ABSTRACT
Advanced aerogel materials with low thermal conductivity and high transparency have shown great application prospects in the solar thermal energy conversion field. However, most aerogels do not meet these requirements due to their low optical transparency and poor mechanical properties. To tackle this problem, we have created versatile polyimide (PI) aerogel materials by adjusting the monomers to alter their molecular structure. These materials exhibit exceptional thermal insulation properties and high transparency, making them ideal for use in the construction of efficient solar collector devices. Incorporating 1,3,5-benzenetricarbonyl trichloride into PI aerogel results in high strength (>3 MPa) and excellent transmittance (>90%) over a broad range of wavelengths (500-2650 nm). The as-prepared PI aerogel solar collector (PIASC) also exhibits a low thermal conductivity (0.032 W/mK), a low density (0.1 g/cm3), and high porosity (90%). By changing the shape of the collector from a flat plate to a cylindrical ring, the heat collection efficiency and capacity are significantly improved, resulting in efficient heat collection. The circular ring collector has a maximum heat collection temperature of 236.8 °C. The PIASC, which is both flexible and highly transparent, is an ideal candidate for advanced optical elements and solar collectors.
