Influence of drying temperature on coconut-fibers.

The use of natural fibers in cementitious composites has been gaining prominence in engineering. The natural lignocellulosic fibers (NLFs) used in these composites have advantages such as reduced density, reduced fragmentation and concrete cracking, thus improving flexural performance and durability. Coconut-fiber is one of those natural fibers and its use presents technical, ecological, social and economic benefits, as it is improperly disposed of, representing a large waste of natural resources, in addition to causing environmental pollution.. Thus, composites reinforced with natural fibers are promising materials for the construction industry, as in addition to meeting the sustainability of buildings, there will also be a reduction in urban solid waste generated and gains for structures with the use of environmentally friendly materials that meet to active efforts and with greater durability. This work aims to evaluate the tensile behavior of green coconut-fibers subjected to different drying temperatures through chemical, thermal (TG/DSC), morphological, visual and mechanical analysis. Drying temperatures of 70 °C, 100 °C and 130 °C were analyzed and the results indicated that the drying temperature at 70 °C was satisfactory, providing fiber-reinforced composites with good tensile strength, combined with good ductility.

Influence of Pulsed Arc Parameters on the Tig Welding Process for the Stainless Steel Duplex UNS S31803.

The influence of parameters involved in the pulsed electric arc, used as an energy source in the tungsten inert gas (TIG)-mediated welding of Duplex UNS S31803 stainless steel, to attend the manufacture of flexible pipes for the extraction of oil and gas is presented. A fundamental part in the manufacturing process of flexible pipelines is the welding of these strips so that corresponding TIG welds will be subjected to the same process and work conditions. Therefore, it is necessary to maintain the same properties in the welded regions. Covering the effects of each parameter of the pulsed electric arc such as peak and base current as welds, cyclic ratio, and pulsation frequency is a desirable endeavor. The final objective is the mitigation of problems that have a great impact on production, such as weld breakage during the conformation of the strip in the process and test failures. With this, tensile, bending, and ferrite percentage tests were performed on 12 samples that qualified as satisfactory in the visual aspect. A minimum tensile strength of 734.57 MPa and a maximum of 775.77 MPa were obtained where all values found are above the tensile strength limit of the base material of 620 MPa. With the completion of the study, it is possible to understand not only the response of the process to each parameter but also the tendency when changing them. Moreover, it is possible to explore the possibility of guiding the changes to achieve results about the visual aspect and the mechanical properties of the welded material.

Comparison of the Permeability of Potential Ballast Rocks from Northern Rio de Janeiro State under Different Fouling Rates after Sodium Sulfate Attack.

This paper aimed to analyze the reduction in the ballast layer permeability simulated in a laboratory in saturated conditions by the presence of rock dust as a contaminant of three types of rocks explored in different deposits in the northern region of the state of Rio de Janeiro, Brazil, through laboratory testing relating the physical properties of rock particles before and after sodium sulfate attack. Sodium sulfate attack is justified by the proximity of some sections of the planned EF-118 Vitória-Rio railway line to the coast and of the sulfated water table to the ballast bed, which could degrade the material used and compromise the railway track. Granulometry and permeability tests were performed to compare ballast samples with fouling rates of 0, 10, 20, and 40% rock dust by volume. A constant head permeameter was used to analyze hydraulic conductivity and establish correlations between the petrography and mercury intrusion porosimetry of the rocks, namely two types of metagranite (Mg1 and Mg3) and a gneisse (Gn2). Rocks, such as Mg1 and Mg3, with a larger composition of minerals susceptible to weathering according to petrography analyses, tend to be more sensitive to weathering tests. This, in conjunction with the climate in the region studied, with average annual temperature and rainfall of 27 °C and 1200 mm, could compromise track safety and user comfort. Additionally, the Mg1 and Mg3 samples showed greater percentage variation in wear after the Micro-Deval test, which could damage the ballast due to the considerable changeability of the material. The mass loss caused by abrasion due to the passage of rail vehicles was assessed by the Micro-Deval test, with Mg3 (intact rock) declining from 8.50 ± 1.5 to 11.04 ± 0.5% after chemical attack. However, Gn2, which exhibited the greatest mass loss among the samples, showed no significant variation in average wear, and its mineralogical characteristics remained almost unchanged after 60 sodium sulfate cycles. These aspects, combined with its satisfactory hydraulic conductivity rate, indicate that Gn2 is suitable for use as railway ballast in the EF-118 railway line.

