Highly efficient degradation of acetaminophen via nano zero-valent iron biochar with periodate system at low temperature.

The development of more efficient advanced oxidation systems for serving various advanced treatment of wastewater is quite necessary and urgent. In this study, a nano-zero valent iron/periodate (nZVI-BC/PI) advanced oxidation system has been constructed, achieving a rapid degradation of acetaminophen (ACT, 1 mg/L) within 1 min (100 % at pH = 11) at low temperature (5℃). This system shows a great degradation in a wide range of pH (1 âˆ¼ 11), improving the pH limitation of PI oxidation system. During the reaction process, ·OH as the main active species collaborate with 1O2, Fe (IV), ·O2- and electron transfer to degrade ACT. In this system, iron ion leaching is low (0.019 mg/L), ACT was effectively degraded (74.36 %∼97.32 %) under different water, moreover, the material has an expected recyclability. The research provides a significant guidance for the advanced treatment of wastewater especially in cold regions.

Simultaneous adsorption of phosphate and tetracycline by calcium modified corn stover biochar: Performance and mechanism.

It is important to solve the problems of biomass treatment and combined contaminants removal in environmental remediation. In this study, a calcium (Ca) modified biochar (CaBC800) was fabricated using corn stover (CS) as a raw material to remove phosphate and tetracycline (TC). The experimental results indicate that CaBC800 can adsorb both inorganic phosphate and organic TC. The entire adsorption process corresponds to pseudo-second-order kinetics and Langmuir adsorption isotherm. The maximum adsorption capacities of phosphate and TC were 33.944 and 33.534 mg/g, respectively. The phosphate adsorption was demonstrated to mainly depend on the chemical precipitation by Ca2+ and ligand exchange by hydroxyl groups from CaBC800. Meanwhile, hydrogen bonding from oxygen functional groups and π-π interactions from aromatic rings are the main adsorption mechanisms of TC. This study provides a new adsorbent to efficiently remove phosphate and TC, and the simultaneous adsorption indicates the application potential of CaBC800 in wastewater remediation.

In situ utilization of biomass pretreatment liquor as a novel flocculant for anion dyes removal: Performance and mechanism.

In this work, it was first found biomass pretreatment liquor (PL) produced from rice straw (RS) pretreatment with FeCl3 and polyethylene glycol 400 co-solvent can be used in situ as a new flocculant to remove anionic dyes from wastewater. The removal performance of nine dyes was investigated using various PL doses at different pH values. The experiment indicated that the PL had different flocculation effects on these dyes (color removal efficiency: 42.58-99.84%). Positive color removal results for the dyes were unachievable with six commercial coagulants. Among the nine dyes treated by PL flocculation, the best removal efficiencies for color, turbidity and suspended matter were obtained for Congo red. In the flocculation process, Fe3+ plays a role in charge neutralization, lignin nanoparticles (LNP) relies on hydroxyl groups to react instantaneously with the amino groups on the dye, and are bridged together by π-π interactions to promote the formation of floc clusters until they completely settle. Utilization of PL as a flocculant helps pave the way to simultaneously treat waste biomass, waste treatment liquor and dye wastewater. This research is of great significance for future water environment remediation and material development.