Spring-In Prediction of CFRP Part Using Coupled Analysis of Forming and Cooling Processes in Stamping.

The spring-in phenomenon of the composite parts can affect the assembly process. This study aims to predict the spring-in phenomenon of a carbon fiber reinforced plastic (CFRP) part. Here, we predict the spring-in of the CFRP part using a coupled analysis of the forming and cooling processes during the stamping process. First, a simulation of the entire forming process, such as the transfer of the composite laminate, gravity analysis, and forming was performed to obtain the temperature distribution of the CFRP part. Subsequently, a finite-element (FE) simulation of the cooling process was conducted to predict the spring-in phenomenon of the shaped CFRP part using the temperature data obtained in the forming simulation. Finally, a CFRP part was manufactured and compared with the results of the FE simulation.

An Integrated Model of Heat Transfer in Meat Products during Multistage Operations.

This work focuses on the modelling of the heat transfer in the key processes during the manufacturing of salted-smoked loin pork, a traditional Danish product called "Hamburgerryg". Drying, smoking, steam-cooking, water-cooling, and air-cooling processes are important process steps in the production of "Hamburgerryg". A mathematical model that describes the heat transfer during these processes was developed. A current model formulation, multiple unit operations, and the transfer between these unit operations were considered and described by an equation that combines boundary conditions. The model governing and boundary equations were solved using the finite element method (COMSOL Multi-physics® version 5.6). The product temperature profile during the processes was predicted as a function of position and time in the loin. The model was validated using measured temperature profiles from industrial production, and a good agreement between the measured and simulated temperature profiles was obtained. Additionally, the effects of the position (in the heating, cooking, and cooling chamber) on the temperature profile were also investigated. The obtained model can be used as a simulation tool to predict the temperature profile (particularly cold and hot spots) for entire processes and this can aid in the digitization of food processes by providing a more accurate and efficient means of temperature control.

Further experimental results on modelling and algebraic control of a delayed looped heating-cooling process under uncertainties.

The aim of this research is to revise and substantially extend experimental modelling and control of a looped heating-cooling laboratory process with long input-output and internal delays under uncertainties. This research follows and extends the authors' recent results. As several significant improvements regarding robust modelling and control have been reached, the obtained results are provided with a link and comparison to the previous findings. First, an infinite-dimensional model based on mathematical-physical heat and mass transfer principles is developed. All important heat-fluid transport and control-signal delays are considered when assembling the model structure and relations of quantities. Model parameter values optimization based on the measurement data follows. When determining static model parameter values, all variations in steady-state measured data are taken into account simultaneously, which enhances previously obtained models. Values of dynamic model parameters and delays are further obtained by least mean square optimization. This innovative model is compared to two recently developed process models and to the best-fit model that ignores the measured variations. Controller structures are designed using algebraic tools for all four models. The designed controllers are robust in the sense of robust stability and performance. Both concepts are rigorously assessed, and the obtained conditions serve for controller parameter tuning. Two different control systems are assumed: the standard closed-loop feedback loop and the two-feedback-controllers control system. Numerous experimental measurements for nominal conditions and selected perturbations are performed. Obtained results are further analyzed via several criteria on manipulated input and controlled temperature. The designed controllers are compared to the Smith predictor structure that is well-established for time-delay systems control. An essential drawback of the predictor regarding disturbance rejection is highlighted.

Evaluation of the effects of thermal changes on the bond strength between zirconia framework and veneering ceramic during the firing process.

Purpose: The aim of this in-vitro study was to evaluate the effect of thermal changes to shear bond strength during the firing process of veneering porcelain on a zirconia framework. Materials and methods: Single yttria-stabilized tetragonal zirconia polycrystal (Y-TZP) framework ceramic (Kavo Dental GmbH) and three different types of veneering ceramics (IPS e.max Ceram, Vita VM9, and GC Initial Zr-FS) were used. One-hundred-twenty standard disc-shaped samples were prepared from zirconia blocks by using a CAD/CAM system (Kavo Everest). Four different cooling processes (maximum, 25°C/min, 50°C/min and 75°C/min) were applied to the veneering ceramics and the shear bond strength (SBS) test was performed. Ceramic surfaces were investigated by using scanning electron microscopeic (SEM). The possible occurrence of a t-m transformation of zirconia was evaluated by X-Ray Diffraction (XRD). Two-way analysis of variance, Bonferroni correction and paired comparisons were used for statistical analysis. Results: The main effects of veneering ceramics on shear bond strength were found to be significant (p=0.042). The mean shear bond strength values differ according to the cooling process (p<0.001). The monoclinic phase ratio increased in groups with fast cooling process. Conclusion: The thermal changes during the firing process of veneering porcelain on a zirconia framework influenced the shear bond strength of the all-ceramic bilayered system. A slow cooling process provided higher strength for bilayer ceramic samples.

