Tailoring the performance of the LiNi0.8Mn0.1Co0.1O2 cathode using Al2O3 and MoO3 artificial cathode electrolyte interphase (CEI) layers through plasma-enhanced atomic layer deposition (PEALD) coating.

The Ni-rich layered oxide cathode has shown high energy density, proper rate capability, and longevity of the rechargeable battery, while poor stability and capacity fading are assumed to be its common cons. To address this obstacle, prospective cathode materials are synthesized by integrating the lithium transition metal oxides with an artificial cathode electrolyte interphase (CEI) layer. Herein, plasma-enhanced atomic layer deposition (PEALD) is employed to coat the LiNi0.8Mn0.1Co0.1O2 (NMC811) electrode with Al2O3 and MoO3. The combined results from morphological examinations revealed the formation of uniform Al2O3 and MoO3 sheets after 200 cycles of PEALD coating. Consistent results from the XRD analysis demonstrate that Al2O3 and MoO3 artificial CEIs can reduce Li-Ni mixing. The cyclic voltammetry tests show the oxidation-reduction kinetic. The modified NMC811 structures with Al2O3 and MoO3 represent a remarkable improvement in terms of capacity retention. The coated cathode with Al2O3 clearly outperforms the modified configuration with MoO3 concerning ionic conductivity, charge/discharge reversibility, and capacity retention. The promising results obtained in this study open the possibility of synthesizing Ni-rich cathodes with enhanced electrochemical performance.

Metal-Organic Framework-Derived ZnO, N Dually Doped Nanocages as an Efficient Host for Stable Li Metal Anodes.

The drastic volume expansion and dendrite growth of lithium metal anodes give rise to poor electrochemical reversibility. Herein, ZnO, N dually doped nanocages (c-ZNCC) were synthesized as the host for lithium metal anodes using the zeolitic imidazolate framework-8 (ZIF-8). The synthesis is based on a two-step core@shell evolution mechanism, which could guide lithium deposition rapidly and offer a fast lithium-ion diffusion during the cycling process. Benefiting from the unique design, the as-obtained c-ZNCC can render a record short lithium infusion as low as 1.5 s, a stable lithium stripping/plating capability as long as 3000 h, and a voltage hysteresis of 95 mV when cycling at 10 mA cm-2 to 10 mA h cm-2. A low Tafel slope of 3.45 mA cm-2 demonstrates the efficient charge transfer of c-ZNCC-Li, and the galvanostatic intermittent titration technique measurement shows high diffusion coefficient of c-ZNCC-Li during the charging process. In addition, the LNMO||c-ZNCC-Li cell exhibits a capacity retention as high as 93.7% at 1 C after 200 cycles. This work creates a new design for deriving nanocages with dual lithiophilic spots using a metal-organic framework and carbon cloth for favorable Li metal anodes.

Super-Resolution Reconstruction of Speckle Images of Engineered Bamboo Based on an Attention-Dense Residual Network.

With the global population surge, the consumption of nonrenewable resources and pollution emissions have reached an alarming level. Engineered bamboo is widely used in construction, mechanical and electrical product packaging, and other industries. Its main damage is the material fracture caused by the expansion of initial cracks. In order to accurately detect the length of crack propagation, digital image correlation technology can be used for calculation. At present, the traditional interpolation method is still used in the reconstruction of engineered bamboo speckle images for digital correlation technology, and the performance is relatively lagging. Therefore, this paper proposes a super-resolution reconstruction method of engineering-bamboo speckle images based on an attention-dense residual network. In this study, the residual network is improved by removing the BN layer, using the L1 loss function, introducing the attention model, and designing an attention-intensive residual block. An image super-resolution model based on the attention-dense residual network is proposed. Finally, the objective evaluation indexes PSNR and SSIM and subjective evaluation index MOS were used to evaluate the performance of the model. The ADRN method was 29.19 dB, 0.938, and 3.19 points in PSNR, SSIM, and MOS values. Compared to the traditional BICUBIC B-spline interpolation method, the speckle images reconstructed by this model increased by 8.55 dB, 0.323, and 1.43 points, respectively. Compared to the SRResNet method, the speckle images reconstructed by this model were increased by 4.53 dB, 0.111, and 0.14 points, respectively. The reconstructed speckle images of engineered bamboo were clearer, and the image features were more obvious, which could better identify the tip crack position of the engineered bamboo. The results show that the super-resolution reconstruction effect of engineered-bamboo speckle images can be effectively improved by adding the attention mechanism to the residual network. This method has great application value.