Effects of Particle Size Distribution of Standard Sands on the Physical-Mechanical Properties of Mortars.

Obtained natural sands can present different particle size distributions (PSD), although they have the same mineralogical origin. These differences directly influence the physical and mechanical behavior of mortars and, therefore, the performance of mortar and ceramic renderings. Standardizing the particle size of sands based on pre-established requirements in normative standards (NBR 7214 or ASTM C778) is one way to minimize these effects. However, these standards do not consider the optimization of the granular skeleton through the analysis of bulk density and PSD, which may be insufficient to obtain satisfactory results. Therefore, this paper analyzes the effects of using different particle size ranges on the physical and mechanical behavior of cement and hydrated lime mortars. The properties of consistency index, bulk density, air content, capillary water absorption, water absorption by immersion, flexural strength, compressive strength, and dynamic modulus of elasticity were evaluated. For this purpose, standardized sands of the same mineralogical origin were made with different particle size ranges, being: (i) standardized sand constituted by 25% of coarse and fine fractions (S25-control), (ii) standardized sand constituted by 30% of coarse fraction and 20% of fine fraction (S30-20), and (iii) standardized sand composed by 40% of coarse fraction, and 10% of fine fraction (S40-10), respectively. The results indicated that variations in the particle size composition of the standardized sands are necessary to obtain mixtures with higher compactness and, therefore, mortars with better physical and mechanical performance. Thus, the dosage of the particle size fractions of standardized sand should consider the optimization of the granular skeleton, being the unit mass and the granulometric composition as important parameters to meet this premise.

Demolition Waste Potential for Completely Cement-Free Binders.

Due to renovation and fighting in the world, a huge accumulation of construction and demolition waste is formed. These materials are effectively used as aggregates, but there is very little information about the use of scrap concrete to create cementless binders. The purpose of the work is to be a comprehensive study of the composition and properties of concrete wastes of various fractions with the aim of their rational use as cementless binders. The scientific novelty lies in the fact that the nature of the processes of structure formation of a cementless binder based on sandy fractions of the screening of fragments of destroyed buildings and structures, as a complex polyfunctional system, has been theoretically substantiated and experimentally confirmed. Different percentages of non-hydrated clinker minerals in concrete scrap were determined. In the smallest fraction (less than 0.16 mm), more than 20% of alite and belite are present. Waste of the old cement paste is more susceptible to crushing compared to the large aggregate embedded in it, therefore, particles of the old cement paste and fine aggregate predominate in the finer fractions of the waste. Comprehensive microstructural studies have been carried out on the possibility of using concrete scrap as a completely cementless binder using scanning electron microscopy, X-ray diffraction analysis, and differential thermal analysis. It has been established that for cementless samples prepared from the smallest fractions (less than 0.315 mm), the compressive strength is 1.5-2 times higher than for samples from larger fractions. This is due to the increased content of clinker minerals in their composition. The compressive strength of the cementless binder after 28 days (7.8 MPa), as well as the early compressive strength at the age of 1 day after steaming (5.9 MPa), make it possible to effectively use these materials for enclosing building structures.

Recycled Aggregate: A Viable Solution for Sustainable Concrete Production.

