ABSTRACT
Two-dimensional (2D) 1H molybdenum disulfide (1H-MoS2) is hard to be directly used in energy storage devices due to its inert basal plane and unfavorable 2D stacking. This work demonstrated how the basal plane of 1H MoS2nanocrystals (NCs) can be activated to offer doubled specific capacitance by simple surface S depletions. Building on the expanded graphene with three-dimensional (3D) structures, as-prepared NCs were chemically grafted on the graphene surface to deliver stable energy storage and high capacitance, which overcame above challenges of 1H-MoS2. Aside from the mostly focused metastable phase, this work confirmed that the stable 1H Mo-S material is also promising in energy storage applications.
ABSTRACT
To develop ideal alternatives to noble metal catalysts, transition metal catalysts supported on graphene have been receiving extensive attention in the field of electrochemical energy. In this work, using graphene oxide (GO) and nickel formate as precursors, Ni/NiO synergistic nanoparticles with regulable composition are anchored on reduced graphene oxide (RGO) to prepare Ni/NiO/RGO composite electrocatalysts through in-situ autoredox. Thanks to the synergistic effect of Ni3+ active sites and Ni electron donors, the as-prepared Ni/NiO/RGO catalysts exhibit efficient electrocatalytic oxygen evolution performance in 1.0 M KOH electrolyte. The optimal sample has an overpotential of only 275 mV at a current density of 10 mA cm-2 and a small Tafel slope of 90 mV dec-1, which are very comparable to those of commercial RuO2 catalyst. Additionally, the catalytic capacity and structure remain stable after 2000 cyclic voltammetry cycles. For the electrolytic cell assembled with the best-performing sample as anode and commercial Pt/C as cathode, the current density can reach 10 mA cm-2 at a low potential of 1.57 V and remains stable after 30 h of continuous work. It would be expected that the as-developed Ni/NiO/RGO catalyst with high activity should have broad application prospects.
