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Acta Crystallogr Sect E Struct Rep Online
; 64(Pt 1): o177, 2007 Dec 06.
Article
in English
| MEDLINE
| ID: mdl-21200740
ABSTRACT
The title compound, C(13)H(12)N(4)O, crystallizes with two independent mol-ecules in the asymmetric unit. The compound crystallizes as the ZE isomer, where Z and E refer to the configuration around the C=N and N-C bonds, respectively, with an N-Hâ¯N(py) (py is pyridine) intra-molecular hydrogen bond. The dihedral angles between the least-squares planes through the semicarbazone group and the pyridyl ring are 22.70â (9) and 27.26â (9)° for the two mol-ecules. There are intermolecular N-Hâ¯O hydrogen bonds.