Construction and demolition activities consume large amounts of natural resources, generating 4.5 bi tons of solid waste/year, called construction and demolition waste (C&DW) and other wastes, such as ceramic, polyethylene terephthalate (PET), glass, and slag. Furthermore, around 32 bi tons of natural aggregate (NA) are extracted annually. In this scenario, replacing NA with recycled aggregate (RA) from C&DW and other wastes can mitigate environmental problems. We review the use of RA for concrete production and draw the main challenges and outlook. RA reduces concrete's fresh and hardened performance compared to NA, but these reductions are often negligible when the replacement levels are kept up to 30%. Furthermore, we point out efficient strategies to mitigate these performance reductions. Efforts must be spent on improving the efficiency of RA processing and the international standardization of RA.

Technogenic Fiber Wastes for Optimizing Concrete.

A promising method of obtaining mineral fiber fillers for dry building mixtures is the processing of waste that comes from the production of technogenic fibrous materials (TFM). The novelty of the work lies in the fact that, for the first time, basalt production wastes were studied not only as reinforcing components, but also as binder ones involved in concrete structure formation. The purpose of the article is to study the physical and mechanical properties of waste technogenic fibrous materials as additives for optimizing the composition of raw concrete mixes. To assess the possibility of using wastes from the complex processing of TFM that were ground for 5 and 10 min as an active mineral additive to concrete, their chemical, mineralogical, and granulometric compositions, as well as the microstructure and physical and mechanical characteristics of the created concretes, were studied. It is established that the grinding of TFM for 10 min leads to the grinding of not only fibers, but also pellets, the fragments of which are noticeable in the total mass of the substance. The presence of quartz in the amorphous phase of TFM makes it possible to synthesize low-basic calcium silicate hydrates in a targeted manner. At 90 days age, at 10-20% of the content of TFM, the strength indicators increase (above 40 MPa), and at 30% of the additive content, they approach the values of the control composition without additives (above 35 MPa). For all ages, the ratio of flexural and compressive strengths is at the level of 0.2, which characterizes a high reinforcing effect. Analysis of the results suggests the possibility of using waste milled for 10 min as an active mineral additive, as well as to give better formability to the mixture and its micro-reinforcement to obtain fiber-reinforced concrete.

Effect of Polymers on Behavior of Ultra-High-Strength Concrete.

The development of ultra-high-performance concrete (UHPC) is still practically limited due to the scarcity of robust mixture designs and sustainable sources of local constituent materials. This study investigates the engineering characteristics of Styrene Butadiene Rubber (SBR) polymeric fiber-reinforced UHPC with partial substitution of cement at 0, 5 and 20 wt.% with latex polymer under steam and air curing techniques. The compressive and tensile strengths along with capillary water absorption and sulfate resistance were measured to evaluate the mechanical and durability properties. Scanning Electron Microscopy (SEM) was carried out to explore the microstructure development and hydration products in the designed mixtures under different curing regimes. The results indicated that the mixtures incorporating 20 wt.% SBR polymer achieved superior compressive strength at later ages. Additionally, the tensile strength of the polymeric UHPC without steel fibers and with 20% polymers was enhanced by 50%, which promotes the development of novel UHPC mixtures in which steel fibers could be partially replaced by polymer, while enhancing the tensile properties.

Mechanical and Physical Properties of Particleboard Made from the Sumatran Elephant (Elephas maximus sumatranus) Dung and Wood Shaving.

Sumatran elephants (Elephas maximus sumatranus) are the world's largest living land mammals. The elephant's digestive system can only absorb 40% of the nutrients in digested feed, and the remainder is excreted as dung. Elephant dung waste can be used as a particleboard material due to its high fiber content. The objectives of this study are: (i) to prepare elephant dung waste as raw material for particleboard, (ii) to improve elephant dung particleboard's physical and mechanical properties using wood shavings, and (iii) to study the influence of several parameters on the physical and mechanical properties of particleboard. The particleboard dimensions and density were set at 20 cm × 20 cm × 1 cm and 0.8 g/cm3, respectively. The mixture ratio of elephant dung and wood shavings was 100/0, 90/10, 80/20, 70/30, 60/40, and 50/50 (% w/w). This mixture ratio of particles was sprayed with 7% isocyanate adhesive. The pressing at a pressure of 30 kg/cm2 for 5 min and 160 °C was used in this study. The physical and mechanical properties of particleboard were tested according to JIS A 5908 (2003) standard. The result shows that the addition of wood shaving improved the elephant dung particleboard's physical and mechanical properties. Except for moisture content and water absorption, the addition of wood shavings has a significant effect on elephant dung particleboard's physical and mechanical properties. The best ratio of elephant dung and wood-shaving for this research is 50/50 and has fulfilled the JIS A 5908-2003 standard, except for thickness swelling.

