Driving factors influencing spatiotemporal variation of natural organic chlorine in Shennongjia forest soil.

Studying the geochemical behavior of chlorine is the basis of understanding the chlorine cycle in nature. To explore the spatiotemporal distribution of natural organic chlorine (Clorg), L layer (litter fall), F-H layer (humification zone), topsoil layer (0-20 cm), and deep soil layer (20-40 cm) samples were collected from 18 sampling sites at different altitudes (851-2918 m) in Shennongjia Forest in May, August, and December. Clorg content was analyzed, and the Clorg stocks were calculated. The major factors affecting the distribution of Clorg were explored. The results revealed that the sum of Clorg content in four layers varied from 7.958 to 184.686 mg/kg, and the highest value was observed in August. Clorg accounted for 46%-77% of total chlorine, with the highest mean ratio in soil layer (0-20 cm). Clorg content exhibited the following trend: F-H layer > L layer > topsoil layer (0-20 cm) > deep soil layer (20-40 cm). The seasonal patterns of Clorg in soil layers were different from that in L and F-H layers, which were mainly controlled by the content and humification degree of organic matter. Clorg storage was much higher in soil layers (61-246 kg/ha) than those in F-H layer (1.1-7.1 kg/ha) and in L layer (0.1-0.8 kg/ha) because of the large thickness of the soil layers. Overall, the Clorg content exhibited an increasing trend with altitude, except at an altitude of approximately 1800 m. Clorg content in L and F-H layers varied more obviously with altitude than that in soil layers. When inorganic chlorine (Clin) was not a limiting factor for the chlorination process, Clorg content in L and F-H layers was significantly affected by climate and organic matter controlled by altitude, while Clorg content in soil layers was also mediated by metal ions and pH, and soil particle size. This study could provide a scientific basis for assessing the chlorine cycle in nature.

Health risks associated with multiple metal(loid)s in groundwater: A case study at Hetao Plain, northern China.

To compare the health risks of multiple metal(loid)s in groundwater, and discuss the feasibility of drinking water standards, 66 groundwater samples were collected from the Hetao Plain in October 2017. Eighteen metal(loid) species (boron (B), manganese (Mn), iron (Fe), strontium (Sr), barium (Ba), lithium (Li), scandium (Sc), titanium (Ti), vanadium (V), cobalt (Co), nickel (Ni), copper (Cu), zinc (Zn), arsenic (As), selenium (Se), rubidium (Rb), molybdenum (Mo), uranium (U)) were analyzed, and the related non-carcinogenic risks were assessed. The results showed that 83.3% of the groundwater samples had As and Fe contents above the maximum allowed contaminant levels (MCLs) in drinking water standards, followed by Mn (70.2%), B (65.2%), Se (60.6%), U (18.2%), Ni (18.2%) and Mo (1.50%). Compared with the dermal exposure pathway, oral ingestion made a risk contribution of more than 99% for all target metal(loid)s. Site-specific hazard quotient (HQ) values ranged from 2.30E+00 to 1.75E+02, indicating that multiple metal(loid)s in the drinking groundwater cause a serious non-carcinogenic risk to the local people. The risk contributions (mean value) were ranked as As (55.2%) > U (25.5%) > Li (10.8%) > other total metal(loid)s (8.60%), and the contributions of U and Li could reach 91.7% (site 20) and 69.8% (site 56), respectively. The calculation of specific health risks further indicated that the MCLs of metal(loid)s do not match the corresponding health risk well. Some metal(loid)s such as Li that showed high exposure risks in this study, still have no MCL values until now. Therefore, current drinking water standards need to be updated.