Atomic-Scale Homogeneous RuCu Alloy Nanoparticles for Highly Efficient Electrocatalytic Nitrogen Reduction.

Ruthenium (Ru) is the most widely used metal as an electrocatalyst for nitrogen (N2 ) reduction reaction (NRR) because of the relatively high N2 adsorption strength for successive reaction. Recently, it has been well reported that the homogeneous Ru-based metal alloys such as RuRh, RuPt, and RuCo significantly enhance the selectivity and formation rate of ammonia (NH3 ). However, the metal combinations for NRR have been limited to several miscible combinations of metals with Ru, although various immiscible combinations have immense potential to show high NRR performance. In this study, an immiscible combination of Ru and copper (Cu) is first utilized, and homogeneous alloy nanoparticles (RuCu NPs) are fabricated by the carbothermal shock method. The RuCu homogeneous NP alloys on cellulose/carbon nanotube sponge exhibit the highest selectivity and NH3 formation rate of ≈31% and -73 µmol h-1 cm-2 , respectively. These are the highest values of the selectivity and NH3 formation rates among existing Ru-based alloy metal combinations.

Realization of Low-wax Lipstick by Rubber Molding Technology.

Reducing the quantity of wax in lipstick can improve the properties of the lipstick, including the glossiness, moisturizing capability, and longevity. However, lipsticks with less wax tend to break more easily. Therefore, to prevent breakage while reducing the wax content, we focused on the crystal structure of the wax gel and strain generated during the cooling and solidification processes as they are structural factors that affect fragility. Generally, if the crystals and strain are small, the structure is less easily broken. However, because the tip of the lipstick cools more rapidly from below than the root, the strain of the root against the tip increases owing to poor heat transmission. This creates large shrink holes in the root. While reheating from above can suppress the generation of shrink holes, it also causes the crystals to grow larger and the structure to become weak owing to slow cooling. Therefore, we adopted a rubber-molding technology generally used to form logos and complicated shapes as a strategy to mitigate these issues. This successfully reduced the strain generated inside the lipstick during the cooling process, as the rubber mold shrunk along with the lipstick, making it possible to quench the root. Therefore, we were able to realize a small crystal structure and low strain on the root of the lipstick. Our results demonstrate that it is possible to realize a lipstick with excellent features by reducing the quantity of wax.

[Case Study:Identification of Microbial Distribution and Contamination Source by PDCA Cycle at a Boiled Noodles Factory].

Boiled noodles are considered to be one of the most perishable foods due to their high moisture content and high water activity. Thus, the hygiene control measures based on HACCP manuals has been recommended in the noodle manufacturing industry. However, there were several cases in which post-packaged products manufactured at the Boiled noodles factory of small-to-medium size company detected a viable cell count higher than their voluntary standards. To identify the source of microbial contamination, an investigation based on the Plan-Do-Check-Act (PDCA) cycle was conducted. The results showed that the bacteria causing the contamination were environmental bacteria. Secondary contamination occurred during the cooling process after sterilization. Airborne environmental bacteria and oxygen may have been introduced into the rinsing and cooling water tank by the strong water flow during the rinsing and cooling process, inducing growth of microorganisms in the cooling water and contaminating the final product. This is a new finding, as such occurrence was not listed in the HACCP manual and should be contributed to plan HACCP system.

Recent advances in multiscale CFD modelling of cooling processes and systems for the agrifood industry.

Spoilage of agrifood produce is a major issue in the industry. Cooling is an effective technique for extending the shelf life of fresh agrifood produce to minimize spoilage. Due to the practical inability of directly solving the wide spatial and temporal scales in large industrial agrifood cooling systems, the porous medium approach is mostly used. However, improvements of current porous medium models and modeling across much wider scales are needed to better understand the multiscale cooling process and system problems. Recently, as a result of increased computational capacity, multiscale computational fluid dynamics (CFD) modeling approaches have been developed to tackle some of these challenges. The associated problems and applications of CFD in the design and process optimization of cooling processes and systems at different scales are considered. CFD solution and scale bridging techniques relevant for handling multiscale cooling processes and systems problems are discussed. Innovative applications of various CFD modeling techniques at different scales in cooling processes and systems are reviewed. CFD modeling techniques can be used to handle multiscale cooling process and system problems. Lattice Boltzmann method (LBM) is a potentially viable discrete modeling technique for complimentary usages alongside current continuum techniques in future multiscale CFD modeling. The multiscale CFD modeling paradigm can overcome the computational resource limitations associated with the direct modeling approach and enhance model extension across wider spatial and temporal scales. Information from multiscale CFD could be used to improve the accuracy of current porous medium models, and thus the design of more efficient cooling systems.

