Elemental composition and potential health risk of vegetable cultivated in residential area situated close to abandoned gold mine dump: Characteristics of soil quality on the vegetables.

The presence of toxic metals in residential areas near abandoned gold mine tailings is a major environmental issue. This study mainly aimed to investigate the elemental distribution of both toxic and essential elements in soils and leafy vegetables (Brassica oleracea) collected from eight different sites around the Davidsonville residential area, located closer to the abandoned Princess gold mine dump, Johannesburg, South Africa. The nutritional value of vegetables in the human diet was determined to assess their value to their health. The vegetables contained metals in the following descending order: Ca > Mg > Ca > Sb > Pb > Fe > Mo > Cr > Se > As > V > Ni > Co > Cd. The bioaccumulation factor (BAF) revealed that vegetables tend to accumulate most metals even (toxic) during the transfer and translocation process. Based on the recommended daily allowance (%RDA) the vegetables showed to contribute 152%, 84% and 75% toward RDA for Se, V and Ca, respectively for most adults and these play a role in human metabolic activities. The vegetables were found to be a good source of essential elements (Ca, Mg, Ni, Na, Fe) but with some traces of toxic metals such as Pb, As and Sb. Based on the health risk assessment, the vegetable posed an adverse health hazard for human consumption due to metals with high HRI >1.

Radon exposure risks among residents proximal to gold mine tailings in Gauteng Province, South Africa: a cross-sectional preliminary study protocol.

Gold mine tailings, a legacy of the mining industry, harbors significant amount of radon gas, a classified human carcinogen. Radon exposure, especially near tailings, is a significant public health threat, potentially leading to increased risk of lung cancer, leukemia, and chronic obstructive pulmonary disease (COPD). These health problems are often associated with lower survival rates and significant financial burdens. This ongoing research aim to evaluating the relationship between indoor radon exposure and lung cancer, leukemia, and COPD risks among residents proximal to gold mine tailings in Gauteng Province, South Africa. This cross-sectional preliminary study focus on two distinct groups: Riverlea (exposed group, <2 km to Gold mine tailings) and Orlando East (unexposed group, >2 km to Gold mine tailings). Indoor radon levels is measured using AlphaE monitors, while health risks (lung cancer, leukemia, and COPD) linked to exposure are evaluated through interview-administered questionnaire and secondary data from Gauteng Health Department. Of the 476 residents randomly selected for this study, 300 have already participated, with balanced representation from both the exposed and unexposed groups. The study will compare indoor radon levels and health outcomes between the two groups. This study's results could aid in creating targeted interventions and policies to mitigate indoor radon exposure risks and safeguard vulnerable communities from this significant public health hazard.

Microbiological and geochemical characterization of As-bearing tailings and underlying sediments.

Over the past 100 years, extensive oxidation of As-bearing sulfide-rich tailings from the abandoned Long Lake Gold Mine (Canada) has resulted in the formation of acid mine drainage (pH 2.0-3.9) containing high concentrations of dissolved As (∼400 mg L-1), SO42-, Fe and other metals. Dissolved As is predominantly present as As(III), with increased As(V) near the tailings surface. Pore-gas O2 is depleted to < 1 vol% in the upper 30-80 cm of the tailings profile. The primary sulfides, pyrite and arsenopyrite, are highly oxidized in the upper portions of the tailings. Elevated proportions of sulfide-oxidizing prokaryotes are present in this zone (mean 32.3% of total reads). The tailings are underlain by sediments rich in organic C. Enrichment in δ34S-SO4 in pore-water samples in the organic C-rich zone is consistent with dissimilatory sulfate reduction. Synchrotron-based spectroscopy indicates an abundance of ferric arsenate phases near the impoundment surface and the presence of secondary arsenic sulfides in the organic-C beneath the tailings. The persistence of elevated As concentrations beneath the tailings indicates precipitation of secondary As sulfides is not sufficient to completely remove dissolved As. The oxidation of sulfides and release of As is expected to continue for decades. The findings will inform future remediation efforts and provide a foundation for the long-term monitoring of the effectiveness of the remediation program.

Genomic insights into the adaptation of Acinetobacter johnsonii RB2-047 to the heavy metal-contaminated subsurface mine environment.

