Direct Imprinting of Large-Area Metallic Photonic Lattices for Infrared Polarization Filters with Broadband Tunability.

Metallic photonic lattices are promising in their application to plasmonic optical devices; however, scalable fabrication strategies are limited by sample size, response wavelength (mostly in the visible range), cost, and duration. This paper proposes a direct imprinting strategy to fabricate large-area metallic photonic lattices, which present a strong plasmonic response and broadband angle-resolved tuning properties in the infrared region. This simple fabrication strategy combines solution-synthesized Au nanoparticle colloid and imprinting technology, which does not require the use of photoresist or lithography. Thus, the feature size and response wavelength can exceed the limitations of the beam size and wave band, thereby offering the advantages of a low cost and high throughput.

Do non-citizens migrate for welfare benefits? Evidence from the Affordable Care Act Medicaid expansion.

We explore if low-educated noncitizens, who have a considerably high uninsured rate, internally migrate to states with more generous public insurance benefits. We utilize the state-level variation in accessing Medicaid benefits and employ a difference-in-differences methodology that compares in-migration and out-migration rates of non-citizens in states that adopted Medicaid expansion, both before and after the policy implementation, to the outcomes of non-citizens in states that did not adopt the expansion. We find that interstate in-migration (out-migration) rates of Medicaid expansion states did not increase (decrease) relative to that of non-expansion states after the expansion.

Suppressing the Step Effect of 3D Printing for Constructing Contact Lenses.

3D printing has been considered as a sustainable method to construct complicated 3D structures. However, the step effect induced by the traditional point-by-point or layer-by-layer additive manufacturing mode inevitably occurs and remains an obstacle to realizing the smoothness and uniformity of 3D samples. Here, a continuous liquid film confined 3D printing strategy is proposed to fabricate high-precision 3D structures based on the Digital Light Processing (DLP) technology. With the control of the confinement of the liquid-solid interface and the continuous printing mode, liquid film adhering to the cured structure is sucked into the cured layer structures with excess resin adhering to the cured structure scraping off, where the step effect is eliminated and post-washing is avoided. The morphology and dimension of the confined liquid film can be well regulated by ink properties and printing parameters to optimize the surface smoothness and printing fidelity. In addition, heat accumulation and thermal diffusion are also suppressed, ensuring the long-term printing stability. A centimeter-scale contact lens structure with central thickness of ≈135 µm comparable to commercial ones can be printed, which possesses extreme smoothness (sub 1.3 nm), homogeneous mechanical characteristic, biocompatibility, and high optical properties with imaging resolution of up to 228.1 lp mm-1 .

3D Printing a Biomimetic Bridge-Arch Solar Evaporator for Eliminating Salt Accumulation with Desalination and Agricultural Applications.

Solar-driven water evaporation has been considered a sustainable method to obtain clean water through desalination. However, its further application is limited by the complicated preparation strategy, poor salt rejection, and durability. Herein, inspired by superfast water transportation of the Nepenthes alata peristome surface and continuous bridge-arch design in architecture, a biomimetic 3D bridge-arch solar evaporator is proposed to induce Marangoni flow for long-term salt rejection. The formed double-layer 3D liquid film on the evaporator is composed of a confined water film for water supplementation and a free-flowing water film with ultrafast directional Marangoni convection for salt rejection, which functions cooperatively to endow the 3D evaporator with all-in-one function including superior solar-driven water evaporation (1.64 kg m-2 h-1 , 91% efficiency for pure water), efficient solar desalination, and long-term salt-rejecting property (continuous 200 h in 10 wt% saline water) without any post-cleaning treatment. The design principle of the 3D structures is provided for extending the application of Marangoni-driven salt rejection and the investigation of structure-design-induced liquid film control in the solar desalination field. Furthermore, excellent mechanical and chemical stability is proved, where a self-sustainable and solar-powered desalination-cultivation platform is developed, indicating promising application for agricultural cultivation.

Self-Driven Multiplex Reaction: Reactant and Product Diffusion via a Transpiration-Inspired Capillary.