Water reuse in industries: analysis of opportunities in the Paraíba do Sul river basin, a case study in Presidente Vargas Plant, Brazil.

In recent years, the demand for clean water has been growing all over the world despite the different threats posed, including increasing pollution, increasing deforestation and climate change. Industrial activity is the second largest consumer of water, so highly industrialized regions are more susceptible to water stress. In this sense, reuse strategies have been progressively discussed and used around the world; however, in Brazil there is still place for many advances, whether due to lack of incentives, cultural issues in society, or poor regulation of the subject. The objective of this work was to carry out a diagnosis of raw water uptake by industries in one Hydrographic Region of the state of Rio de Janeiro and to propose a discussion on the adoption of water reuse practices for non-potable purposes from the use of treated effluents. A survey of the theoretical framework on the subject was carried out, as well as an analysis of sustainability indicators and reports of the companies, including the current licensing processes of large undertakings consuming water resources. With this study, it was possible to obtain the average cost of implementing a water reuse unit for an industry in the state of Rio de Janeiro-Brazil, which, despite still being expensive, has a strong tendency to use due to world water shortages. Finally, it was concluded that the state of Rio de Janeiro has a threat of water scarcity that could be aggravated in the coming years, if measures and investments in supply alternatives are not adopted (water reuse), and improvement in all stages of water management water resources.

Experimental Findings and Validation on Torsional Behaviour of Fibre-Reinforced Concrete Beams: A Review.

Fibres have long been utilized in the construction sector to improve the mechanical qualities of structural elements such as beams, columns, and slabs. This study aims to review the torsional behaviour of various forms of fibre reinforced concrete to identify possible enhancements and the practicability of concrete structural beams. Concrete reinforced steel fibre, synthetic fibre, and hybrid fibre are examples of fibre reinforced concrete. The review found that the mixing, orientation, and volume of fibres, the size of coarse particles, the aspect ratio of fibres, and the stiffness of fibres all affect the torsional strength of fibre reinforced concrete. Nevertheless, the application of fibres to recycled self-consolidating concrete of various forms needs to be explored and studied to ascertain its feasibility to facilitate greener concrete. Thus, with the results compiled in this review paper, it was possible to delimit advances and gaps on the effect of editing reinforcement fibres in relation to the torsion of structural elements.

Potential of Using Amazon Natural Fibers to Reinforce Cementitious Composites: A Review.

The engineering application of natural lignocellulosic fibers (NLFs) has been intensifying all over the world due to their low cost and abundance, as well as their being eco-friendly and presenting favorable technological properties in polymeric and cementitious composites. Brazil, especially the Amazon region, owing to its climate and geographic position, has an abundant variety of NLFs that are still unexplored with great potential for use in various composite materials and applications such as civil construction, automobile parts and armor. Therefore, this review aims to establish a parallel between the technological properties of cementitious composites reinforced with Amazon NLFs, both in fresh and hardened states, and to analyze, compare results and contribute to a better understanding of the similarities and differences between the types of reinforcements. A relevant contribution of this review is the possibility of improving knowledge about Amazon NLFs, showing their potential for application in eco-friendly materials, in addition to contributing to studies with new NLFs not yet applied in composite. For this, it was necessary to carry out a literature survey on the physical, chemical and mechanical properties of cementitious composites reinforced with NLFs, in addition to analyzing case studies involving fibers such as curaua, açai, bamboo, jute and sisal. It can be concluded that the physical and chemical characteristics of the Amazon NLFs directly influence the technological properties of cementitious compounds, such as mechanical strength and water absorption. However, there might be a need for surface treatment aimed at improving adhesion and durability of the cementitious composite. Finally, some suggestions for future research work are highlighted in order to show the need to continue investigations on the application of Amazon NLFs in cementitious composites.