The subsurface mine environments characterized by high levels of toxic metals and low nutrient availability represent an extreme threat to bacterial persistence. In recent study, the genomic analysis of the Acinetobacter johnsonii strain RB2-047 isolated from the Rozália Gold Mine in Slovakia was performed. As expected, the studied isolate showed a high level of heavy metal tolerance (minimum inhibitory concentrations were 500 mg/L for copper and nickel, 1,500 mg/L for lead, and 250 mg/L for zinc). The RB2-047 strain also showed noticeable resistance to several antibiotics (ampicillin, kanamycin, chloramphenicol, tetracycline and ciprofloxacin). The genomic composition analysis demonstrated a low number of antibiotic and metal resistance coding genes, but a high occurrence of efflux transporter genes located on the bacterial chromosome. The experimental inhibition of efflux pumps resulted in decreased tolerance to Zn and Ni (but not to Cu and Pb) and to all antibiotics tested. In addition, the H33342 dye-accumulation assay confirmed the high efflux activity in the RB2-047 isolate. These findings showed the important role of efflux pumps in the adaptation of Acinetobacter johsonii strain RB2-047 to metal polluted mine environment as well as in development of multi-antibiotic resistance.

Draft genome sequence of active gold mine isolate Pseudomonas iranensis strain ABS_30.

Pseudomonas iranensis ABS_30, isolated from gold mining soil, exhibits metal-resistant properties valuable for heavy metal removal. We report the draft genome sequencing of the P. iranensis ABS_30 strain, which is 5.9 Mb in size.

Selected rhizobacteria facilitated phytoremediation of barren and heavy metal contaminated gold mine tailings by Festuca arundinacea.

Gold mine tailings pose a significant challenge for phytoremediation due to their poor nutrition and heavy metal pollution. Rhizobacteria-assisted phytoremediation is a promising method, yet limited research has been conducted on its application in gold mine tailings. In this study, rhizobacteria R1 (Bacillus paramycoides) and R2 (Klebsiella michiganensisW14T) were isolated from the rhizosphere of Festuca arundinacea (F. arundinacea) to enhance the phytoremediation of gold mine tailings. Our results showed that inoculation of R1 and R2 led to a significant increase in the average germination rates of F. arundinacea by 36.9% and 16.5%, respectively. Furthermore, the average plant height increased by 68.3% and 53.4%, respectively. Importantly, after inoculation with rhizobacteria, the contents of Mn, Pb, and As in F. arundinacea increased by 13.2-33.9%, 40.1-41.0%, and 98.1%-124.5%, respectively, indicating that the rhizobacteria enhanced the plant uptake of heavy metals. The improved nutrient content and enzyme activity in the tailings after inoculation with rhizobacteria were positively correlated with the heavy metal content in F. arundinacea. In addition, inoculation of rhizobacteria significantly altered the microbial community structure of the tailings, with Bacillus becoming the dominant genus in the rhizosphere tailings of F. arundinacea after R1 inoculation. Overall, our findings demonstrated that rhizobacteria R1 was better to enhance the phytoremediation of gold mine tailings. These results offer valuable insights into the mechanism of rhizobacteria-assisted phytoremediation and provide a practical method to enhance remediation of gold mine tailings.

Socio-Environmental Risks Linked with Mine Tailings Chemical Composition: Promoting Responsible and Safe Mine Tailings Management Considering Copper and Gold Mining Experiences from Chile and Peru.

There is a need to define mine tailings in a clear, precise, multidisciplinary, transdisciplinary, and holistic manner, considering not only geotechnical and hydraulic concepts but also integrating environmental and geochemical aspects with implications for the sustainability of mining. This article corresponds to an independent study that answers questions concerning the definition of mine tailings and the socio-environmental risks linked with mine tailings chemical composition by examining the practical experience of industrial-scale copper and gold mining projects in Chile and Peru. Definitions of concepts and analysis of key aspects in the responsible management of mine tailings, such as characterization of metallic-metalloid components, non-metallic components, metallurgical reagents, and risk identification, among others, are presented. Implications of potential environmental impacts from the generation of acid rock drainage (ARD) in mine tailings are discussed. Finally, the article concludes that mine tailings are potentially toxic to both communities and the environment, and cannot be considered as inert and innocuous materials; thus, mine tailings require safe, controlled, and responsible management with the application of the most high management standards, use of the best available technologies (BATs), use of best applicable practices (BAPs), and implementation of the best environmental practices (BEPs) to avoid risk and potential socio-environmental impact due to accidents or failure of tailings storage facilities (TSFs).

Pollution assessment of mercury and other potentially toxic elements in the marine sediments of Mambulao Bay, Jose Panganiban, Camarines Norte, Philippines.