The Effect of the Cooling Process on the Crystalline Morphology and Dielectric Properties of Polythene.

In this study, LDPE samples were prepared by melt blending with different cooling processes, which were natural air cooling, rapid air cooling, water cooling and oil cooling, respectively. According to polarization microscope (PLM) and differential scanning calorimeter (DSC) tests of these four low-density polyethylene (LDPE) samples, the effect of different cooling processes on polythene crystalline morphology could be studied. According to conductivity, dielectric frequency spectra and space charge tests, the effect of crystalline morphology on dielectric macroscopic properties could be explored. The microstructure characteristic results indicated the cooling medium significantly affected polythene crystalline morphology. When the samples were produced with natural air cooling, the crystalline grain size was large. On the other hand, after rapid air cooling, water cooling and oil cooling processes, the samples' crystalline grain dispersed uniformly, and the grain sizes were lower. The space charge testing results indicate the samples produced with water cooling and oil cooling processes restrained the electrode injection in the process of pressurization. During short-circuits, the rates of charge release of these two samples were fast, and the remaining space charges were fewer. The conductivity and dielectric frequency spectra testing results indicated the conductivities of samples produced with water cooling and oil cooling processes were both less than those of samples produced with a natural air cooling process. Besides, with increasing experimental frequency, the relative dielectric constants of all testing samples decreased. Among them, the relative dielectric constant of the LDPE sample with the natural air cooling process was the largest. However, the crystalline structures of samples produced with rapid air cooling and water cooling processes were close, which restrained the movement of polymer macromolecule chains. Thus, the dielectric constants were lower. Additionally, because of the influence of relaxation polarization and dipole polarization, the dielectric losses of LDPE with water cooling and oil cooling processes increased to varying degrees.

Research on the Microstructures and Mechanical Properties of Bainite/Martensite Rail Treated by the Controlled-Cooling Process.

A bainite/martensite multiphase rail is treated by the controlled-cooling process with different finish-cooling temperatures. The simulated temperature-time curves of the position of 5 mm and 15 mm below the rail tread (P5 and P15) express different trends. P5 has greater impact toughness and lower tensile strength than P15. Microstructural characterization was carried out by conducting scanning electron microscopy, X-ray diffraction, electron backscatter diffraction, and transmission electron microscopy. The greater tensile strength is due to the dispersed ε-carbides hindering the movement of dislocations. The greater impact toughness is attributed to the filmy retained austenite and the smaller effective grain with high-angle boundary. Finite element modeling (FEM) and microstructural characterization reasonably explain the changes of mechanical properties. The present work provides experimental and theoretical guidance for the development of rail with excellent mechanical properties.

3D Viscoplastic Finite Element Modeling of Dislocation Generation in a Large Size Si Ingot of the Directional Solidification Stage.

Growing very large size silicon ingots with low dislocation density is a critical issue for the photovoltaic industry to reduce the production cost of the high-efficiency solar cell for affordable green energy. The thermal stresses, which are produced as the result of the non-uniform temperature field, would generate dislocation in the ingot. This is a complicated thermal viscoplasticity process during the cooling process of crystal growth. A nonlinear three-dimensional transient formulation derived from the Hassen-Sumino model (HAS) was applied to predict the number of dislocation densities, which couples the macroscopic viscoplastic deformation with the microscopic dislocation dynamics. A typical cooling process during the growth of very large size (G5 size: 0.84 m × 0.84 m × 0.3 m) Si ingot is used as an example to validate the developed HAS model and the results are compared with those obtained from qualitatively critical resolved shear stress model (CRSS). The result demonstrates that this finite element model not only predicts a similar pattern of dislocation generation with the CRSS model but also anticipate the dislocation density quantity generated in the Si ingot. A modified cooling process is also employed to study the effect of the cooling process on the generation of the dislocation. It clearly shows that dislocation density is drastically decreased by modifying the cooling process. The results obtained from this model can provide valuable information for engineers to design a better cooling process for reducing the dislocation density produced in the Si ingot under the crystal growth process.

Fabrication of Uniform Wrinkled Silica Nanoparticles and Their Application to Abrasives in Chemical Mechanical Planarization.

A simple one-pot method is reported for the fabrication of uniform wrinkled silica nanoparticles (WSNs). Rapid cooling of reactants at the appropriate moment during synthesis allowed the separation of nucleation and growth stages, resulting in uniform particles. The factors affecting particle size and interwrinkle distance were also investigated. WSNs with particle sizes of 65-400 nm, interwrinkle distances of 10-33 nm, and surface areas up to 617 m2 g-1 were fabricated. Furthermore, our results demonstrate the advantages of WSNs over comparable nonporous silica nanospheres and fumed silica-based products as an abrasive material in chemical mechanical planarization processes.

High-Throughput Sequencing of Viable Microbial Communities in Raw Pork Subjected to a Fast Cooling Process.