A Sawn Timber Tree Species Recognition Method Based on AM-SPPResNet.

Sawn timber is an important component material in furniture manufacturing, decoration, construction and other industries. The mechanical properties, surface colors, textures, use and other properties of sawn timber possesed by different tree species are different. In order to meet the needs of reasonable timber use and product quality of sawn timber products, sawn timber must be identified according to tree species to ensure the best use of materials. In this study, an optimized convolution neural network was proposed to process sawn timber image data to identify the tree species of the sawn timber. The spatial pyramid pooling and attention mechanism were used to improve the convolution layer of ResNet101 to extract the feature vector of sawn timber images. The optimized ResNet (simply called "AM-SPPResNet") was used to identify the sawn timber image, and the basic recognition model was obtained. Then, the weight parameters of the feature extraction layer of the basic model were frozen, the full connection layer was removed, and using support vector machine (SVM) and XGBoost classifier which were commonly used in machine learning to train and learn the 21 × 1024 dimension feature vectors extracted by feature extraction layer. Through a number of comparative experiments, it is found that the prediction model using linear function as the kernel function of support vector machine learning the feature vectors extracted from the improved convolution layer performed best, and the F1 score and overall accuracy of all kinds of samples were above 99%. Compared with the traditional methods, the accuracy was improved by up to 12%.

Detection Method for Bolted Connection Looseness at Small Angles of Timber Structures based on Deep Learning.

Bolted connections are widely used in timber structures. Bolt looseness is one of the most important factors leading to structural failure. At present, most of the detection methods for bolt looseness do not achieve a good balance between cost and accuracy. In this paper, the detection method of small angle of bolt loosening in a timber structure is studied using deep learning and machine vision technology. Firstly, three schemes are designed, and the recognition targets are the nut's own specification number, rectangular mark, and circular mark, respectively. The Single Shot MultiBox Detector (SSD) algorithm is adopted to train the image datasets. The scheme with the smallest identification angle error is the one identifying round objects, of which the identification angle error is 0.38°. Then, the identification accuracy was further improved, and the minimum recognition angle reached 1°. Finally, the looseness in a four-bolted connection and an eight-bolted connection are tested, confirming the feasibility of this method when applied on multi-bolted connection, and realizing a low operating costing and high accuracy.

Research on the Prediction of Green Plum Acidity Based on Improved XGBoost.

The acidity of green plum has an important influence on the fruit's deep processing. Traditional physical and chemical analysis methods for green plum acidity detection are destructive, time-consuming, and unable to achieve online detection. In response, a rapid and non-destructive detection method based on hyperspectral imaging technology was studied in this paper. Research on prediction performance comparisons between supervised learning methods and unsupervised learning methods is currently popular. To further improve the accuracy of component prediction, a new hyperspectral imaging system was developed, and the kernel principle component analysis-linear discriminant analysis-extreme gradient boosting algorithm (KPCA-LDA-XGB) model was proposed to predict the acidity of green plum. The KPCA-LDA-XGB model is a supervised learning model combined with the extreme gradient boosting algorithm (XGBoost), kernel principal component analysis (KPCA), and linear discriminant analysis (LDA). The experimental results proved that the KPCA-LDA-XGB model offers good acidity predictions for green plum, with a correlation coefficient (R) of 0.829 and a root mean squared error (RMSE) of 0.107 for the prediction set. Compared with the basic XGBoost model, the KPCA-LDA-XGB model showed a 79.4% increase in R and a 31.2% decrease in RMSE. The use of linear, radial basis function (RBF), and polynomial (Poly) kernel functions were also compared and analyzed in this paper to further optimize the KPCA-LDA-XGB model.

Online Color Classification System of Solid Wood Flooring Based on Characteristic Features.