Effect of Ornamental Stone Waste Incorporation on the Rheology, Hydration, Microstructure, and CO2 Emissions of Ordinary Portland Cement.

The ornamental stone industry generates large amounts of waste thus creating environmental and human health hazards. Thus, pastes with 0-30 wt.% ornamental stone waste (OSW) incorporated into ordinary Portland cement (OPC) were produced and their rheological properties, hydration kinetics, and mechanical properties were evaluated. The CO2 equivalent emissions related to the pastes production were estimated for each composition. The results showed that the paste with 10 wt.% of OSW exhibited similar yield stress compared to the plain OPC paste, while pastes with 20 and 30 wt.% displayed reduced yield stresses up to 15%. OSW slightly enhanced the hydration kinetics compared to plain OPC, increasing the main heat flow peak and 90-h cumulative heat values. The incorporation of OSW reduced the 1-, 3-, and 28-days compressive strength of the pastes. Water absorption results agreed with the 28 days compressive strength results, indicating that OSW increased the volume of permeable voids. Finally, OSW incorporation progressively reduced the CO2 emission per m3 of OPC paste, reaching a 31% reduction for the highest 30 wt.% OSW content. Overall, incorporating up to 10 wt.% with OSW led to pastes with comparable fresh and hardened properties as comported to plain OPC paste.

Life cycle approach applied to the production of ceramic materials incorporated with ornamental stone wastes.

The use of the ornamental stone wastes, such as the originated from granite or marble, has been the subject of technological studies that evaluated its application in ceramic and cement materials; however, some complementary assessments, such as its life cycle assessment, are still not well explored in the literature. Therefore, the objective of this study was to discuss the main environmental impacts related to the manufacture of ceramic specimens, comparing conventional production versus the production of specimens incorporated with ornamental stone wastes. For this, the life cycle assessment was conducted in accordance with ISO 14.040 and 14.044. For this research, the ornamental stone wastes from the municipality of Cachoeiro do Itapemirim-ES and clay from the municipality of Campos dos Goytacazes-RJ were used. The system was modeled, using the SimaPro 9.0 software and the Ecoinvent database 3.3, for the life cycle assessment of the ceramic specimens and the potentiality regarding the use of ornamental stone wastes in ceramic materials using alternative input energy for burning, contributing to the effectiveness of the solid wastes reuse by the ceramic industry. The evaluation identified that the ornamental stone wastes incorporated into the ceramic specimens had significant potential in reducing environmental impacts and that the alternative input energy in burning stage makes them even more relevant. The study points out as the main result, the reduction of 35.74% of the impacts related to the category of the emission of greenhouse gases, and scarcity of mineral resources, 14.83% reduction, when compared to specimens to conventional brick production and alternative brick production, which emphasizes that the ceramic materials with wastes contribute to the mitigation of impacts.

Influence of Ultrasonication of Functionalized Carbon Nanotubes on the Rheology, Hydration, and Compressive Strength of Portland Cement Pastes.

