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Lewis acid promoted carbon-carbon double-bond formation via organozinc reagents and carbonyl compounds.

Peng, Zhi-Yong; Ma, Fang-Fang; Zhu, Lv-Feng; Xie, Xiao-Min; Zhang, Zhaoguo.

J Org Chem ; 74(17): 6855-8, 2009 Sep 04.

Article in English | MEDLINE | ID: mdl-19658428

ABSTRACT

Using cheap and readily available AlCl(3) as Lewis acid, functionalized aldehydes react with organozinc reagents to give (E)-alkenes stereoselectively in high yields.

Subject(s)

Acids/chemistry , Carbon/chemistry , Chemistry, Organic/methods , Ketones/chemistry , Zinc/chemistry , Alcohols/chemistry , Aldehydes/chemistry , Bromides/chemistry , Ethers/chemistry , Lithium/chemistry , Magnesium/chemistry , Metals/chemistry , Models, Chemical , Stereoisomerism , Toluene/chemistry

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