When dealing with reactions of a liquid reactant and a solid catalyst, macroreactors with vigorous stirring equipment may be dangerous and cause wastage of energy. Reducing the diffusion distance and promoting reactants to reach the catalyst surface for efficient reaction remain the key challenges. Here, inspired by capillary-driven water motion in plants, we propose to implement a self-driven multiplex reaction (SMR) in nanocatalyst-loaded microchannels. Unlike the classical capillary rise, the droplet in SMR has variable pressure difference, leading to tunable flow velocity for controlling the reaction rate without any auxiliary equipment. The SMR in microchannels contributes to an increase in the reaction rate by more than 2 orders of magnitude compared to that in macroreactors. Specifically, this strategy reduces the reaction volume by 170 times, the catalyst usage by about 12 times, and the energy consumption by 50 times. This apparatus with a small volume and less catalyst content promises to provide an efficient strategy for the precise manipulation of chemical reactions.

The facile synthesis of a Co3O4-NiNP composite as an electrochemical non-enzymatic sensing platform for small chemical molecules.

In this paper, a new Co3O4-Ni nanocomposite-modified glassy carbon electrode (Co3O4-NiNPs/GCE) was successfully constructed and used to detect glucose and hydrogen peroxide (H2O2). The morphologies and structures of the Co3O4 and Co3O4-Ni nanocomposites were characterized via transmission electron microscopy (TEM), scanning electron microscopy (SEM), and X-ray diffraction (XRD). The construction process of the modified electrode was characterized via electrochemical impedance spectroscopy (EIS) and cyclic voltammetry (CV) techniques. Co3O4-NiNPs/GCE shows more excellent electrocatalytic activity for the detection of glucose and H2O2 compared with Co3O4/GCE and NiNPs/GCE. The amperometric i-t method was used for the quantitative analysis of glucose and H2O2. The plots of current difference versus concentration of glucose and H2O2 were linear in the range of 0.3-550 µM and 0.5-89 µM, respectively. The corresponding limits of detection (LODs) were 0.086 µM and 0.23 µM for glucose and H2O2, respectively. This recommended sensor was successfully applied for the quantitative analysis of glucose in fruit and H2O2 in water samples.

Impacts of shifting responsibility for high-cost individuals on Health Insurance Exchange plan premiums and cost-sharing provisions.

Insurance companies can respond to increases in expected per-capita healthcare expenditures by adjusting premiums, cost-sharing requirements, and/or plan generosity. We use a Difference-in-Difference model with Plan-level Fixed Effects to estimate the impacts of increases in expected expenditures generated by closure of state-operated High Risk Pools (HRPs). For Silver plans, we find that issuers responded to HRP closures by increasing both premiums and deductibles, and by increasing the ratios of premiums to deductibles. This adjustment to the structure of plan prices is consistent with the hypothesis that issuers will be reluctant to adjust deductibles, because consumers tend to overweight changes in deductibles over changes in premiums. The increase in the ratio of premiums to deductibles indicates that the increase in expected expenditures triggered an increase in the share of total risk-pool healthcare expenditures paid by low healthcare utilizers, and a decrease in the share paid by high utilizers.

Bartha-k61 vaccine protects growing pigs against challenge with an emerging variant pseudorabies virus.

Since late 2011, pseudorabies (PR) has resurfaced in many large pig farms, causing great economic loss for the swine industry in China. The PRV variant strain with high virulence and antigenic variation has been considered to be the main cause, and much attention has been focused on how to prevent and control the reoccurrence of this disease in China. In this study, two kinds of vaccination strategy were employed to evaluate the protective effects of Bartha-k61vaccine against both variant PRV (XJ5) and classical PRV (Ra) strain challenge. Humoral immunity response, clinical signs, survival rate, body weight, virus shedding and pathology were assessed in commercial pigs. The results showed that Bartha-k61vaccine, administered either once or twice, was effective against the PRV variant (XJ5) challenge, while no significant differences were observed between single and prime-boost vaccinated pigs. However, pigs vaccinated twice had better body weight gains than those vaccinated once, following challenge with the classical PRV strain (Ra) (p<0.01). Therefore, the Bartha-k61 vaccine appears to be an effective vaccine to control the spread of PRV variants in China in the absence of new powerful candidate vaccines specific to these PRV strains.