Lithium isotopic fingerprints of sources and processes in surface waters of the Ebro River Basin (Spain).

The Ebro River in north-eastern Spain is among the largest contributors of freshwater to the Mediterranean Sea and ends in the Ebro delta, one of the major wetlands in Europe. The bedrock of the Ebro River basin mainly consists of carbonate rocks and evaporites of Palaeozoic and Mesozoic age, and the river flows through several large cities, and agricultural and industrial areas. The Ebro outlet at Amposta was sampled once a month for a year (2006), and a field campaign in April of the same year sampled the Ebro along its main course as well as its principal tributaries. In the present study, the behaviour of Li and its isotopes was investigated at basin scale, with the objective of elucidating the processes controlling the lithium-isotope signatures of a large river draining mostly sedimentary bedrock. δ7Li values show a narrow range from +17.1 ‰ to +18.3 ‰ along the Ebro main stream, and between +16.3 and +18.9 ‰ at the outlet. In the major tributaries, the δ7Li values ranged from +12.9 ‰ to +20.9 ‰, with bedrock values ranging from +0.5 to +29.3 ‰. Comparing Li concentrations with Cl and SO4 ones, it appears that evaporite weathering plays an important role in controlling Li concentrations, but no anthropogenic agricultural or industrial influence on Li concentrations was detected. The Na/Li, Cl/Li and SO4/Li ratios clearly reflect the role of halite dissolution for some tributaries (Gallego, Ega and Aragon), gypsum dominating others (Guadalope, Matarrana, Huerva and Segre), and little influence of carbonate in all tributaries, the Ebro itself being a mixture of all tributaries. We tentatively applied the simple Rayleigh fractionation model, but most δ7Li values of the Ebro water samples plotted away from the fractionation line, reinforcing the major role of mixing processes in the Ebro basin, rather than fractionation processes during water/rock interactions. A comparison of δ7Li values and 87Sr/86Sr ratios further demonstrates the role of gypsum/anhydrite and limestone in the Ebro and its tributaries. Sr-isotopes show a non-negligible role of carbonate dissolution, generally considered to be weak in the control of the lithium cycle in catchments.

Spatio-Temporal Distribution and Environmental Behavior of Dissolved Rare Earth Elements (REE) in the Zhujiang River, Southwest China.

Rare earth elements (REE) geochemistry can reveal the environmental information of solutes in river systems because REE is sensitive to hydro-geochemical changes in the earth's surface environment. This work collected the river water samples from Zhujiang River (the largest river in South China) to investigate the concentration, fractionation, and environmental implication of dissolved REE. The total dissolved REE (∑REE) concentrations are similar in different seasons. In mid-lower reaches, the REE concentrations tend to increase corresponding to low pH, and the normalized ratios of lanthanum (La) to ytterbium (Yb) are higher, suggesting weak fractionation between light REE and heavy REE. Compared to the previous study in 2000, the higher samarium (Sm) and europium (Eu) concentrations are most likely influenced by stronger water/particle interaction. These findings provide preliminary information for REE cycle in the surface environment.

Dissolved iron and isotopic geochemical characteristics in a typical tropical river across the floodplain: The potential environmental implication.

Iron (Fe) is an essential element for bio-physiological functioning terrestrial organisms, in particular of aquatic organisms. It is therefore crucial to understand the aquatic iron cycle and geochemical characteristics, which is also significant to obtain the key information on earth-surface evolution. The stable iron isotopic composition (δ56Fe) of the dissolved fraction is determined in the Mun River (main tributary of Mekong River), northeast Thailand to distinguish the human and nature influenced riverine iron geochemical behavior. The results show that dissolved Fe concentration ranges from 8.04 to 135.27 µg/L, and the δ56Fe ranges from -1.34‰ to 0.48‰, with an average of 0.23‰, 0.14‰ and -0.15‰ in the upper, middle and lower reaches, respectively. The δ56Fe values of river water are close to that of the bulk continental crust and other tropical rivers. The correlations between δ56Fe and Fe, Al, and physicochemical parameters show mixing processes of different Fe end-members, including the rock weathering end-member (low Fe/Al ratio and high δ56Fe), the urban activities end-member (high Fe/Al ratio and moderate δ56Fe), and a third end-member with probable sources from the Chi River and reservoir. For the most river water samples, the primary contribution is attributed to rock weathering, and the second is urban activities (only a few samples are from the upper and middle reaches). Thus, Fe isotopes could be employed as a proxy to identify and quantify the natural and anthropogenic contributions, respectively. These findings also provide data support for the scientific management of water resources in the Mun River catchment and other large tropical rivers.

Atmospheric CO2 consumption by rock weathering over a five year period in a large non-perennial tropical river basin of southern India.