Solid wood flooring has good esthetic properties and is an excellent material for interior decoration. To meet the artistic effects of specific interior decoration requirements, the color of solid wood flooring needs to be coordinated. Thus, the color of the produced solid wood flooring needs to be sorted to meet the individual needs of customers. In this work, machine vision, deep learning methods, and ensemble learning methods are introduced to reduce the cost of manual sorting and improve production efficiency. The color CCD camera was used to collect 108 solid wood floors of three color grades provided by the company and obtained 108 18,000 × 2048 pixel wood images. A total of 432 images were obtained after data expansion. Deep learning methods, such as VGG16, DenseNet121, and XGBoost, were compared. After using XGBoost to filter the features, the accuracy of solid wood flooring color classification was 97.22%, the training model time was 5.27 s, the average test time for each picture was 51 ms, and a good result was achieved.

Defect Classification of Green Plums Based on Deep Learning.

The green plum is rich in amino acids, lipids, inorganic salts, vitamins, and trace elements. It has high nutritional value and medicinal value and is very popular among Chinese people. However, green plums are susceptible to collisions and pests during growth, picking, storage, and transportation, causing surface defects, affecting the quality of green plums and their products and reducing their economic value. In China, defect detection and grading of green plum products are still performed manually. Traditional manual classification has low accuracy and high cost, which is far from meeting the production needs of green plum products. In order to improve the economic value of green plums and their products and improve the automation and intelligence level of the product production process, this study adopted deep learning methods based on a convolutional neural network and cost-effective computer vision technology to achieve efficient classification of green plum defects. First, a camera and LEDs were used to collect 1240 green plum images of RGB, and the green plum experimental classification standard was formulated and divided into five categories, namely, rot, spot, scar, crack, and normal. Images were randomly divided into a training set and test set, and the number of images of the training set was expanded. Then, the stochastic weight averaging (SWA) optimizer and w-softmax loss function were used to improve the VGG network, which was trained and tested to generate a green plum defect detection network model. The average recognition accuracy of green plum defects was 93.8%, the test time for each picture was 84.69 ms, the recognition rate of decay defect was 99.25%, and the recognition rate of normal green plum was 95.65%. The results were compared with the source VGG network, resnet18 network, and green lemon network. The results show that for the classification of green plum defects, the recognition accuracy of the green plum defect detection network increased by 9.8% and 16.6%, and the test speed is increased by 1.87 and 6.21 ms, respectively, which has certain advantages.

Recognition and Grasping of Disorderly Stacked Wood Planks Using a Local Image Patch and Point Pair Feature Method.

Considering the difficult problem of robot recognition and grasping in the scenario of disorderly stacked wooden planks, a recognition and positioning method based on local image features and point pair geometric features is proposed here and we define a local patch point pair feature. First, we used self-developed scanning equipment to collect images of wood boards and a robot to drive a RGB-D camera to collect images of disorderly stacked wooden planks. The image patches cut from these images were input to a convolutional autoencoder to train and obtain a local texture feature descriptor that is robust to changes in perspective. Then, the small image patches around the point pairs of the plank model are extracted, and input into the trained encoder to obtain the feature vector of the image patch, combining the point pair geometric feature information to form a feature description code expressing the characteristics of the plank. After that, the robot drives the RGB-D camera to collect the local image patches of the point pairs in the area to be grasped in the scene of the stacked wooden planks, also obtaining the feature description code of the wooden planks to be grasped. Finally, through the process of point pair feature matching, pose voting and clustering, the pose of the plank to be grasped is determined. The robot grasping experiment here shows that both the recognition rate and grasping success rate of planks are high, reaching 95.3% and 93.8%, respectively. Compared with the traditional point pair feature method (PPF) and other methods, the method present here has obvious advantages and can be applied to stacked wood plank grasping environments.

Detecting Defects on Solid Wood Panels Based on an Improved SSD Algorithm.

Wood is widely used in construction, the home, and art applications all over the world because of its good mechanical properties and aesthetic value. However, because the growth and preservation of wood are greatly affected by the environment, it often contains different types of defects that affect its performance and ornamental value. To solve the issues of high labor costs and low efficiency in the detection of wood defects, we used machine vision and deep learning methods in this work. A color charge-coupled device camera was used to collect the surface images of two types of wood from Akagi and Pinus sylvestris trees. A total of 500 images with a size of 200 × 200 pixels containing wood knots, dead knots, and checking defects were obtained. The transfer learning method was used to apply the single-shot multibox detector (SSD), a target detection algorithm and the DenseNet network was introduced to improve the algorithm. The mean average precision for detecting the three types of defects, live knots, dead knots and checking was 96.1%.