ABSTRACT
Although bright organic mechanoluminescence (ML) has been observed for a few luminophores with aggregation-induced emission (AIE), details of the positive effect of AIE on ML performance remain unclear and a feasible design principle for AIE-ML compounds has not yet been presented. Herein, an effective strategy for the molecular design of efficient AIE-ML materials is demonstrated, based on tetraphenylethene (TPE) building blocks with formyl substituents, which yield non-centrosymmetric crystal structures with prominent piezoelectric properties for molecular excitation combined with AIE features for intense emission. Following this approach, three AIE-active compounds have been developed and are found to show unique ML characteristics. Furthermore, the results of single crystal X-ray analysis and density functional theory (DFT) calculations suggest that the ML performance would probably be further enhanced by creating molecules with larger dipolar moments and enhanced AIE properties.
ABSTRACT
Surface-enhanced Raman scattering (SERS) spectroscopy has found a wide range of applications in biomedicine, food safety and environmental monitoring. However, to date, it is difficult for most SERS substrates to provide an extremely sensitive and highly uniform Raman response simultaneously. Here, we developed a sensitive and uniform SERS sensing strategy based on grating-integrated gold nanograsses (GIGNs), which can amplify the SERS signal up to 10-fold compared to the nanograss without grating (namely on the flat substrate) experimentally. Numerical simulation results show that such an improvement of SERS sensitivity arises from the enhanced hotspots relying on the strong coupling between the localized surface plasmon resonances of individual stripe-regulated gold nanorod assemblies and Wood's anomalies in air and dielectric grating. Importantly, these hotspots on the substrate can be flexibly tailored by adjusting the height and periodicity of the loaded grating. The SERS performances of the GIGNs have further been successfully demonstrated with the label-free detection of adenine and cytosine (DNA bases) molecules at the nanomolar level. Moreover, the GIGNs also presented the uniform spot-to-spot and sample-to-sample SERS signals of the analyte molecules (relative standard deviations down to â¼11% and 13%, respectively). These advantages suggest that our GIGN substrates are of great potential for SERS-related sensing.
ABSTRACT
Optical filters with reconfigurable spectral properties are highly desirable in a wide range of applications. We propose and experimentally demonstrate a tunable submicro-optofluidic polymer guided-mode resonance (PGMR) filter. The device is composed of a periodic grating sandwiched between a high index waveguide layer and a low index capping layer, which integrates submicro-fluidic channel arrays and a PGMR filter elegantly. A finite difference time domain (FDTD) method is employed to understand the spectral properties and determine appropriate device parameters. We fabricated the polymer guided-mode resonance filter with a method combining two-beam interference lithography, floating nanofilm transfer and thermal bonding techniques. Experimental results show that our tunable submicro-optofluidic PGMR filters can provide a broad spectral tuning range (13.181 nm), a narrow bandwidth (<2.504 nm), and a high reflection efficiency (>85%) in the visible region. Such submicro-optofluidic PGMR filters are highly compatible with existing nano/microfluidic technologies and would be valuable for the integrated flexible optical system.
ABSTRACT
Organic materials exhibiting mechanoluminescence (ML) are promising for usage in displays, lighting and sensing. However, the mechanism for ML generation remains unclear, and the light-emitting performance of organic ML materials in the solid state has been severely limited by an aggregation-caused quenching (ACQ) effect. Herein, we present two strongly photoluminescent polymorphs (i.e., Cg and Cb) with distinctly different ML activities based on a tetraphenylethene derivative P4TA. As an aggregation-induced emission (AIE) emitter, P4TA perfectly surmounted the ACQ, making the resultant block-like crystals in the Cg phase exhibit brilliant green ML under daylight at room temperature. The ML-inactive prism-like crystals Cb can also have their ML turned on by transitioning toward Cg with the aid of dichloromethane vapor. Moreover, the Cg polymorph shows ML and mechanochromism simultaneously and respectively without and with UV irradiation under a force stimulus, thus suggesting a feasible design direction for the development of efficient and multifunctional ML materials.
