Preparation and application of acidified/calcined red mud catalyst for catalytic degradation of butyl xanthate in Fenton-like process.

Acidified/calcined red mud (ACRM), a novel catalyst used in Fenton-like process, was prepared by acidification and calcination of red mud (RM). Catalyst characterization showed that iron phase of ACRM was mainly α-Fe2O3 and ACRM was a porous material with rough surface and loose structure. Degradation of butyl xanthate in Fenton-like process catalyzed by ACRM was investigated. Butyl xanthate was effectively degraded, and the degradation of butyl xanthate was well fitted by second order kinetic model. ACRM had an excellent long-term stability in a Fenton-like process. The possible mechanisms of hydroxyl radical production and butyl xanthate degradation in a Fenton-like process catalyzed by ACRM were presented.

Performance investigation of an integrated Young interferometer sensor using a novel prism-chamber assembly.

A novel prism-chamber assembly was prepared for application in optical waveguide based chemical and biological sensors, making the sensor easily and reproducibly operate. By using the prism-chamber assembly, the performance of a composite waveguide based integrated Young interferometer sensor was investigated. The temporal interference pattern detected with a single-slit photodetector heavily relies on the slit width, and regular high-contrast patterns can be obtained under the condition that the slit width is smaller than the spatial periodicity of the sensor. Increasing the temperature of water in the chamber leads to a quasi-linear variation in the phase difference with Deltaphi/DeltaT approximately -9.1 degrees/degrees C. Significant dependence of the sensor's sensitivity on the polarization state of the guided mode was also observed. The sensor is stable and reliable, capable of real-time detection of very slow bioreactions at the interface.

Integrated Young interferometer sensor with a channel-planar composite waveguide sensing arm.

A simple integrated Young interferometer sensor was prepared on a glass substrate with a pair of single-mode straight channel waveguides 75 microm apart. A tapered thin film of TiO2 was locally deposited on one channel to form a composite waveguide sensing arm with a greatly enhanced evanescent field. With the prism-coupling method a single beam of laser light was simultaneously launched into the two channels to yield a high-contrast interference pattern. Refractive-index sensitivity of the interferometer and its response to protein adsorption were investigated by using a slit-photodetector assembly to interrogate the sensor signal. The factors affecting the fringe contrast were analyzed.

[Freeze-dried allograft of posterior spinal fusion in patients with scoliosis].

OBJECTIVE: To observe the effectiveness and safety of allograft in posterior spinal fusion in patients with scoliosis. METHODS: 41 cases of 54 scoliosis patients with allograft for spinal fusion were followed up. The mean follow-up time is 16 months. Foreign body reaction was studied clinically and fusion status was assessed radiographically. RESULTS: There was no foreign body reaction significantly in all patients. Acute deep wound infection happened in one patient and no chronic deep wound infection occurred. There was no disease transferred by allograft in followed patients. New bone formation appeared after 4 months postoperatively in radiogram. At final follow-up, the mean angle of 3.4 degrees lost and minimal -1 degrees and maximal 6 degrees . Implants were fastened and did not loosen and fracture. CONCLUSIONS: Allograft for posterior spinal fusion in scoliosis patients was useful and safe.