Electrochemical processes for the treatment of contaminant-rich wastewater: A comprehensive review.

Global water demand and environmental concerns related to climate change require industries to develop high-efficiency wastewater treatment methods to remove pollutants. Likewise, toxic pollutants present in wastewater negatively affect the environment and human health, requiring effective treatment. Although conventional treatment processes remove carbon and nutrients, they are insufficient to remove pharmaceuticals, pesticides, and plasticizers. Electrochemical processes effectively remove pollutants from wastewater through the mineralization of non-biodegradable pollutants with consequent conversion into biodegradable compounds. Its advantages include easy operation, versatility, and short reaction time. In this way, this review initially provides a global water scenario with a view to the future. It comprises global demand, treatment methods, and pollution of water resources, addressing various contaminants such as heavy metals, nutrients, organic compounds, and emerging contaminants. Subsequently, the fundamentals of electrochemical treatments are presented as well as electrochemical treatments, highlighting the latest studies involving electrocoagulation, electroflocculation, electroflotation, capacitive deionization and its derivatives, eletrodeionization, and electrochemical advanced oxidation process. Finally, the challenges and perspectives were discussed. In this context, electrochemical processes have proven promising and effective for the treatment of water and wastewater, allowing safe reuse practices and purification with high contaminant removal.

Biosorption of europium and erbium from aqueous solutions using crosslinked sericin-alginate beads.

Critical metals such as rare earths are essential for important industrial applications and for producing high-tech materials. Currently, the development of alternative and non-conventional biomaterials has gained significant interest. This work investigated the use of crosslinked sericin-alginate-based natural polymeric particles for the removal of rare earths from water. Affinity tests showed that sericin-alginate/polyethylene glycol diglycidyl ether had the highest potential for capturing europium (0.258 mmol/g and 94.33%) and erbium (0.259 mmol/g and 94.55%). Next, erbium was selected based on the affinity with sericin-alginate/polyethylene glycol diglycidyl to investigate the effect of dose/pH, biosorption kinetics, isothermal equilibrium, desorption/reuse, and selectivity. The effect of dose and pH showed that 8.0 g/L (95.91%) and pH 5.0 (97.53%) were more efficient in capturing erbium. The biosorption kinetics showed that the equilibration time was reached within 210 min. The PSO and EMTR models effectively represented the kinetics data. The isothermal equilibrium revealed that the maximum uptake capacity for erbium was 0.641 mmol/g. The isothermal curves better fit the Dubinin-Radushkevich (55 °C) and Langmuir (25 and 40 °C) models. Thermodynamic quantitates indicated that erbium uptake was spontaneous, governed by entropic changes, and endothermic. The recovery of Er3+ was greater than 98% and the reuse of the eluent in the cycles enriched the Er3+ load 10-times (1.0 to 9.91 mmol/L). The beads also showed better performance for capturing Er3+ and Eu3+ with other coexisting ions. Characterization analyzes revealed the ion exchange mechanism between Ca2+/Er3+ prevailed in the Er3+ removal. Thus, the results pointed out that crosslinked sericin-alginate can be used as an alternative and promising biosorbent to remove and recover rare earths.

Cerium biosorption onto alginate/vermiculite-based particles functionalized with ionic imprinting: Kinetics, equilibrium, thermodynamic, and reuse studies.

Cerium is an essential element for several applications in industry, therefore, recovering it from secondary sources is a promising strategy from an economic and environmental perspective. For this purpose, biosorption is a low-cost and effective alternative. The present work evaluated the recovery of Ce3+ from aqueous solutions using alginate/vermiculite-based particles (ALEV) functionalized by ionic imprinting. From the kinetic assays, it was verified that the uptake of Ce3+ followed the pseudo-second-order model and was mainly controlled by external diffusion. The Langmuir model better described the equilibrium data, and a maximum biosorption capacity of 0.671 mmol/g at 45 °C was attained. The evaluation of the thermodynamic quantities revealed that the process occurs spontaneously and endothermically. The particles reuse and Ce3+ recovery were achieved using 0.1 mol/L HCl or 1.0 mol/L CaCl2 solutions for up to four cycles of biosorption/desorption. The biosorbent was characterized before and posted Ce3+ biosorption to investigate the morphology, textural properties, crystallinity, thermal resistance, composition, and functional groups of the biosorbent.

Biosorption of rare-earth and toxic metals from aqueous medium using different alternative biosorbents: evaluation of metallic affinity.

