Dissolved and particulate heavy metal pollution status in seawater and sedimentary heavy metals of the Bohai Bay.

Heavy metal contamination has been the focus of many studies owing to its potential risk on the health of coastal ecosystems. The Bohai Bay (BHB) is the second largest bay of Bohai Sea and subjected to serious anthropogenic perturbations. The aim of this study was to evaluate the distribution and pollution status of toxic heavy metals in seawater with two fractions (dissolved and suspended particulate phases) and surface sediments of this coastal system. Therefore, several hydrochemical parameters and concentration of seawater metals and sediment metals were measured at two cruises of 2020 summer and autumn. The spatial distribution and potential ecological risks were examined and their inter-element relationships were analyzed to identify potential geochemical processes. By comparing historical data since 1978, we find declining trends in contents of most trace metals in seawater and sediments, suggesting that recent pollution control in BHB have an effect on diminishing metal pollution. Dissolved metals showed no significant dependence on their particulate phase. The seawater posed a moderate to high level of ecological risk. The hydrochemical factors mainly had a greater impact on dissolved metals during summer, whereas they influenced suspended metals more significantly during autumn. These results provide fundamental information to support environmental quality management and ecological protection in coastal systems.

Seasonal differences in trace metal concentrations in the major rivers of the hyper-arid southwestern Andes basins of Peru.

The southern rivers of Peru originate in the Andes Mountains and flow in a southwestern direction to the Pacific Ocean through one of the most hyper-arid regions of the world. During each sub-equatorial summer from December to February, rains and snow melt in the Andes increase the streamflow in these rivers, even as they pass through the 100 km arid zone to the ocean. This study quantified seasonal dynamics of 34 trace metal elements (TM) and other constituent concentrations in four southern river basins of Peru (Chili-Quilca, Tambo, Camana-Majes-Colca, and Ocoña) during 2019-2020. Consistent with previous studies, we observed that: (1) the river water in the southern basins had relatively high concentrations of B, As, Fe, Al, Mn, P, Pb and Ni, with As the most ubiquitous toxic TM in all the basins, often detected at concentrations surpassing Peruvian and USEPA regulated concentrations; and (2) basins with the most to least toxic TM contamination were the Tambo > Chili-Quilca > Camana-Majes-Colca > Ocoña. Seasonal streamflow strongly influenced the concentrations of twenty TM, with 15 TM (Al, Au, Ba, Cd, Co, Cu, Fe, Gd, Mn, Ni, P, Pb, Ti, Yb and Zr) consistently higher in the wet season, and with As, B, Ge, Li, and Pd higher in the dry season. Our results improve the understanding of seasonal variability and vulnerability in western Andes superficial water sources, which are highly influenced by both local geogenic and anthropogenic conditions. A Spanish translation of this paper is available in the online Supplementary Material.

The spatial-temporal impact on dissolved and particulate metals in Brunei Bay, Malaysia: Spectrometric and chemometrics approach.

The concentrations of metals in the waters of Brunei Bay, Malaysia were determined to define the current level and changes of its distribution. Discriminant analysis showed that metals distribution was spatially influenced by anthropogenic activities, whereas the distribution of cadmium (Cd) and zinc (Zn) was temporally influenced by the seasonal changes. High concentration of particulate metals in the coastal region during the wet season was presumably affected by freshwater intrusion and strong current disturbance. Generally, the enrichment factor of the aluminium (Al), Cd, copper (Cu), lead (Pb), and Zn proved enrichment by anthropogenic sources, except for iron (Fe). Furthermore, Cd has the highest enrichment factor value, signifying the potential risk of Cd on the Brunei Bay waters even at a low level. However, the Malaysia Marine Water Quality Criteria and Standard have classified the Brunei Bay waters as unpolluted.

The influence of urban surface type and characteristics on runoff water quality.

Untreated runoff was collected over multiple rain events from 19 impermeable urban surfaces, including nine roofs, six roads and four carparks, to quantify the differences in water quality due to surface type, age, condition and location. All 19 sites were exposed to the same climatic conditions. Samples were analysed for key urban pollutants of concern, namely total suspended solids and total and dissolved copper and zinc. Results showed uncoated zinc-based roofs produced zinc concentrations (up to 55 mg/L) several orders of magnitude higher than receiving environment water quality guidelines in New Zealand, of which the vast majority was in dissolved form. Even non-metallic roofs with zinc-based guttering produced zinc concentrations over ten times higher than the same roof material without zinc-based guttering. Older zinc-based roofs had approximately five times higher zinc concentrations, demonstrating a substantial age effect on the untreated runoff quality. Similarly, copper roofs produced more than an order of magnitude higher copper concentrations (up to 7.8 mg/L) above the next highest copper-producing surfaces: higher trafficked roads and carparks. Regardless of traffic volume or function, all roads and carparks produced high TSS concentrations. Dissolved metal concentrations were high across the dataset confirming that metal partitioning is an important consideration for effective pollutant control as different removal processes need to be used for dissolved versus particulate metals. This dataset provides an important benchmark of untreated runoff quality across different impermeable surface types within the same geographical area and clearly shows the influence of surface characteristics on water quality runoff regardless of the local differences in land use. These findings provide valuable guidance to stormwater managers in identifying priority surfaces and selection of appropriate treatment strategies for effective stormwater management for total suspended solids, zinc and copper.

