Sulphur-Boosted Active Hydrogen on Copper for Enhanced Electrocatalytic Nitrate-to-Ammonia Selectivity.

Electrocatalytic nitrate reduction to ammonia is a promising approach in term of pollutant appreciation. Cu-based catalysts performs a leading-edge advantage for nitrate reduction due to its favorable adsorption with *NO3. However, the formation of active hydrogen (*H) on Cu surface is difficult and insufficient, leading to the significant generation of by-product NO2 -. Herein, sulphur doped Cu (Cu-S) is prepared via an electrochemical conversion strategy and used for nitrate electroreduction. The high Faradaic efficiency (FE) of ammonia (~98.3 %) and an extremely low FE of nitrite (~1.4 %) are achieved on Cu-S, obviously superior to its counterpart of Cu (FENH3: 70.4 %, FENO2 -: 18.8 %). Electrochemical in situ characterizations and theoretical calculations indicate that a small amount of S doping on Cu surface can promote the kinetics of H2O dissociation to active hydrogen. The optimized hydrogen affinity validly decreases the hydrogenation kinetic energy barrier of *NO2, leading to an enhanced NH3 selectivity.

Formamide Electrosynthesis from Methanol and Ammonia in Water over Pr-Doped MnO2.

A rare earth element doping strategy is reported to boost the activity and enhance the stability of MnO2 for selective formamide production through electrocatalytic oxidation coupling (EOC) of methanol and ammonia. MnO2 doped with 1% Pr was selected as the best candidate with an optimized formamide yield of 211.32 µmol cm-2 h-1, a Faradaic efficiency of 22.63%, and a stability of more than 50 h. The easier formation of Mn6+ species and the lower dissolution rate of Mn species over Pr-doped MnO2 revealed by in situ Raman spectra were responsible for the boosted formamide production and enhanced stability. In addition, a two-electrode flow electrolyzer was developed to integrate EOC with C2H2 semihydrogenation for simultaneously producing value-added products in both the anode and cathode.

Variation in cell wall structure and composition of wheat grain based on geography and regulatory effect of cell wall on water mobility.

Wheat grain from 12 different regions in China was used to study variations in the cell wall structure and chemical composition based on geography. The mobility and migration rate of water in wheat grain during moisture absorption and drying were determined under different relative humidity conditions. Depending on the geography, variations were noted in the thickness and component content of the wheat grain cell wall. Cell wall thickness was positively correlated with the total arabinoxylan (TAX) content. Cell wall thickness and TAX content of the aleurone layer were positively correlated with altitude and negatively correlated with longitude. The water migration rate decreased with the increase of cell wall thickness and TAX content. Nuclear magnetic resonance (NMR) results revealed that grains with thick aleurone cell wall showed increased molecular mobility of water. These findings lay the foundation for further study of water regulation in wheat cell wall.

Cloning and function analysis of a drought-inducible gene associated with resistance to Curvularia leaf spot in maize.

ZmDIP was cloned and its function against Curvularia lunata was analyzed, according to a previous finding on a drought-inducible protein in resistant maize identified through MALDI-TOF-MS/MS. The ZmDIP expression varied in roots, leaf sheaths, and young, as well as old, leaves of different maize inbred lines. The ZmDIP transcript level changed in leaves over the course of time after inoculation with C. lunata. A prokaryotic expression analysis demonstrated that the gene can regulate the salt stress tolerance of Escherichia coli. The ZmDIP transient expression in the maize leaf showed that the gene was also linked to leaf resistance against the C. lunata infection. ZmDIP-mediated ROS and ABA signaling pathways were inferred to be closely associated with maize leaf resistance to the pathogen infection.