Currently, the world faces difficulties related to the quantity and quality of water because of industrial expansion, population growth, and urbanization intensification. Biosorption is considered a promising technology that can be applied to remove toxic metals (TMs) and rare-earth metals (REMs) in wastewater at low concentrations, due to its efficiency and low cost. In this work, we investigated different non-conventional biosorbents to remove metallic ions (TMs and REMs) in biosorptive affinity tests. Metallic affinity assays among lanthanum and different biosorbents showed that greater affinities were found for sericin-alginate beads crosslinked with polyvinyl alcohol (SAPVA) (0.280 mmol/g) and polyethylene glycol diglycidyl ether (SAPEG) (0.277 mmol/g), expanded vermiculite (0.281 mmol/g), Sargassum filipendula seaweed (0.287 mmol/g), and seaweed biomass waste (0.289 mmol/g). Among the biosorbents evaluated, SAPVA and SAPEG beads, besides to sericin-alginate beads crosslinked with proanthocyanidins (SAPAs) were selected for affinity assays with other REMs and TMs. Compared to other particles, SAPVA beads showed higher potential for biosorption by REMs with the following order of affinity: Yb3+ > Dy3+ > Nd3+ > Ce3+ > La3+. Additionally, the biosorptive affinity of TMs by SAPVA beads followed the order: Al3+ > Cr3+ > Pb2+ > Cu2+ > Cd2+ > Zn2+ > Ni2+.

Effective recovery of ytterbium through biosorption using crosslinked sericin-alginate beads: A complete continuous packed-bed column study.

The recovery of rare-earth from secondary sources is essential for cleaner production. The development of natural biocomposites is promising for this purpose. Sericin is a waste protein from silk manufacturing. The highly polar groups on the surface of sericin facilitate blending and crosslinking with other polymers to produce biocomposites with improved properties. In this work, we investigate ytterbium recovery onto a natural biocomposite based on sericin/alginate/poly(vinyl alcohol) (SAPVA) in packed-bed column, aiming to establish a profitable application for sericin. Effects of flow rate and ytterbium inlet concentration showed that the highest exhaustion biosorption capacity (128.39 mg/g) and lowest mass transfer zone (4.13 cm) were reached under the operating conditions of 0.03 L/h and 87.95 mg/L. Four reusability cycles were performed under the optimum operating conditions using 0.3 mol/L HNO3. Ytterbium recovery was highly successful; desorption efficiency was higher than 97% and a final ytterbium-rich concentrate (3870 mg/L) was 44 times higher than input concentration. Regenerated beads characterization showed that the cation exchange mechanism plays a major function in continuous biosorption of ytterbium. SAPVA beads also showed higher biosorption/desorption performance for ytterbium than other competing ions. These results suggest the application of SAPVA may be an alternative for large-scale ytterbium recovery.

One waste and two products: choosing the best operational temperature and hydraulic retention time to recover hydrogen or 1,3-propanediol from glycerol fermentation.

This study aimed to compare the production of hydrogen and 1,3-propanediol from crude glycerol (10 g/L) in mesophilic (30 °C) and thermophilic (55 °C) anaerobic fluidized bed reactors, namely AFBR30 °C and AFBR55 °C, respectively, at hydraulic retention times (HRT) reduced from 8 to 1 h. In AFBR30 °C, the absence or low hydrogen yields can be attributed to the production of 1,3-propanediol (maximum of 651 mmol/mol glycerol), and the formation of caproic acid (maximum of 1097 mg/L) at HRTs between 8 and 2 h. In AFBR55 °C, the hydrogen yield of 1.20 mol H2/mol glycerol consumed was observed at the HRT of 1 h. The maximum yield of 1,3-propanediol in AFBR55 °C was equal to 804 mmol/mol glycerol at the HRT of 6 h and was concomitant with the production of hydrogen (0.87 mol H2/mol glycerol consumed) and butyric acid (1447 mg/L).

Anaerobic Biodegradation of Biodiesel Industry Wastewater in Mesophilic and Thermophilic Fluidized Bed Reactors: Enhancing Treatment and Methane Recovery.

