High Recovery of Ceramic Membrane Cleaning Remediation by Ozone Nanobubble Technology.

The persistent issue of ceramic membrane fouling poses significant challenges to its widespread implementation. To address this concern, ozone nanobubbles (ozone-NBs) have garnered attention due to their remarkable mass transfer efficiency. In this investigation, we present a novel ozone-NB generator system to effectively clean a fouled ceramic membrane that is typically employed in the dye industry. The surface characteristics of the ceramic membrane underwent significant alterations, manifesting incremental changes in surface roughness and foulant accumulation reduction, as evidenced in atomic force microscopy, scanning electron microscopy, X-ray fluorescence, and energy-dispersive spectroscopy. Remarkably, the sequential 4 h cleaning process demonstrates an effective outcome leading to an almost 2-fold enhancement in the membrane flux. The initial fouled state of 608 L/h/m2 increased to 1050 L/h/m2 in the 4 h state with a recovery of 50%. We propose such membrane performance improvement governed by the ozone-NBs with a size distribution of 213.2 nm and a zeta potential value of -20.26 ± 0.13 mV, respectively. This effort showcases a substantial innovative and sustainable technology approach toward proficient foulant removal in water treatment applications.

Electrospun Nanofibers from Waste Polyvinyl Chloride Loaded Silver and Titanium Dioxide for Water Treatment Applications.

The electrospun nanofiber membrane from polyvinyl chloride (PVC) waste for water treatment applications has been successfully produced. The PVC precursor solution was prepared by dissolving the PVC waste in DMAc solvent, and a centrifuge was used to separate undissolved materials from the precursor solution. Ag and TiO2 were added to the precursor solution before the electrospinning process. We studied the fabricated PVC membranes using SEM, EDS, XRF, XRD, and FTIR to study the fiber and membrane properties. The SEM images depicted that Ag and TiO2 addition has changed the morphology and size of fibers. The EDS images and XRF spectra confirmed the presence of Ag and TiO2 on the nanofiber membrane. The XRD spectra showed the amorphous structure of all membranes. The FTIR result indicated that the solvent completely evaporated throughout the spinning process. The fabricated PVC@Ag/TiO2 nanofiber membrane showed the photocatalytic degradation of dyes under visible light. The filtration test on the membrane PVC and PVC@Ag/TiO2 depicted that the presence of Ag and TiO2 affected the flux and separation factor of the membrane.

High-Efficiency Water Filtration by Electrospun Expanded Polystyrene Waste Nanofibers.

Nanofiber membranes were successfully synthesized from expanded polystyrene (EPS) waste with the addition of poly(vinylpyrrolidone) (PVP) for water microfiltration using the electrospinning method. The EPS-based nanofiber membranes exhibited a smooth morphology and were uniform in size. The concentration of the EPS/PVP solution changed some of the physical parameters of the nanofiber membrane, such as viscosity, conductivity, and surface tension. Greater viscosity and surface tension increase the nanofiber membrane diameter, whereas the addition of PVP results in hydrophilicity. Additionally, increasing the pressure increased the flux value of each variation of the nanofiber membranes. Furthermore, the rejection value was 99.99% for all variations. Finally, the use of EPS waste for nanofiber membranes is also beneficial for decreasing the amount of EPS waste in the environment and is an alternative to the current membranes available in the market for water filtration applications.

Waste acrylonitrile butadiene styrene (ABS) incorporated with polyvinylpyrrolidone (PVP) for potential water filtration membrane.

Acrylonitrile butadiene styrene (ABS) is one of the most common fused-filament feedstocks for 3D printing. The rapid growth of the 3D printing industry has resulted in huge demand for ABS filaments; however, it generates a large amount of waste. This study developed a novel method using waste ABS to fabricate electrospun nanofiber membranes (ENMs) for water filtration. Polyvinylpyrrolidone (PVP) was employed to modify the properties of waste ABS, and the effect of PVP addition in the range of 0-5 wt% was investigated. The results showed that adding PVP increased the viscosity and surface tension but decreased the conductivity of the precursor solution. After electrospinning, PVP could reduce the number of beads, increase the porosity and fiber diameter, and improve the wettability of the fabricated fibers. Moreover, the bilayer of ABS ENMs achieved a high flux value between 2951 and 48 041 L m-2 h-1 and a high rejection rate of 99%. Our study demonstrates a sustainable strategy to convert waste plastics to inexpensive materials for wastewater treatment membranes.

Synthesis of Electrospun PAN/TiO2/Ag Nanofibers Membrane As Potential Air Filtration Media with Photocatalytic Activity.

The PAN/TiO2/Ag nanofibers membrane for air filtration media was successfully synthesized with electrospinning method. The morphology, size, and element percentage of the nanofiber were characterized by a scanning electron microscopy-energy dispersive spectroscopy, while X-ray fluorescence and FTIR were used to observe the chemical composition. The water contact angle and UV-vis absorption were measured for physical properties. Performance for air filtration media was measured by pressure drop, efficiency, and quality factor test. TiO2 and Ag have been successfully deposited in nonuniform 570 nm PAN/TiO2/Ag nanofibers. The nanofiber membrane had hydrophilic surface after TiO2 and Ag addition with a water contact angle of 34.58°. UV-vis data showed the shifting of absorbance and band gap energy of nanofibers membrane to visible light from 3.8 to 1.8 eV. The 60 min spun PAN/TiO2/Ag nanofibers membrane had a 96.9% efficiency of PM2.5, comparable to results reported in previous studies. These properties were suitable to be applied on air filtration media with photocatalytic activity for self-cleaning performance.

The synthesis of nanofiber membranes from acrylonitrile butadiene styrene (ABS) waste using electrospinning for use as air filtration media.

Acrylonitrile butadiene styrene (ABS) waste has been successfully recycled into nanofiber membranes by an electrospinning method for air filter applications. The ABS precursor solutions were made by dissolving the ABS waste in three different solvents, DMAc, DMF, and THF, with various concentrations of 10, 20, and 30 wt%. The solvent and solution concentrations affected the fiber properties (size and morphology) and membrane properties (wettability, crystallinity, and mechanical). Accordingly, we tested the fabricated membranes using SEM, FTIR, XRD, water contact angle, and tensile strength test measurements. The SEM images depicted three different morphologies, i.e. beads, beaded fibers, and pure fibers. The FTIR spectra showed that the solvents completely evaporated during the electrospinning process. The water contact angle test exhibited the hydrophobic properties of all the membrane samples. The XRD spectra showed the amorphous structures of all the membranes. The tensile strength test showed that the membranes fabricated using DMF and DMAc solvents had the best mechanical properties. Considering the fiber size, wettability, and mechanical properties, the membranes fabricated using DMAc and DMF solvents had the best criteria as air filter media. Filtration tests on the membranes fabricated using DMAc and DMF solvents with various solution concentrations depicted that the beads affected the membrane pressure drop and efficiency. The beads gave more space among the fibers, which facilitated the air flow through the membrane. The beads greatly reduced the pressure drop without an overly reduced membrane filtration efficiency. This led to a high-quality factor of the membranes that demonstrated their applicability as potential air filter media.