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1.
Acta Crystallogr Sect E Struct Rep Online ; 68(Pt 8): o2325, 2012 Aug 01.
Article in English | MEDLINE | ID: mdl-22904797

ABSTRACT

In the title compound, C(11)H(8)F(2)N(2)O(2)·0.5H(2)O, the dihedral angle between the benzene and isoxazole rings is 8.08 (3)°. In the crystal, the components are linked by O-H⋯N and N-H⋯O hydrogen bonds, in which the water mol-ecule acts as both a donor and an acceptor, into a tape with an R(4) (4)(16) graph-set motif along the a axis. The water mol-ecule is located on a twofold rotation axis. The methyl H atoms were treated as disordered groups over two sites with a refined site-occupancy ratio of 0.48 (6):0.52 (6).

2.
Acta Crystallogr Sect E Struct Rep Online ; 68(Pt 5): o1450, 2012 May 01.
Article in English | MEDLINE | ID: mdl-22590329

ABSTRACT

In the title compound, C(12)H(9)F(3)N(2)O(2), the benzene ring is nearly perpendicular to the isoxazole ring, making a dihedral angle of 82.97 (2)°. In the crystal, mol-ecules are linked by N-H⋯O hydrogen bonds into a supra-molecular chain running along the c axis.

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