In the past few years, the extraction of value-added compounds from the anaerobic digestion of glycerol has been an option to add value to this waste because biodiesel production is increasing worldwide. The evolution of research on glycerol valorization by anaerobic digestion has reached the use of high-rate reactors. However, no study has evaluated glycerol digestion in an anaerobic fluidized bed reactor (AFBR), a configuration with potential advantages in methane production. Still, the best operating temperature for high-rate glycerol digestion remains unclear. To clarify these gaps, the present study aimed to compare glycerol digestion in mesophilic AFBR (30 °C) and thermophilic AFBR (55 °C). In both reactors, glycerol concentration was increased from 1.0 to 7.0 g L-1 at a fixed hydraulic retention time of 24 h, resulting in an increase at the organic loading rate from 1.2 to 7.6 kg COD m-3 day-1. Thermophilic digestion of glycerol achieved superior removals of organic matter (67.7-94.2%) and methane yield (330.8 mL CH4 g-1 COD) than the mesophilic digestion (48.6-93.0% and 266.6 mL CH4 g-1 COD). Additionally, the application of the kinetic model of substrate utilization (modified Stover-Kincannon model) indicated a higher substrate utilization coefficient in the thermophilic AFBR (23.09 g L-1 day-1) than the mesophilic AFBR (7.14 g L-1 day-1). Therefore, the application of glycerol concentrations higher than 7.0 g L-1 in thermophilic AFBR should be further investigated. Also, given only operational results, the application of the AFBR in the two-stage anaerobic digestion of glycerol is recommended.

Equilibrium, Thermodynamic, Reuse, and Selectivity Studies for the Bioadsorption of Lanthanum onto Sericin/Alginate/Poly(vinyl alcohol) Particles.

In a scenario of high demand, low availability, and high economic value, the recovery of rare-earth metals from wastewater is economically and environmentally attractive. Bioadsorption is a promising method as it offers simple design and operation. The aim of this study was to investigate lanthanum bioadsorption using a polymeric bioadsorbent of sericin/alginate/poly(vinyl alcohol)-based biocomposite. Batch system assays were performed to evaluate the equilibrium, thermodynamics, regeneration, and selectivity of bioadsorption. The maximum capture amount of lanthanum at equilibrium was 0.644 mmol/g at 328 K. The experimental equilibrium data were better fitted by Langmuir and Dubinin-Radushkevich isotherms. Ion exchange mechanism between calcium and lanthanum (2:3 ratio) was confirmed by bioadsorption isotherms. Thermodynamic quantities showed that the process of lanthanum bioadsorption was spontaneous (-17.586, -19.244, and -20.902 kJ/mol), endothermic (+15.372 kJ/mol), and governed by entropic changes (+110.543 J/mol·K). The reusability of particles was achieved using 0.1 mol/L HNO3/Ca(NO3)2 solution for up to five regeneration cycles. The bioadsorbent selectivity followed the order of lanthanum > cadmium > zinc > nickel. Additionally, characterization of the biocomposite prior to and post lanthanum bioadsorption showed low porosity (9.95 and 12.35%), low specific surface area (0.054 and 0.019 m2/g), amorphous character, and thermal stability at temperatures up to 473 K. This study shows that sericin/ alginate/poly(vinyl alcohol)-based biocomposites are effective in the removal and recovery of lanthanum from water.

Crosslinked alginate/sericin particles for bioadsorption of ytterbium: Equilibrium, thermodynamic and regeneration studies.

Sericin is a soluble globular protein, present in Bombyx mori silkworm cocoons. Sericin's properties can be improved to expand its application by producing blends with other substances, such as alginate polysaccharide and crosslinking agent poly(vinyl alcohol). This study evaluates the use of alginate and sericin particles chemically crosslinked with poly(vinyl alcohol) (SAPVA) for batch bioadsorption of rare-earth element ytterbium from aqueous medium. The equilibrium study showed that the maximum bioadsorption capacity for ytterbium was 0.642 mmol/g at 55 °C. Equilibrium data fit both Langmuir and Dubinin-Radushkevich models. The estimation of thermodynamic parameters showed that there was an increase in the entropy change, and that the bioadsorption process is endothermic and spontaneous. Characterization analyzes revealed that SAPVA particles, even after ytterbium bioadsorption, showed spherical shape, homogeneous composition, amorphous structure, low surface area, macropores, and low porosity. After the first regeneration cycle, the amount of captured ytterbium ions showed a slight increase (about 0.01 mmol/g) and calcium ions were completely released by SAPVA particles. Bioadsorbent particles separated selectively ytterbium from synthetic effluent containing different toxic metal ions. These results show that the SAPVA particles can be used as an effective bioabsorbent to remove and recover ytterbium from wastewater.