ABSTRACT
Due to the high surface area and uniform porosity of covalent organic frameworks (COFs), they exhibit superior properties in capturing and detecting even trace amounts of gases in the air. However, the COFs materials that possess dual detected functionality are still less reported. Here, an imine-based COF containing thiophene as a donor and triazine as an acceptor to form spatial-distribution-defined D-A structures was prepared. D-A system between thiophene and triazine facilitates the charge transfer process during the protonation process of the imine and the triazine units. The obtained COF exhibits simultaneous sensing ability toward both acidic and alkaline vapors with obvious colorimetric sensing functionality.
ABSTRACT
Two imine-based 2D covalent organic frameworks (COFs) with slight differences in their core structures are presented. The COF containing benzotrithiophene moieties with better planarity and π-conjugation (BTTh-TZ-COF) shows much better photocatalytic activity than the COF with trithienylbenzene cores (TThB-TZ-COF). Further photoelectrochemical study reveals the catalytic mechanism in more detail. Since other factors such as crystallinity, porosity, and optical bandgaps are equal, the different structures of the cores in the two similar COFs are the major contributors to the significantly different photocatalytic performance. The better electron delocalization of the planar trithiophene-based core and the enhanced D-A interactions between the triazine and trithiophene units in BTTh-TZ-COF create efficient charge separation and transfer, thus leading to superior photocatalytic hydrogen evolution activity. A new strategy for preparing high-performance organic photocatalysts for solar-energy conversion is revealed by this study.