Metal size distribution in rainfall and snowmelt-induced runoff from three urban catchments.

The size distribution of metals transported by urban runoff has implications for treatment type and design, predicting their mobility and evaluating their potential impact on receiving waters. There is an urgent need to better understand the distribution of metals between fractions, particularly those in the sub-dissolved fractions. As a contribution to addressing this need, this study characterises the size distribution of Cd, Cr, Cu, Ni, V and Zn using conventional and novel techniques. Data is presented as event mean concentrations (EMC) of a total of 18 rainfall and snowmelt events at three urban sites. For all studied metals in all events and at all sites, the contribution of the truly dissolved fraction made a greater contribution to the total concentrations than the colloidal fraction. Truly dissolved Cd and Zn concentrations contributed (on average) 26% and 28% respectively, of the total EMCs with truly dissolved Cu and Ni contributing (on average) 18%. In contrast, only 1% (V) and 3% (Cr) were identified in the truly dissolved fraction. The greatest contribution of truly dissolved Cd, Cu and Zn concentrations (relative to total concentrations) were reported during rainfall events. However, no seasonal differences were identified and differences between the sites regarding the EMCs distribution by fractions were not at a statistically significant level (p > 0.05) for any metal or event. The loads of truly dissolved and colloidal metals did not follow the patterns of particulate metal loads indicating particulates are not the main source of sub-dissolved metals. The data suggests that ultrafiltration as a treatment technique would not efficiently mitigate the risks posed by metals to receiving water ecologies.

Long-term monitoring emphasizes impacts of the dredging on dissolved Cu and Pb contamination along with ultraplankton distribution and structure in Toulon Bay (NW Mediterranean Sea, France).

A long-term monitoring during dredging and non-dredging periods was performed. Total and dissolved Cu and Pb concentrations, DGT-labile Pb, ultraphytoplankton abundance and structure were monitored at four sites: dredging site, dumping site (inside/outside of a geotextile bag) and reference site. During the reference period (non-dredging), an increasing contamination in Pb, Cu and a progressive shift from Synechococcus to photosynthetic picoeukaryotes dominance was observed from reference to dumping site. Pb concentrations were significantly higher during dredging period, pointing out sediment resuspension as Pb major source of contamination. Unlike Pb, Cu concentrations were not statistically different during the two periods. Dredging period did not impact on ultraphytoplankton abundance and structure but influence heterotrophic prokaryotes abundance. Sediment resuspension is therefore a major driver of chemical and biological qualities in Toulon Bay. Furthermore, although the geotextile bag reduces particulate transport of the dredged sediment, the transport in the dissolved phase remains a major problem.

Linking molecular and optical properties of dissolved organic matter across a soil-water interface on Akimiski Island (Nunavut, Canada).

Dissolved organic matter (DOM) plays a crucial role in terrestrial and aquatic carbon and biogeochemical cycles; however, molecular transformations between aquatic and terrestrial systems remain poorly understood due to the complexity and heterogeneity of DOM. In this study, we investigated the molecular diversity of aquatic DOM and adjacent soil derived water extractable organic matter (WEOM) from seven locations on Akimiski Island, Nunavut using a combination of absorbance spectroscopy and Fourier transform ion cyclotron mass spectrometry (FT-ICR-MS). Assigned elemental formula and Van Krevelen compositional analysis reveal compositional similarities in river, inland ponds and coastal pool sites for aquatic DOM and WEOM. More aromatic, oxygenated polyphenolic carbon rich molecules were found in aquatic DOM whereas WEOM was abundant in highly unsaturated aliphatic material. A total of 276 phenolic, unsaturated aliphatic, and vascular plant-derived polyphenolic molecules were identified as being conserved between WEOM and aquatic DOM at one river and two inland pond locations suggesting similar CHO sources from adjacent soils. Moreover, contributions of polyphenolic compounds in aquatic DOM and WEOM were greater at inland ponds than coastal pools, congruent with a greater aromaticity at inland sites. Our results highlight the similarities and differences in WEOM to aquatic DOM composition and how they range across surrounding watersheds that provide insight into the biogeochemical dynamics across a Canadian subarctic terrestrial-aquatic-continuum.

