ABSTRACT
Photocatalytic reduction of CO2 to chemical fuels is attractive for solving both the greenhouse effect and the energy crisis, but the key challenge is to design and synthesize photocatalysts with remarkable performance under visible light irradiation. Efficient catalytic carbon dioxide reduction (CO2RR) with light is considered a promising sustainable and clean approach to solve environmental problems. Herein, we found a new photocatalyst ([Mn(en)2]6[V12B18O54(OH)6]) (abbreviated as Mn6V12) based on the modifiability of polyoxometalates, in which Mn acts as a modifying unit to efficiently reduce CO2 to CO and effectively inhibit the hydrogen precipitation reaction. This Mn modified polyoxometalate catalyst has a maximum CO generation rate of 4625.0 µmol g-1 h-1 and a maximum H2 generation rate of 499.6 µmol g-1 h-1, with a selectivity of 90.3% for CO generation and 9.7% for H2 generation. This polyoxometalate photocatalyst can effectively reduce CO and inhibit the hydrogen precipitation reaction. It provides a new idea for the efficient photocatalytic carbon dioxide reduction (CO2RR) with polyoxometalate catalysts.
