Supercritical fluid technology as a sustainable alternative method for textile dyeing: An approach on waste, energy, and CO2 emission reduction.

The clothing industry is considered one of the most polluting industries on the planet due to the high consumption of water, energy, chemicals/dyes, and high generation of solid waste and effluents. Faced with environmental concerns, the textile ennoblement sector is the most critical of the textile production chain, especially the traditional dyeing processes. As an alternative to current problems, dyeing with supercritical CO2 (scCO2) has been presented as a clean and efficient process for a sustainable textile future. Supercritical fluid dyeing (SFD) has shown a growing interest due to its significant impact on environmental preservation and social, economic, and financial gains. The main SFD benefits include economy and reuse of non-adsorbed dyes; reduction of process time and energy expenditure; capture of atmospheric CO2 (greenhouse gas); use and recycling of CO2 in SFD; generation of carbon credits; water-free process; effluent-free process; reduction of CO2 emission and auxiliary chemicals. Despite being still a non-scalable and evolving technology, SFD is the future of dyeing. This review presented a comprehensive overview of the environmental impacts caused by traditional processes and confronted the advantages of SFD. The SFD technique was introduced, along with its latest advances and future perspectives. Financial and environmental gains were also discussed.

Influence of different textile fibers on characterization of dyeing wastewater and final effluent.

Textile industry needs to recover and reuse its wastewater as to fulfil the demand of increasingly strict regulations. The characterization of dyeing wastewater samples according to textile fiber and final textile effluent enables the application of different treatment methods. This study aims to characterize dyeing wastewater in black color of polyamide, polyester, and viscose fibers and final textile effluent. Samples were collected and characterized completely for major pollution indicator parameters. Dyeing wastewater of polyester showed higher values for some parameters, e.g., 4994.44% (49,944,400 mg L-1 and 917 NTU) of turbidity and 4100.00% of phenol when compared to dyeing wastewater of other fibers. Other parameters such as pH, alkalinity, color, phosphorus, nitrogen, sulfides, chlorides, oil and grease, dissolved solids, and chemical and biochemical oxygen demand were also assessed. In addition to individual characterization, this study also presents a correlation of the contribution of each parameter to the final textile effluent. Although dyeing wastewater of polyamide contributes the most in terms of quantity for the final effluent, this study revealed that dyeing wastewater of polyester influenced the most on the final composition of the textile wastewater when evaluating color, turbidity, total iron, biochemical oxygen demand, chemical oxygen demand, phenol, mercury, oil and grease, and total phosphorus. The present study is focused on bringing new insights to provide future research with other strategies to improve the treatment of dyeing wastewater. In addition, some suggestions are also given for wastewater treatments according to type of textile fiber.