long-term operation of solid insulation materials, strong electric fields and mechanical stress cause electrical trees and cracks that are undetectable and irreversible, leading to the failure of electronic and electrical devices. A promising means of protecting against these problems is to endow the insulating materials with some self-healing capability alongside their excellent intrinsic properties. However, this has proved extremely challenging. In this paper, we describe an ultraviolet light, moisture, and magnetic field triple-response microcapsule that enables epoxy resin materials to heal themselves against various forms of damage without affecting the intrinsic performance of the matrix. In particular, microcapsules wrapped inside functional shells containing Fe3O4 nanoparticles are precisely controlled by a targeted magnetic field and distributed in the vulnerable area of the insulation materials, resulting in a high healing rate at low doping concentrations. Using the in situ ultraviolet light emitted by the electrical trees, artificial ultraviolet light, and moisture in the operating environment, it is possible to induce active or passive curing of the healing agent, thus realizing the intelligent, non-contact, and targeted self-healing of mechanical cracks and electrical tree damage. This method opens an avenue toward the development of self-healing insulation materials for electrical and electronic applications.

Novel Smart Insulating Materials Achieving Targeting Self-Healing of Electrical Trees: High Performance, Low Cost, and Eco-Friendliness.

It remains challenging to promptly inhibit and autonomically heal electrical trees inside insulating dielectrics, which are caused by sustained strong electrical fields and substantially shorten electronic device lifetimes and even cause premature failure of electrical equipment. Therefore, we demonstrate a magnetically targeted ultraviolet (UV)-induced polymerization functional microcapsule (MTUF-MC) to endow insulating materials with physical and electrical dual-damage self-healing capabilities. Specifically, Fe3O4@SiO2 and TiO2 nanoparticles, which serve as magnetic targets and UV shields (thereby preventing the healing agent from prematurely triggering), constitute a functional microcapsule shell, ensuring a low dopant concentration and excellent self-healing ability of the epoxy composites without affecting the intrinsic performance of the matrix. By exploiting in situ electroluminescence originating from electrical trees, UV-induced polymerization of healing agent is handily triggered without any applying external stimuli to intelligently, contactlessly, and autonomously self-healing electrical trees inside insulating dielectrics.