Data on dissolved metals in Terengganu waters of South China Sea during pre-, post-, and Northeast Monsoon season.

Metals are natural elements existed in the environment. However, due to the rapid development of urbanisation and economic, high content of anthropogenic metals are being perceived in polluting the environment. The oceans are known to be a part of the sinking basin for anthropogenic metals ends. Dataset provided is purposely to give an overview of dissolved metals spatial distribution in the South China Sea off the east Peninsular of Malaysia during the pre-, post- and Northeast (NE) Monsoon period. Seawater samples were collected in a grid of 18 stations at 3 different water depth. Dissolved metals were pre-concentrated on-board ship using Chelex-100 resin and analysed using Inductively Coupled Plasma Mass Spectrophotometry (ICPMS). The dataset shows the effect of NE Monsoon on dissolved metals spatial distribution mainly at the area closer to the land. Therefore, this dataset could reveal the past information on anthropogenic metals intrusion in the South China Sea, since Terengganu state was recently pointed to be one of the Malaysian waterfront city. Additionally, this dataset also could help in studying the cycle of metals in the southern South China Sea waters.

Remobilization of dissolved metals from a coastal mine tailing deposit driven by groundwater discharge and porewater exchange.

Mining impacts on coastal environments have been extensively studied around the world. However, the role of Submarine Groundwater Discharge (SGD) and Porewater Exchange (PEX) as pathways for pollutants from mining waste deposits into seawater has been largely overlooked. Portmán Bay is located in the Cartagena-La Unión Pb-Zn sulphur mining district in Murcia, SE of Spain. The disposal of about 60 million tons of metal-rich mine tailings from 1957 to 1990 led to the infill of most of the bay. Although the effects of metals on indicator organisms have been shown previously, there is a major lack of knowledge on the release of dissolved metals from the emerged tailing deposit into the sea, more than 25 years after the closure of the mining activities. Samples for Ra isotopes (223Ra, 224Ra, 226Ra and 228Ra) and dissolved metals (Ag, Cd, Co, Pb, Zn) were analyzed in porewaters and seawater in order to separately estimate SGD and PEX driven dissolved metal fluxes. Our results show a continuous release of dissolved metals into the sea driven by both PEX and SGD. Most of dissolved metals are remobilized and released into the water column by PEX, which is a ubiquitous mechanism acting along the shoreline. Although SGD only represents 13% of the water flow, it drives large fluxes of dissolved Fe into the sea, mainly restricted to the west side of the bay. Large inputs of dissolved Fe2+ from the anoxic tailings deposit trigger a massive precipitation of iron hydroxides that enables the removal of most dissolved metals from the water column. This study highlights the role of PEX and SGD as significant mechanisms for the land to ocean transfer of dissolved metals from coastal mine tailings deposits.

Relationship between pesticide accumulation in transplanted zebra mussel (Dreissena polymorpha) and community structure of aquatic macroinvertebrates.

This study examined to what degree bioaccumulated pesticides in transplanted zebra mussels can give an insight to pesticide bioavailability in the environment. In addition, it was investigated if pesticide body residues could be related to ecological responses (changes in macroinvertebrate community composition). For this at 17 locations, 14 pesticide concentrations and nine dissolved metals were measured in translocated zebra mussels and the results were related to the structure of the macroinvertebrate community. Critical body burdens in zebra mussel, above which the ecological status was always low, could be estimated for chlorpyrifos, terbuthylazine and dimethoate being respectively 8.0, 2.08 and 2.0 ng/g dry weight. With multivariate analysis, changes in the community structure of the macroinvertebrates were related to accumulated pesticides and dissolved metals. From this analysis, it was clear that the composition of the macroinvertebrate communities was not only affected by pesticides but also by metal pollution. Two different regions could be clearly separated, one dominated by metal pollution, and one where pesticide pollution was more important. The results of this study demonstrated that zebra mussel body burdens can be used to measure pesticide bioavailability and that pesticide body burdens might give insight in the ecological impacts of pesticide contamination. Given the interrelated impacts of pesticides and heavy metals, it is important to further validate all threshold values before they can be used by regulators.

The content of metals in organisms of various trophic levels in freshwater and brackish lakes on the coast of the sea of Japan.

The content of trace metals (Pb, Zn, Cd, Cu) was examined in water-in the suspended and dissolved forms, in the suspended material and organisms of the food chain-phytoplankton-filter-feeding bivalves (Kunashiria coptzevi, Corbicula japonica) in fresh- and brackish-water lakes of the coast of the Sea of Japan. It was demonstrated that the fresh-water lakes were no different from the brackish-water ones in concentrations of metals in organisms and water. The anthropogenically altered Vaskovskoye Lake is distinguished among the fresh lakes by the elevated concentrations of Pb and Zn in the ecosystem components. Trace metals do not accumulate in the phytoplankton-mollusks food chain: content of Pb decreases while concentrations of Zn, Cd, and Cu do not change practically. This is associated with the low content of heavy metals in water, suspended matter, and suspended organic carbon controlling the filtration rate of organisms.