The functionalization process usually increases the localized defects of carbon nanotubes (CNT). Thus, the ultrasonication parameters used for dispersing non-functionalized CNT should be carefully evaluated to verify if they are adequate in dispersing functionalized CNT. Although ultrasonication is widely used for non-functionalized CNT, the effect of this dispersing process of functionalized CNT has not been thoroughly investigated. Thus, this work investigated the effect of ultrasonication on functionalized CNT + superplasticizer (SP) aqueous dispersions by ultraviolet-visible (UV-Vis) spectroscopy, dynamic light scattering (DLS), and Fourier transform infrared spectroscopy (FTIR). Furthermore, Portland cement pastes with additions of 0.05% and 0.1% CNT by cement weight and ultrasonication amplitudes of 0%, 50% and 80% were evaluated through rheometry, isothermal calorimetry, compressive strength at 1, 7 and 28 days, X-ray diffraction (XRD), and thermogravimetric analysis (TGA). FTIR results from CNT + SP dispersions indicated that ultrasonication may negatively affect SP molecules and CNT graphene structure. The increase in CNT content and amplitude of ultrasonication gradually increased the static and dynamic yield stress of paste but did not significantly affect its hydration kinetics. Compressive strength results indicated that the optimum CNT content was 0.05% by cement weight, which increased the strength of composite by up to 15.8% compared with the plain paste. CNT ultrasonication neither increases the degree of hydration of cement nor the mechanical performance of composite when compared with mixes containing unsonicated CNT. Overall, ultrasonication of functionalized CNT is not efficient in improving the fresh and hardened performance of cementitious composites.

Natural Fibers as an Alternative to Synthetic Fibers in Reinforcement of Geopolymer Matrices: A Comparative Review.

Geopolymer materials have been gaining ground in the civil construction sector not only for having superior physical properties when compared to conventional cement, but also for being less harmful to the environment, since the synthesis of the geopolymer does not release toxic gases or require high energy costs. On the other hand, geopolymer materials like cementitious matrices have low flexural strength and have fragile breakage. To overcome these deficiencies, the insertion of fibers in geopolymeric matrices has been evaluated as a solution. Although most research on this practice focuses on the use of synthetic fibers, the use of natural fibers has been growing and brings as an advantage the possibility of producing an even more ecological material, satisfying the need to create eco-friendly materials that exists today in society. Thus, this paper aimed to, through the evaluation of research available in the literature, understand the behavior of fibers in geopolymer matrices, identify similarities and differences between the performance of geopolymer composites reinforced with natural and synthetic fibers and, understanding that it is possible, point out ways to optimize the performance of these composites.

Recycled PET Sand for Cementitious Mortar.

Cementitious materials cause a great impact on the environment due to the calcination of clinker and the extraction of non-renewable mineral resources. In this work, the replacement of quartz sand from the river by PET sand was evaluated at levels of 10%, 20%, and 30%. Tests were performed in the fresh state through consistency, air retention, density, and incorporated air and in the hardened state for compressive strength, flexural strength, density, capillarity, and water absorption. The results show that PET sand is viable in contents of up to 10%, improving the mechanical properties of the mortar and without compromising its workability and incorporated air properties. Above that level, the loss of properties is very excessive, mainly of workability and incorporated air. The incorporated air of the 30% composition, for example, reaches 24%, an excessive value that impacts the properties of the hardened state, making it impossible to use the material at levels greater than 20%. It is concluded that the use of recycled PET sand is a possibility that contributes to sustainable development, as it reduces the extraction of quartz sand from the river, a non-renewable mineral resource.

Characterizing the paper industry sludge for environmentally-safe disposal.

The world paper industry produces a great amount of industrial solid waste that undergoes a treatment process that can be either primary, secondary, or tertiary, in order to adapt the waste for correct disposal. The paper manufacturing industries search for the best way to dispose of their wastes, generally in landfills, but there are few studies proving the effectiveness of such measure from the environmental, technological and economic points of view. Knowing the characteristics of this waste and understanding the treatment process it is submitted to are fundamental issues to manage it and comply with environmental demands. The purpose of this paper is to perform a chemical, mineralogical, thermal, morphological, physical and environmental characterization of the paper and pulp industry wastes, in order to assess alternatives for their adequate disposal, such as controlled landfills, sanitation, incineration, and sea dumping. It was observed that the material presents physical, chemical, and morphological features that indicate the possibility of reusing it in other production chains, such as the ceramic industry, besides being classified as non-hazardous wastes. Furthermore, disposal in sanitary landfills presents advantages in environmental and technological terms.