1.
Acta Crystallogr Sect E Struct Rep Online
; 64(Pt 1): o292, 2007 Dec 18.
Article
in English
| MEDLINE
| ID: mdl-21200857
ABSTRACT
THE TITLE COMPOUND (SYSTEMATIC NAME: 11-cyclo-propyl-4-methyl-5,11-dihydro-6H-dipyrido[3,2-b:2',3'-e][1,4]diazepin-6-one butanol 0.3-solvate), C(15)H(14)N(4)O·0.3C(4)H(9)OH, was crystallized in a new triclinic pseudopolymorphic form, a butanol solvate, and the crystal structure determined at 150â K. The mol-ecular conformation of this new form differs from that reported previously, although the main inter-molecular hydrogen-bond pattern remains the same. N-Hâ¯O hydrogen bonds [Nâ¯O = 2.957â (3)â Å] form centrosymmetric dimers and the crystal packing of this new pseudopolymorph generates infinite channels along the b axis.