Rivers engage in carbon cycle by transporting the dissolved products of weathering of rocks to the oceans, and this process is sensitive to the global climatic changes. The present study was carried out with an objective of estimating the spatial and temporal variation in carbon consumption due to rock weathering in Cauvery, which is a major non-perennial tropical river in the peninsular India. The samples of all the rock types of this river basin were collected and subjected to mineralogical analysis. The water samples from this river were collected three times a year from 2013 to 2017 at 28 locations and were analysed for pH, EC and major ions. The spatiotemporal variations in the chemistry of river water were used to understand the amount of carbon dioxide consumed by rock weathering. The contribution of weathering to dissolved load of the river was higher followed by the contribution of anthropogenic activities and rainfall. The contribution of silicate weathering is dominant during the high river flow, whereas during low flow time periods, the contribution of carbonate weathering is on par with silicate weathering. The carbon consumption due to weathering in the Cauvery river was higher when the flow was significant, and it was lower during summer months. It is also evident that the carbon consumption is high in the upper and middle regions of the basin due to the weathering of gneissic and granodiorite rocks. Thus, the carbon consumption and flux in this basin are dynamic, both spatially and temporally. The east flowing rivers draining through the peninsular India, which is mostly composed of massive rocks, also functions as carbon sink, thus benefitting the environment by reducing the excess CO2 in the atmosphere.

Mercury isotope compositions in large anthropogenically impacted Pearl River, South China.

Rivers integrate natural and anthropogenic mercury (Hg), and are important vectors of terrestrial Hg to the oceans. Here, we report the total Hg concentration and Hg isotope compositions of dissolved load in the Pearl River, the second largest river in China, in order to understand the processes and sources affecting Hg systematics in large anthropogenically-impacted river water. The dissolved Hg showed a concentration varying from 0.45 to 2.44 ng/L, within the range reported for natural background lake and river waters. All river water samples showed significantly negative δ202Hg (-2.89‰ to -0.57‰), slightly positive Δ200Hg (-0.05‰ to 0.52‰), and mostly positive Δ199Hg (0.10‰ to 0.57‰), except for three extremely negative values (-2.25‰ to -0.76‰). Combined with other geochemical parameters, we suggest that the influence of in-river processes, such as sorption and reduction, on the Hg isotope compositions is very limited, and the dissolved Hg in the Pearl River mainly comes from atmospheric precipitation and surface soil weathering. Although the whole river basin is largely affected by urban, industrial and mining activities, unlike other heavy metals, their direct contributions to dissolved Hg seem limited. It is worth noting that the three samples with very negative Δ199Hg values (down to -2.25‰) are derived from special source which attribute to the input of Hg released from the local incineration of electronic wastes. This study demonstrates that isotope approach is a powerful tool for tracing sources and pathways of Hg in large complex river systems.

Química de igarapés de água preta do nordeste do Amazonas - Brasil / Chemical composition of black water creeks from northern of Amazonas - Brasil

Neste estudo foram analisados pH, Eh, condutividade elétrica, cloreto, sílica, fosfato, K, Na, Ca, Mg, Fe, F, Zn, Ni, Co, Mn, Pb, Cu, Cr, Li e Cd nas águas de drenagens de pequeno porte no nordeste do Amazonas. As águas são pretas, predominantemente ácidas e levemente redutoras e com baixo conteúdo de elementos dissolvidos. Contudo, a química indica que são heterogêneas e refletem o ambiente geológico por onde percolam. SiO2, Na e K são os constituintes mais abundantes na fase dissolvida, especialmente nas drenagens mais a norte pertencentes as bacias do Uatumã, Urubu e no igarapé Canoas que drenam as rochas da Suíte Intrusiva Água Branca e Mapuera e as sedimentares do Grupo Iricoumé e as Formações Prosperança, Nhamundá, Manacapuru, Pitinga Os igarapés menores, que drenam exclusivamente os sedimentos da Formação Alter do Chão, são os mais diluídos. Os elementos-traços analisados estão em concentrações muito baixas.

The present study analyzed pH, Eh, electric conductivity, chloride, silica, phosphate, K, Na, Ca, Mg, Fe, Zn, Ni, Co, Mn, Pb, Cu, Cr, Li and Cd in draining waters making part of smaller creeks located in the northeastern Amazonas State. The waters have black colour, are predominantly acid and slightly reductive and have low content in dissolved elements. Otherwise they are chemically heterogeneous and reflect the geological environment. The SiO2, Na and K are the most abundant dissolved constituents, especially on the drainages farther north belonging to Uatumã, Urubu basins and Canoas Stream, which drain the rocks of Água Branca and Mapuera Intrusive Suite, Iricoumé Group and Prosperança, Nhamundá, Manacapuru, Pitinga Formations. Smaller Streams, which drains Alter do Chão Formation sediments, exclusively, are the most diluted ones. The analysed trace elements present very low concentrations.