ABSTRACT
Researchers have focused on incorporating porous carbon particles such as carbon-derived carbon (CDC) into polypyrrole (PPy), preferably on the surface, to achieve high-capacitive electrodes. Less attention is afforded to their linear actuation properties. Therefore, in this work, we chose two different electropolymerization processes using the typical PPy doped with dodecylbenzene sulfonate (DBS-) and added CDC particles, compared with CDC with phosphotungstic acid (PTA), forming CDC-PT4- dopants. The resulting PPy/DBS-CDC (PPyCDC) and PPy/DBS-CDC-PT (PPyCDC-PT) films showed different morphologies, with PPyCDC having the most CDC particles on the surface with less surrounding PPy, while in PPyCDC-PT, all the CDC particles were covered with PPy. Their linear actuation properties, applying electrochemical techniques (cyclic voltammetry and square wave potential steps), were found to enhance the PPyCDC-PT films in organic (2-times-higher strain) and aqueous electrolytes (2.8-times-higher strain) in an applied potential range of 0.8 V to -0.5 V. The energy storage capability found for the PPyCDC was favorable, with 159 ± 13 F cm-3 (1.2 times lower for PPyCDC-PT) in the organic electrolyte, while in the aqueous electrolyte, a result of 135 ± 11 F cm-3 was determined (1.8 times lower for PPyCDC-PT). The results showed that PPyCDC was more favorable in terms of energy storage, while PPyCDC-PT was suitable for linear actuator applications. The characterization of both the film samples included scanning electron microscopy (SEM), Raman, FTIR, and energy-dispersive X-ray (EDX) spectroscopy.
ABSTRACT
A combination of polyoxometalates with polypyrrole is introduced in this work. Our goal was to include phosphotungstic acid (PTA) in different molar concentrations (0.005, 0.01, and 0.05 M) in the electropolymerization of pyrrole doped with dodecylbenzene sulfonate (DBS) and phosphotungstinates (PT), forming PPy/DBS-PT films. Scanning electron microscopy (SEM) revealed that the PPy/DBS-PT films became denser and more compact with increasing PTA concentrations. The incorporation of PT in PPy/DBS was analyzed using Fourier-transform infrared (FTIR) and energy dispersive X-ray (EDX) spectroscopy. The linear actuation in cyclic voltammetry and potential square wave steps in an organic electrolyte revealed increasing mixed actuation, with major expansion upon oxidation found for PPy/DBS-PT films with a PTA concentration of 0.005 M. Best results of a strain of 12.8% and stress at 0.68 MPa were obtained for PPy/DBS-PT (0.01 M). The PPy/DBS-PT films polymerized in the presence of 0.05 M of PTA and showed main expansion upon reduction, changing the actuation direction. Chronopotentiometric measurements of PPy/DBS-PT samples were conducted to determine the specific capacitance optimal for a 0.01 M PTA concentration in the range of 80 F g-1 (±0.22 A g-1).
ABSTRACT
Linear actuators based on polypyrrole (PPy) are envisaged to have only one ion that triggers the actuation direction, either at oxidation (anion-driven) or at reduction (cation-driven). PPy doped with dodecylbenzenesulfonate (PPy/DBS) is the most common applied conducting polymer having cation-driven actuation in aqueous solvent and mainly anion-driven actuation in an organic electrolyte. It is somehow desired to have an actuator that is independent of the applied solvent in the same actuation direction. In this research we made PPy/DBS with the addition of phosphorus tungsten acid, forming PPyPT films, as well with included carbide derived carbon (CDC) resulting in PPyCDC films. The solvent in electropolymerization was changed from an aqueous ethylene glycol mixture to pure EG forming PPyPT-EG and PPyCDC-EG composites. Our goal in this study was to investigate the linear actuation properties of PPy composites applying sodium perchlorate in aqueous (NaClO4-aq) and propylene carbonate (NaClO4-PC) electrolytes. Cyclic voltammetry and square potential steps in combination with electro-chemo-mechanical-deformation (ECMD) measurements of PPy composite films were performed. The PPyPT and PPyCDC had mixed ion-actuation in NaClO4-PC while in NaClO4-aq expansion at reduction (cation-driven) was observed. Those novel PPy composites electropolymerized in EG solvent showed independently which solvent applied mainly expansion at reduction (cation-driven actuator). Chronopotentiometric measurements were performed on all composites, revealing excellent specific capacitance up to 190 F g-1 for PPyCDC-EG (best capacitance retention of 90 % after 1000 cycles) and 130 F g-1 for PPyPT-EG in aqueous electrolyte. The films were characterized by scanning electron microscopy (SEM), Raman, Fourier-transform infrared (FTIR) and energy dispersive X-ray spectroscopy (EDX).
ABSTRACT
In films of conducting polymers, the electrochemical reaction(s) drive the simultaneous variation of different material properties (reaction multifunctionality). Here, we present a parallel study of actuation-sensing-energy storage triple functionality of polypyrrole (PPy) blends with dodecylbenzenesulfonate (DBS-), PPy/DBS, without and with inclusion of polyethyleneoxide, PPy-PEO/DBS. The characterization of the response of both materials in aqueous solutions of four different salts indicated that all of the actuating, sensing and charge storage responses were, independent of the electrolyte, present for both materials, but stronger for the PPy-PEO/DBS films: 1.4× higher strains, 1.3× higher specific charge densities, 2.5× higher specific capacitances and increased ion-sensitivity towards the studied counterions. For both materials, the reaction energy, the material potential and the strain variations adapt to and sense the electrical and chemical (exchanged cation) conditions. The driving and the response of actuation, sensing and charge can be controlled/read, simultaneously, via just two connecting wires. Only the cooperative actuation of chemical macromolecular motors from functional cells has such chemical multifunctionality.
ABSTRACT
Either as salts or room temperature ionic liquids, fluorinated anion-based electrolytes have been a common choice for ionic electroactive polymer actuators, both linear and bending. In the present work, propylene carbonate solutions of four electrolytes of the three hugely popular anions-triflouromethanesulfonate, bis(trifluoromethane)sulfonimide, and hexafluorophosphate were compared and evaluated in polypyrrole linear actuators. The actuation direction, the characteristics-performance relations influence the behavior of the actuators. Isotonic Electro-chemo-mechanical deformation (ECMD) measurements were performed to study the response of the PPy/DBS samples. The highest strain for pristine PPy/DBS linear actuators was found in range of 21% for LiTFSI, while TBAPF6 had the least cation involvement, suggesting the potential for application in durable and controllable actuators. Interesting cation effects on the actuation of the same anions (CF3SO3-) were also observed.