ABSTRACT
We have fabricated gold (Au) elliptical nanodisc (ND) arrays via three-beam interference lithography and electron beam deposition of gold. The enhanced photoluminescence intensity and emission rate of quantum dots (QDs) near to the Au elliptical NDs have been studied by tuning the nearest distance between quantum dots and Au elliptical NDs. We found that the photoluminescence intensity is polarization-dependent with the degree of polarization being equal to that of the light extinction of the Au elliptical NDs, while the emission rate is polarization-independent. This is resulted from the plasmon-coupled emission via the coupling between the QD dipole and the plasmon nano-antenna. Our experiments fully confirm the evidence of the plasmophore concept proposed recently in the interaction of the QDs with metal nanoparticles.
ABSTRACT
We propose theoretically and demonstrate experimentally a dislocated double-layer metal grating structure, which operates as a unidirectional coupler capable of launching surface plasmon polaritons in a desired direction under normal illumination. The structure consists of a slanted dielectric grating sandwiched between two gold gratings. The upper gold grating has a nonzero lateral relative displacement with respect to the lower one. Numerical simulations show that a grating structure with 7 periods can convert 49% of normally incident light into surface plasmons with a contrast ratio of 78 between the powers of the surface plasmons launched in two opposite directions. We explain the unidirectional coupling phenomenon by the dislocation-induced interference of the diffracted waves from the upper and lower gold gratings. Furthermore, we developed a simple and cost-effective technique to fabricate the structure via tilted two-beam interference lithography and subsequent shadow deposition of gold. The experimental results demonstrate a coupling efficiency of 36% and a contrast ratio of 43. The relatively simple periodic nature of our structure lends itself to large-scale low-cost fabrication and simple theoretical analysis. Also, unlike the previous unidirectional couplers based on aperiodic structures, the design parameters of our unidirectional coupler can be determined analytically. Therefore, this structure can be an important component for surface-plasmon-based nanophotonic circuits by providing an efficient interface between free-space and surface plasmon waves.
ABSTRACT
The complicated behaviors of InAs/GaAs quantum dots with increasing V/III ratio associated with several competing mechanisms have been described. The results demonstrate that the densities of InAs quantum dots can be tuned in a wide range from 105 to 1010 cm-2 by simply manipulating V/III ratio via metal-organic chemical vapor deposition. These results are mainly ascribed to the changes of coverage and In adatom migration length due to the increasing V/III ratio.
ABSTRACT
We have proposed an easy and controllable method to prepare highly ordered Au nanoarray by pulse alternating current deposition in anodic aluminum oxide template. Using the ultraviolet-visible-near-infrared region spectrophotometer, finite difference time domain, and Green function method, we experimentally and theoretically investigated the surface plasmon resonance, electric field distribution, and local density of states enhancement of the uniform Au nanoarray system. The time-resolved photoluminescence spectra of quantum dots show that the emission rate increased from 0.0429 to 0.5 ns-1 (10.7 times larger) by the existence of the Au nanoarray. Our findings not only suggest a convenient method for ordered nanoarray growth but also prove the utilization of the Au nanoarray for light emission-manipulating antennas, which can help build various functional plasmonic nanodevices.
ABSTRACT
We developed a method to fabricate a periodic array of three-dimensional crescent-like holes (3DCLH) via an inverted hemispherical colloidal lithography. It is found that there exists an extraordinary optical transmission in this non-planar perforated periodic array of 3DCLH when the electric field of the incident light is perpendicular to the cross-line of the crescent-like hole. This extraordinary optical peak is insensitive with the incident angles and sensitive with the angle between the electric field of the incident light to the cross-line of the 3DCLH. Numerical simulation based on finite-difference time-domain method reveals that this peak is caused by an asymmetric localized surface plasmon resonance. This structure might be useful for the optical sensing and optical-integrated circuits.
ABSTRACT
We developed a method to fabricate an array of silver non-planar nano-arc-gaps via inverted hemispherical colloidal lithography and shadow metal evaporation methods. It is found that there is a localized surface plasmon mode which results in extraordinary optical transmission. The electric field is strongly localized at the nano-arc-gap region and therefore induces a resonance that has an ultra-small mode volume of less than 2.44 × 10(-6) µm(3). The ratio of the quality factor to the mode volume is as high as 1.44 × 10(6) µm(-3). This would be valuable for the design of optoelectric circuits.