This study aimed to investigate the effect of the fast cooling process on the microbiological community in chilled fresh pork during storage. We established a culture-independent method to study viable microbes in raw pork. Tray-packaged fresh pork and chilled fresh pork were completely spoiled after 18 and 49 d in aseptic bags at 4 °C, respectively. 16S/18S ribosomal RNAs were reverse transcribed to cDNA to characterize the activity of viable bacteria/fungi in the 2 types of pork. Both cDNA and total DNA were analyzed by high-throughput sequencing, which revealed that viable Bacteroides sp. were the most active genus in rotten pork, although viable Myroides sp. and Pseudomonas sp. were also active. Moreover, viable fungi were only detected in chilled fresh pork. The sequencing results revealed that the fast cooling process could suppress the growth of microbes present initially in the raw meat to extend its shelf life. Our results also suggested that fungi associated with pork spoilage could not grow well in aseptic tray-packaged conditions.

The impact of thermal treatment and cooling methods on municipal solid waste incineration bottom ash with an emphasis on Cl.

Municipal solid waste incineration (MSWI) bottom-ash products possess qualifications to be utilized in cement production. However, the instant use of bottom ash is inhibited by a number of factors, among which the chlorine (Cl) content is always strictly restricted. In this paper, the unquenched MSWI bottom ash was used as the experimental substance, and the influences of thermal treatment and cooling methods on the content and existence of Cl in the ash residues were investigated. The characterization of the MSWI bottom-ash samples examined by utilizing X-ray diffraction, optical microscopy, scanning electron microscopy/energy dispersive X-ray spectroscopy. The experimental results show that as a function of thermal treatment, the reduction rate of Cl is slight below 15.0%, which is relatively low compared with water washing process. Different cooling methods had impacts on the existing forms of Cl. It was understood that most of Cl existed in the glass phase if the bottom ash was air cooled. Contrarily in case of water-quenched bottom ash, Cl could also be accumulated in the newly-formed quench products as chloride salts or hydrate substances such as Friedel's salt.

Effects of glycerol and sugar mixing temperature on the morphologic and functional integrity of cryopreserved ram sperm.

Sperm deep freezing procedures for ram semen have considerable variations regarding the steps being employed for cooling, freezing, and addition of cryoprotectants. In this work, we evaluated the effects of the addition of glycerol and/or the disaccharides sucrose and trehalose to hypertonic diluents either before or after cooling from 30 °C to 5 °C in Merino Australian ram semen cryopreservation. Using optical and transmission electron microscopy techniques, we assessed that glycerol was beneficial to the cooling process independently of its addition at 30 °C or 5 °C in terms of sperm membrane integrity in different regions of the plasma membrane (acrosomal region, 14.5% higher integrity; postacrosomal region, 8.0% higher integrity [P < 0.01]; hypoosmotic swelling test [HOST], 10.8% higher integrity [P < 0.001]). Disaccharides were necessary for a better cryopreservation in liquid nitrogen, and the best procedure was their addition after cooling at 5 °C (12% higher sperm motility [P < 0.001]; 8% higher acrosome integrity, [P < 0.05]; 9.5% higher plasma membrane integrity assessed by HOST [P < 0.001]). Trehalose showed a greater preservation cryoprotectant capacity than sucrose, as indicated by sperm motility after thawing (8.1% greater [P < 0.01]) and by the integrity of the intermediate piece (20% greater [P < 0.05]). From these results, we conclude that the best procedure for ram semen cryopreservation in hypertonic disaccharide-containing diluents is the addition of glycerol and trehalose after the cooling process, at 5 °C.

Economia de escala no processo de resfriamento do leite / Economies of scale in the milk cooling process

Objetivou-se, neste artigo, estimar os custos envolvidos no processo de resfriamento do leite cru, tipo B, após a implantação da Instrução Normativa 51 e a verificação das possíveis fontes de economias de escala nesse processo. A partir dos conceitos da engenharia econômica calculou-se o custo uniforme líquido equivalente de investimento do processo de resfriamento do leite, que somado ao custo operacional, resultou no custo uniforme líquido total por litro de leite. Concluiu-se que existe forte tendência à economia de escala nessa atividade devido aos retornos crescentes no custo de investimento e operacional, conforme aumenta-se a capacidade dos tanques de resfriamento.

This article aims to estimate the costs involved in the milk cooling process after the Normative Instruction 51 was issued and it also aims to verify the sources of economies scale. Using the concepts of the economical engineering, the uniform net costs of the investment in the milk cooling process were calculated. They were added to the operational cost and it resulted in the total uniform net cost per unit. It was concluded that there is a strong tendency to economies scale in the milk cooling process as a consequence of the growing returns in the investment and operational costs as the milk cooling tank capacity increases.