Microwave-assisted preparation of cotton stem-derived activated carbon for dye removal from synthetic wastewater.

Cotton stem is used to produce the high-efficient adsorbent (CSA) for Rhodamine B (RB) dye removal from wastewater, and hydrogen rich fuel gas via on-pot method using microwave heating. The adsorption data indicate that RB adsorption behavior follows the Langmuir model with the maximum adsorption capacity of 265.96 mg/g, whereas the adsorption kinetics follows the pseudo-second-order model. Thermodynamic calculations indicate that RB adsorption on CSA is spontaneous and endothermic process. The adsorption data are fitted to the Thomas and Yoon-Nelson model to predict the breakthrough curve in the column experiment. The RB removal could still be maintained at 71.22% of the original value after five cycles, demonstrating the reusability of CSA. The chemical functional groups, electrostatic interaction, and pore filling of CSA are found to be responsible for high RB adsorption capability. CSA exhibits excellent RB removal efficiency in treating actual water. The major components of byproduct gases collected from activation process are H2 and CO.

High-efficiency removal of lead/cadmium from wastewater by MgO modified biochar derived from crofton weed.

The adsorption performance and mechanisms of Pb2+ and Cd2+ in wastewater using MgO modified biochar derived from crofton weed (MBCW600) are investigated. The Pb2+ and Cd2+ adsorption capacities of MBCW600 by the Hill model reach 384.08 mg/g and 207.02 mg/g, respectively, which is larger than that of original biochar. Pb2+ could be more easily captured by MBCW600 compared to Cd2+ in the multimetal system. Mg2+ contributes to Pb2+ and Cd2+ adsorption among coexisting cations. The exhausted MBCW600 could be well regenerated by simple method after use. The adsorption mechanism study indicates that Pb2+ and Cd2+ removal are primary contributed to mineral precipitation and ion exchange. The effective treatment volumes of Pb2+ and Cd2+ wastewater achieve 3050 mL and 2150 mL in the fixed-bed column experiment, respectively. Therefore, MBCW600 presents remarkable adsorption capability, excellent recoverability and large throughput, which shows the potential application in future treatment of wastewater containing heavy metal.