1.
Chem Commun (Camb)
; 58(91): 12700-12703, 2022 Nov 15.
Article
in English
| MEDLINE
| ID: mdl-36305224
ABSTRACT
The first example of a cationic cluster-based fcu-lanthanide metal-organic framework (MOF) bearing an asymmetric linker, herein named UOTT-4, has been designed and fully characterized. Compared to its rare-earth (RE) anionic counterpart (RE-UiO-66), UOTT-4 was found to significantly improve the performance towards adsorption of iodine vapour at room temperature, opening avenues for the design of the next-generation cationic porous materials for the beneficial uptake and confinement of target molecules.