ABSTRACT
Measurements of thermal diffusivity, heat capacity and thermal expansion of X37CrMoV5-1 (1.2343) hot-work tool steel and Maraging 350 (1.6355) steel in the temperature range from -50 °C to 1000 °C were carried out in this paper. Both X37CrMoV5-1 and Maraging 350 are tested for military use as barrel steels. Thermophysical properties were tested using specialised test stands from NETZSCH. Thermal diffusivity was studied using both the LFA 427 laser flash apparatus in the temperature range of RT-1000 °C and the LFA 467 laser flash apparatus in the temperature range of -50 °C-500 °C. Specific heat capacity was investigated using a DSC 404 F1 Pegasus differential scanning calorimeter in the range RT-1000 °C, and thermal expansion was investigated using both a DIL 402 Expedis pushrod dilatometer in the range -50 °C-500 °C and a DIL 402 C in the range RT-1000 °C. Inconel 600 was selected as the reference material during the thermal diffusivity test using LFA467. Tests under the light microscope (LM), scanning electron microscopy (SEM) and Vickers microhardness measurements were carried out to detect changes in the microstructure before and after thermophysical measurements. This paper briefly characterises the research procedures used. In conclusion, the results of testing the thermophysical properties of X37CrMoV5-1 hot-work tool steel and Maraging 350 steel are compared with our results on 38HMJ (1.8509), 30HN2MFA and Duplex (1.4462) barrel steels. The thermophysical properties of X37CrMoV5-1 (1.2343) hot-work tool steel and Maraging 350 (1.6355) steel are incomplete in the literature. The paper presents the thermophysical properties of these steels over a wide range of temperatures so that they can be used as input data for numerical simulations of heat transfer in cannon barrels.
ABSTRACT
Over the past decade, the neodymium (Nd) isotope composition of mineral matter from peat cores has seen increasingly common use as a tracer of dust influx associated with major changes in the Holocene atmospheric circulation. However, the incomplete understanding of the local controls on the sources of the sediment supplied to peatlands remains a key difficulty in the interpretation of the archived Nd isotope signals. Here, we used neodymium isotopes to reconstruct environmental disturbances in peatlands. We performed a multi-proxy study of two peatlands that experienced peatland burning and validated the recorded peat Nd signatures using reference surface sampling. Our data show a link between the Nd isotope signals and local environmental disturbances: peat burning, local fire activity and pollution fluxes. Our study illustrates the crucial role of identifying local events that influence the supply of mineral material to peatlands. Insufficient recognition of such local controls may either obscure the large-scale variations in the atmospheric circulation patterns, or introduce artefacts to the Holocene climate record. We also provide recommendations for the use of Nd isotopes in palaeoecological studies of peatlands.
ABSTRACT
The purpose of this study is to investigate the effect of heat treatments and resulting changes in microstructure on the thermophysical properties of commercial 1.4462 duplex stainless steel. Three types of heat treatment and a raw sample were used. In the first heat treatment, a duplex steel bar was annealed in an air atmosphere furnace for one hour at 1200 °C and then quickly cooled in water (1200 °C + water). The second heat treatment was the same as the first, but afterwards, the bar was annealed in an air atmosphere furnace for 4 h at 800 °C and then slowly cooled down in the furnace to room temperature (1200 °C + water + 800 °C). In the third heat treatment, the duplex steel bar was annealed in the furnace in an air atmosphere for one hour at 900 °C and then slowly cooled in the furnace to room temperature (900 °C). As a result, the weight percentages of ferrite and austenite in the samples achieved the following ratios: 75:25, 65:35 and 44:56. Light microscope examinations (LM), scanning electron microscopy (SEM), Vickers micro-hardness measurements and thermophysical studies using a laser flash apparatus (LFA), differential scanning calorimetry (DSC) and push-rod dilatometry (DIL) were performed to reveal the microstructure and changes in thermophysical properties including thermal diffusivity, thermal conductivity, thermal expansion and specific heat. Along with presenting these data, the paper, in brief, presents the applied investigation procedures.
