Evaluation of aircraft deicing fluid as an external carbon source for denitrification.

Water resource recovery facilities (WRRFs) performing biological nitrogen removal (BNR) often require external carbon sources for meeting nitrogen discharge permit limits. This brings an additional financial burden to the facilities considering the continuous need of these external carbon sources. This paper evaluates the utilization of airport stormwater, which in the winter season is rich in aircraft deicing fluid (ADF) as an alternative external carbon source. Denitrification and nitrification bench scale experiments were performed to assess the efficacy of external carbon sources to remove nitrogen in WRRFs. Experimental results showed that ADFs achieve denitrification rates of 0.064-0.066 d-1, higher than what achieved by a commercial carbon source, MicroC 2000A, with corresponding value of 0.058 d-1 at low temperatures, as low as 13 °C, which is considered a worst-case scenario for nitrogen removal efficiency. Furthermore, no inhibition to nitrification associated with the ADFs was observed. Subsequently a dynamic modeling study was conducted to assess the performance of ADFs as external carbon sources for denitrification and compared them to the conventional source that was being used in a full-scale BNR process. Results from the dynamic modeling study revealed that if 40 % of the spent-ADF at LaGuardia airport, New York City, could be collected with the stormwater and conveyed to a WRRF via the sewer collection system, an approximate reduction of 30 % of the commercial external carbon source could be accomplished by repurposing a waste product. This study contributes to the potential of ADF as a denitrification aid and an alternative for commercially available carbon sources with comparable nitrogen removal efficiencies.

Mesoporous Silicas Obtained by Time-Controlled Co-Condensation: A Strategy for Tuning Structure and Sorption Properties.

Mesoporous silicas synthesized by the co-condensation of two and three different silica monomers were synthesized by varying the time intervals between the addition of individual monomers, while the total time interval was kept constant. This resulted in different structural properties of the final silicas, particularly in their porosity and local ordering. One of the obtained samples exhibited an unusual isotherm with two hysteresis loops and its total pore volume was as high as 2.2 cm3/g. In addition, to be thoroughly characterized by a wide range of instrumental techniques, the obtained materials were also employed as the adsorbents and release platforms of a diclofenac sodium (DICL; used here as a model drug). In the case of DICL adsorption and release, differences between the samples were also revealed, which confirms the fact that time control of a monomer addition can be successfully used to fine-tune the properties of organo-silica materials.

Empowering carbon materials robust gas desulfurization capability through an inclusion of active inorganic phases: A review of recent approaches.

Gas-phase desulfurization on carbon materials is an important process attracting the attention of scientists and engineers. When involving physical adsorption, reactive adsorption and catalytic oxidation combined, the process is considered as energy-efficient. Recent developments in materials science directed the attention of researchers to inorganic phases which react with H2S and participate to its oxidation to elemental sulfur. To fully utilize their capability, a developed surface area is needed and this feature is delivered by carbons. This review presents examples of recent advances in this field with focus not only on the activity of inorganic phases, dispersed on the surface or introduced as nanoparticles, but also on the important contribution of a carbon support as providing specific synergistic effects. The active phase promotes the H2S oxidation and participates in the reactions with H2S, while the carbon phase ensures its high dispersion, adds to oxygen activation and to an efficient electron transfer.

Alternative view of oxygen reduction on porous carbon electrocatalysts: the substance of complex oxygen-surface interactions.

Electrochemical oxygen reduction reaction (ORR) is an important energy-related process requiring alternative catalysts to expensive platinum-based ones. Although recently some advancements in carbon catalysts have been reported, there is still a lack of understanding which surface features might enhance their efficiency for ORR. Through a detailed study of oxygen adsorption on carbon molecular sieves and using inelastic neutron scattering, we demonstrated here that the extent of oxygen adsorption/interactions with surface is an important parameter affecting ORR. It was found that both the strength of O2 physical adsorption in small pores and its specific interactions with surface ether functionalities in the proximity of pores positively influence the ORR efficiency. We have shown that ultramicropores and hydrophobic surface rich in ether-based groups and/or electrons enhance ORR on carbon electrocatalysts and the performance parameters are similar to those measured on Pt/C with the number of electron transfer equal to 4.

Proposing an unbiased oxygen reduction reaction onset potential determination by using a Savitzky-Golay differentiation procedure.

For proper and fair comparison of the performance of Oxygen reduction reaction (ORR) electrocatalysts an un-biased method to determine an onset potential value is needed. Here we report an easy mathematical approach based on the second derivative of linear sweep voltammetry curves, referred to as a second order discrete differentiation method (SODDM) that allows to accurately provide the onset potential. Analysis of the published results showed that the reported values might be affected by an intrinsic human error associated with the application of the most common approaches addressed as a tangent method or those relaying on a visual estimation of the onset potential based on the shape of a linear scan voltammetry (LSV) curve. We have also demonstrated that by using SODDM, electrochemical data collected on different instruments by different researchers leads to comparable results in terms of the ORR onset potential values.

A New Generation of Surface Active Carbon Textiles As Reactive Adsorbents of Indoor Formaldehyde.

Highly porous carbon textiles were modified by impregnation with urea, thiourea, dicyandiamide, or penicillin G, followed by heat treatment at 800 °C. This resulted in an incorporation of nitrogen or nitrogen and sulfur heteroatoms in various configurations to the carbon surface. The volume of pores and, especially, ultramicropores was also affected to various extents. The modified textiles were then used as adsorbents of formaldehyde (1 ppmv) in dynamic conditions. The modifications applied significantly improved the adsorptive performance. For the majority of samples, formaldehyde adsorption resulted in a decrease in the volume of ultramicropores. The enhancement in the adsorption was linked not only to the physical adsorption of formaldehyde in small pores but also to its reactivity with sulfonic groups and amines present on the surface. Water on the surface and in challenge gas decreased the adsorptive performance owing to the competition with formaldehyde for polar centers. The results collected show that the S- and N-modified textiles can work as efficient media for indoor formaldehyde removal.