ABSTRACT
Fe-Cu-Co prealloyed powder is used for bonding metal of diamond tools. In order to obtain diamond tools with good mechanical properties by pressureless sintering, it is necessary to add Cu-Sn sintering aids. The substrate also has high corrosion resistance requirements, which is conducive to the chemical erosion of diamond tools. This paper mainly studies the effects of Cu-Sn on the corrosion behavior of pressureless sintered Fe-Cu-Co substrate. The results show that the linear contraction rate and relative density of pressureless sintered Fe-Cu-Co alloy at 875 °C reach their peak when the Cu-Sn content is 8 wt.%, 15.13% and 97.5%, respectively. The substrate is mainly composed of α-Fe and Cu-rich phases, and selective corrosion occurs during electrochemical corrosion; namely, α-Fe grains are more prone to corrosion than Cu-rich grains to form porous corrosion surfaces. With the increase in Cu-Sn addition, the volume fraction of the Cu-rich phase increases, the corrosion current density and the passive current density gradually decrease, and the corrosion resistance of the alloy is improved. The amount and integrity of anodic passive film on the Fe-Cu-Co surface increases with the increase in Cu-Sn addition. The oxygen content of the anodic passivation film is lower than that of the active corrosion products of the α-Fe phase, thus reducing the oxygen concentration gradient and slowing down the corrosion. The addition of Cu-Sn is conducive to improving the corrosion resistance of Fe-Cu-Co alloy as the substrate of diamond tools.
ABSTRACT
TiC-high Mn steel-bonded carbide with a cellular structure was designed and fabricated by powder metallurgy techniques using coarse and fine TiC particles as the hard phase. This preparation process of the alloy was designed carefully and optimized. The microstructure of the alloy was observed using a scanning electron microscope. The results show that there are two types of microstructures observed in this TiC steel-bonded carbide: the coarse-grained TiC structure and fine-grained TiC structure. The transverse rupture strength and impact toughness of the alloy reach maximum values 2231 MPa and 12.87 J/cm2, respectively, when the starting weight ratio of MP-A (containing coarse TiC particles) to MP-B (containing fine TiC particles) is 60:40. Hence, this study serves as a feasible and economical example to prepare a high-strength and high-toughness TiC-high Mn steel-bonded carbide with little production cost increase.