ABSTRACT
This study presents first isoscape maps of strontium isotope signatures and their spatial variation in Poland, based on ~900 samples of rocks, sediments, surface water, and flora. This dataset is supplemented by 87Sr/86Sr ratios predicted for several carbonate rock units. High, radiogenic Sr isotope ratios (>0.72), related to the Pleistocene glacial deposits, are omnipresent throughout the country and are also found in the Sudetes and the Holy Cross Mountains, where igneous and clastic Palaeozoic rocks are widely exposed. The lowest Sr signatures (<0.71) occur predominantly in the Silesian-Malopolska and Lublin uplands and are related to exposures of Palaeozoic, Mesozoic, and Neogene carbonate rocks. The large variation of 87Sr/86Sr ratios in the environment across the country is chiefly driven by the diversity in the geological substrate, and locally, it is also influenced by anthropogenic contamination. Strontium isoscapes for the geological substrate and surface waters differ from each other, in terms of the range of 87Sr/86Sr values and their distributional pattern. The differences result primarily from mixing processes in the geosphere (weathering), hydrosphere, and biosphere that control Sr inputs from various natural sources present in the environment. On the other side, they are also created by anthropogenic contamination of surface water and presumably of soils. This situation has important implications for future archaeological provenance and migration studies, as isoscapes for surface water and vegetation cannot be directly used to estimate the local 87Sr/86Sr baselines for past human populations. Therefore, caution is required when modern Sr data of surface water and plants are used in archaeological research. 87Sr/86Sr values of the geological substrate, which may be affected by anthropogenic contamination to a lesser extent than water, soil, and vegetation, are favoured for the baseline estimation for historical times.
ABSTRACT
In this paper, thermophysical and viscoelastic dynamic mechanical measurements (DMA) were performed for bare and clad aluminum AW-2024-T3 alloys. Specific heat, thermal diffusivity, and dynamic module (storage and loss) tests were performed in the range of 50 to 500 °C, except for DMA ones (RT-400 °C). All tests were carried out using the following specialized measuring stands: a light flash apparatus (LFA), differential scanning calorimeter (DSC), and a dynamic mechanical analyzer (DMA). The microstructures and compositions of alloys were investigated by light microscope (LM), scanning electron microscope (SEM), and energy-dispersive X-ray spectroscopy (EDS). Furthermore, Vickers micro-hardness measurements were conducted prior to and after DSC studies. Different precipitation kinetics of the q' and S' metastable phases in the bare 2024-T3 compared to the clad alloy were observed by DSC. Additionally, the DSC results for a few selected scan rates were analyzed by the Kissinger method to give activation energies for the precipitation of q' and S' metastable phases in the alloys. The apparent activation energy of the q' and S' phases corresponds to 137.1 ± 4.4 for the bare alloy and 131.0 ± 6.0 (exo) and 104.1 ± 2.1 (exo) (two peaks) for the clad alloy.
ABSTRACT
Anthropogenic impact on surface waters and other elements in the environment was investigated in the Notec River basin in central Poland. The approach was to trace changes in the Sr isotope composition ((87)Sr/(86)Sr) and concentration in space and time. Systematic sampling of the river water shows a very wide range of (87)Sr/(86)Sr ratios, from 0.7089 to 0.7127. This strong variation, however, is restricted to the upper course of the river, whereas the water in the lower course typically shows (87)Sr/(86)Sr values around 0.7104-0.7105. Variations in (87)Sr/(86)Sr are associated with a wide range of Sr concentrations, from 0.14 to 1.32mg/L. We find that strong variations in (87)Sr/(86)Sr and Sr concentrations can be accounted for by mixing of two end-members: 1) atmospheric waters charged with Sr from the near-surface weathering and wash-out of Quaternary glaciogenic deposits, and 2) waters introduced into the river from an open pit lignite mine. The first reservoir is characterized by a low Sr content and high (87)Sr/(86)Sr ratios, whereas mine waters display opposite characteristics. Anthropogenic pollution is also induced by extensive use of fertilizers which constitute the third source of Sr in the environment. The study has an important implication for future archeological studies in the region. It shows that the present-day Sr isotope signatures of river water, flora and fauna cannot be used unambiguously to determine the "baseline" for bioavailable (87)Sr/(86)Sr in the past.
Subject(s)
Environmental Monitoring/methods , Rivers/chemistry , Water Pollutants, Chemical/analysis , Poland , Strontium Isotopes/analysisABSTRACT
Hydropsyche angustipennis (Insecta, Trichoptera) larvae were used as indicators of stream contamination in the city of Lódz, Poland. The larvae of H. angustipennis were present at 9 sampling sites established for this study. Significant differences between the sampling sites were noted for environmental parameters as well as concentration of chemicals in water and biodiversity of aquatic invertebrates. Statistical analyses showed significant correlations between quantity and quality of water pollutants and density of H. angustipennis larvae, concentration of metals in larval bodies, and the appearance of morphological anomalies in tracheal gills and anal papillae. In comparison to literature data, the level of contaminants in water, including heavy metals, for each of the studied streams of Lódz was surprisingly low while concentration of these metals in the whole bodies of H. angustipennis larvae was very high. Some of the heavy metals present in the water might be identified only after conducting analyses of their concentration in the larval bodies. Therefore, long life cycle of H. angustipennis and heavy metal tolerance with a possibility of their accumulation in the larval bodies may constitute a support to traditional chemical assessment of water quality or traditional biomonitoring.
