ABSTRACT
Circularly polarized luminescence (CPL) is one of the critical chiroptical properties for chiral nanomaterials, which exhibit wide potential applications in many research fields. However, it remains a big challenge for real application, limited by their small luminescence dissymmetry factor or low emission intensity. Here, an upconverted near-infrared circularly polarized luminescence (UC-NIR-CPL) system is constructed based on the chiroptical property of chiral liquid crystals, embedding with the lanthanide-doped upconversion nanoparticles. More importantly, a strategy for improving the overall performance of UC-NIR-CPL was proposed and realized by taking advantage of the "dual-band-edge enhancement effect", wherein the glum value was amplified, while the NIR emission intensity showed dual enhancement and the threshold of excitation was decreased. Based on the improved overall performance of the UC-NIR-CPL, which can be used as a distinctive covert light, a kind of photonic barcode with multiple encryptions was realized. These findings will upgrade the level of information encryption through improving the overall performance of CPL-active materials.
ABSTRACT
Chirality, an intrinsic property of nature, has received increased attention in chemistry, biology, and materials science because it can induce optical rotation, ferroelectricity, nonlinear optical response, and other unique properties. Here, by introducing chirality into hybrid rare-earth double perovskites (HREDPs), we successfully designed and synthesized a pair of enantiomeric three-dimensional (3D) HREDPs, [(R)-N-methyl-3-hydroxylquinuclidinium]2RbEu(NO3)6 (R1) and [(S)-N-methyl-3-hydroxylquinuclidinium]2RbEu(NO3)6 (S1), which possess ferroelasticity, multiaxial ferroelectricity, high quantum yields (84.71% and 83.55%, respectively), and long fluorescence lifetimes (5.404 and 5.256 ms, respectively). Notably, the introduction of chirality induces the coupling of multiaxial ferroelectricity and ferroelasticity, which brings about a satisfactory large piezoelectric response (103 and 101 pC N-1 for R1 and S1, respectively). Moreover, in combination with the chirality and outstanding photoluminescence properties, circularly polarized luminescence (CPL) was first realized in HREDPs. This work sheds light on the design strategy of molecule-based materials with a large piezoelectric response and excellent CPL activity, and will inspire researchers to further explore the role of chirality in the construction of novel multifunctional materials.
ABSTRACT
Flexible organic crystals with unique mechanical properties and excellent optical properties are of paramount significance for their wide applications in various research fields such as adaptive optics and soft robotics. However, low-temperature-resistant flexible organic crystal with circularly polarized luminescence (CPL) has never been reported. Herein, chiral organic crystals with CPL activity and low-temperature flexibility (77â K) are fabricated by the solvent diffusion method from chiral Schiff base, S(R)-4-bromo-2-(((1-phenylethyl)imino)methyl)phenol (S(R)-BPEMP). The corresponding chirooptical properties for the two enantiomeric crystals were thoroughly investigated, including the measurements of circular dichroism (CD) and CPL. To the best of our knowledge, this is the first report on low-molecular-weight flexible organic crystals with CPL activity, and we believe that the results will give a new impetus to the research of organic crystals.
ABSTRACT
Correction for 'Circularly polarized luminescent porous crystalline nanomaterials' by Anyi Zheng et al., Nanoscale, 2022, 14, 1123-1135, DOI: 10.1039/D1NR07069J.
ABSTRACT
Circularly polarized luminescence (CPL)-active materials have attracted exclusive attention because of their wide potential applications in low-power-consumption displays, encrypted information storage, chiroptical sensors, and so on. However, there is always a trade-off between the luminescence dissymmetry factor (glum) and luminescence quantum yield, which are two critical parameters. Therefore, developing materials with both large glum values and high luminescence efficiency is a key issue for constructing high-efficiency CPL materials. To date, chiral porous crystalline nanomaterials (PCNMs) including metal-organic frameworks (MOFs), porous organic-cages (POCs), metal-organic cages (MOCs), and supramolecular organic frameworks (SOFs), have shown excellent potential for solving this problem and achieving functional CPL-active materials. In this review, we will summarize several approaches for fabricating CPL-active PCNMs, such as direct synthesis, chirality induction, and symmetry breaking. Furthermore, with flexibly tunable structures and comprehensive host-guest chemistry, modulation and amplification of CPL can be achieved in these PCNMs. We would like to provide insight and perspective that PCNMs can act as an efficient platform in the CPL research field.