Arsenic and trace metals in a large reservoir: Seasonal and spatial variations, source identification and risk assessment for both residential and recreational users.

The Keban Dam Reservoir in Turkey is an internationally important reservoir, because it is located on the Euphrates River, which is an important transboundary river. Water samples were seasonally collected from 11 sampling sites on the reservoir between autumn 2014 and summer 2015. Spatial and seasonal variations, possible sources and health risks of dissolved trace metals (TMs) were investigated. Among ten TMs, only Cr and Mn showed significant spatial variations, while Cr, Mn and Pb did not show significant seasonal variations. The average concentrations of TMs except As and Cd indicated a decreasing trend from autumn to summer. Also, minimum total metal concentration was recorded in summer due to raised water level of the reservoir. Maximum concentrations of all TMs were lower than the drinking water guideline values set by EC (European Community), WHO and USEPA. Principle component analysis/factor analysis and correlation analysis demonstrated that all TMs originate from natural sources. Non-carcinogenic and carcinogenic risks through ingestion and dermal contact exposure pathways were estimated for both residential and recreational receptors exposed to TMs in reservoir water. Hazard quotient, hazard index (HI) and total HI values were lower than 1. Also, carcinogenic risk (CR) values of As and Cr for each exposure route and total CR values were within the acceptable range of 10-4 and 10-6. Thus, the Keban Dam Reservoir is safe for human health in terms of residential and recreational uses.

Comportamento e avaliação de metais potencialmente tóxicos (Cu (II), Cr (III), Pb(II) e Fe(III)) em águas superficiais dos Riachos Capivara e Bacuri Imperatriz-MA, Brasil / Behavior and evaluation of potentially toxic metals (Cu(II), Cr(III), Pb(II) and Fe(III)) in surface waters of streams Capivara and streams Bacuri Imperatriz-MA, Brazil

RESUMOEsta pesquisa avaliou a dinâmica e a distribuição dos metais Cu (II), Cr (III), Pb (II) e Fe (III), em amostras de água superficiais no Riacho Capivara e Riacho Bacuri na cidade de Imperatriz, Maranhão. As amostras de água foram coletadas em 2 pontos de amostragem à montante e jusante da cidade de Imperatriz para avaliar a influência da urbanização. Foram analisados os metais potencialmente tóxicos Cu (II), Cr (III), Pb (II) e Fe (III) e os seguintes parâmetros físicos e químicos: pH, sólidos totais dissolvidos, turbidez, e condutividade elétrica. As determinações dos metais foram feitas por meio de espectrometria de absorção atômica em chama (FAAS). As variações observadas para os parâmetros físico-químicos (pH, Condutividade Sólidos Totais Dissolvidos e Turbidez) indicam alterações na qualidade da água em virtude de ações antrópicas. Foi observada a presença sistemática de todos os metais investigados durante todo o período amostrado. Os resultados obtidos demostraram que Cu (II), Cr (III), Pb (II) e Fe (III) encontram-se preferencialmente associados a material particulado em suspensão (MPS). As variações observadas para os parâmetros físico-químicos e nas concentrações dos metais investigados indicam haver contribuição de caráter antropogênico associada à litologia da região, o que juntamente com a sazonalidade e fontes difusas e pontuais, contribuem, para a deterioração das águas superficiais desses corpos hídricos.

ABSTRACTThis research evaluated the dynamics and distribution of Cu (II), Cr (III), Pb (II) and Fe (III) in samples of surface water in the streams Capivara and streams Bacuri in Imperatriz city, Maranhão state, Brazil. There were two water sampling points upstream and downstream of the city of Imperatriz to evaluate the influence of urbanization. Were analyzed the potentially toxic metals (Cu (II), Cr (III), Pb(II) and Fe(III)) and the following physical and chemical parameters: pH, total dissolved solids, turbidity and electrical conductivity. Measurements of Cu(II), Pb(II) and Fe(III) were made by means of atomic absorption spectrometry in the flame (FAAS). The variations observed for the physical and chemical parameters (pH, Conductivity and Total Dissolved Solids Turbidity) indicate changes in water quality due to human actions. We observed the systematic presence of all metals investigated over the sampling points. The results showed that Cu (II), Cr (III), Pb (II) and Fe (III) are preferentially associated with suspended particulate matter (SPM). The variations observed for the physical and chemical parameters and concentrations of the metals investigated indicate a contribution of anthropogenic character associated with the lithology region, which along with the seasonality and diffuse and point source contribute to the deterioration of surface water body of water.