In Jose Panganiban, Camarines Norte, small-scale gold miners dispose of untreated tailings into nearby rivers, which eventually flow into Mambulao Bay. In this study, nine (9) marine sediments were collected and analyzed to assess the pollution of potentially toxic elements (PTEs) in Mambulao Bay. Au concentrations in the sediments were also determined. The results showed that the Mambulao Bay sediments have high concentrations of Hg and other PTEs. The average concentrations of potentially toxic elements in the marine sediments were observed in the following order: Zn (638 mg/kg) > Pb (297 mg/kg) > Cr (283 mg/kg) > Cu (209 mg/kg) > Ni (146 mg/kg) > As (35 mg/kg) > Hg (4.4 mg/kg) > Cd (1.4 mg/kg). Geoaccumulation index values suggest that Mambulao Bay sediments close to the Danao River estuary are strongly to extremely polluted by Hg, strongly polluted by Pb, moderately to strongly polluted by Zn, and moderately polluted by Cd, Cu, Cr, Ni, and As. A high average Au concentration (0.42 mg/kg) was also reported in the sediments. The enrichment values suggest that the PTE pollution has an anthropogenic origin, most likely from the artisanal gold mine tailings of Jose Panganiban. Most of the marine sediments have Hg, Pb, Zn, and Cu concentrations above the probable effect levels for PTEs, which can result in occasional adverse biological effects on the aquatic biota of Mambulao Bay. The average Hg content of Mambulao Bay sediments is higher than those of Honda and Agusan Bays, while the average Pb and Zn contents are higher than those of Honda and Butuan Bays, Boac River estuary, and Tañon Strait. These results can help the government address marine pollution in Mambulao Bay for sustainable aquatic resources and coastal management and can serve as a baseline for future monitoring and assessment of the water body.

Environmental contamination and health risk assessment of potentially toxic trace metal elements in soils near gold mines - A global meta-analysis.

Gold mining is the most important anthropogenic source of heavy metal emissions into the environment. Researchers have been aware of the environmental impacts of gold mining activities and have conducted studies in recent years, but they have only selected one gold mining site and collected soil samples in its vicinity for analysis, which does not reflect the combined impact of all gold mining activities on the concentration of potentially toxic trace elements (PTES) in nearby soils at a global scale. In this study, 77 research papers from 24 countries were collected from 2001 to 2022, and a new dataset was developed to provide a comprehensive study of the distribution characteristics, contamination characteristics, and risk assessment of 10 PTEs (As, Cd, Cr, Co, Cu, Hg, Mn, Ni, Pb, and Zn) in soils near the deposits. The results show that the average levels of all 10 elements are higher than the global background values and are at different levels of contamination, with As, Cd, and Hg at strong contamination levels and serious ecological risks. As and Hg contribute to a greater non-carcinogenic risk to both children and adults in the vicinity of the gold mine, and the carcinogenic risks of As, Cd, and Cu are beyond the acceptable range. Gold mining on a global scale has already caused serious impacts on nearby soils and should be given adequate attention. Timely heavy metal treatment and landscape restoration of extracted gold mines and environmentally friendly approaches such as bio-mining of unexplored gold mines where adequate protection is available are of great significance.

Environmental exposure to uranium in a population living in close proximity to gold mine tailings in South Africa.

BACKGROUND: Gold mining activities in South Africa resulted in contamination of residential environment with uranium-rich wastes from mine tailings. Health of the people living around the mine tailings could be affected by uranium exposure due to its hazardous chemotoxic and radiological properties. METHODS: We conducted a cross-sectional study to assess i) uranium (U) concentrations in individual hair samples of children and adults living in close proximity to mine tailings in Northeast- Soweto in Johannesburg, South Africa, and ii) the association between U concentrations in hair and various factors, including zone of residence, socio-demographic and housing characteristics. Sampling sites were divided into three zones based on the distance between a dwelling and a cluster of mine tailings (zone 1: <= 500 m, zone 2: 2-3 km away, zone 3: 4-5 km away). U concentrations in hair samples were measured using inductively coupled plasma mass spectrometry. To test the association between U concentrations and selected factors we used robust regression models with log-transformed U concentrations. RESULTS: Among 128 subjects with available U measurements, 63 (49%) were children (ages 7-15 years) of which 38 were girls, the remaining 65 (51%) were adult females. Mean (median) U concentration in hair samples was 143 (92) µg/kg. In the mutually adjusted analyses, only an inverse association between age and U concentration in hair remained statistically significant, with geometric mean in children being 2.1 times higher compared to adults (P < 0.001). There was no evidence of an association between zones and U concentration (P = 0.42). CONCLUSIONS: There was little evidence of association between U concentration in hair and distance from the mine tailings within the 5 km range, but overall concentrations were elevated compared to general population samples in other parts of the world. Children had statistically significantly higher geometric mean of uranium concentration in hair compared to adults. The results are important for improvement of mining waste policies and implementation of health monitoring and protective measures in populations at risk. ARTICLE CATEGORY: Research Article.

The Diagenetic Alterations of Historic Skeletons from the Crown Mines Cemetery, South Africa.

Human skeletons associated with early gold mining in Johannesburg, South Africa are investigated. An unmarked cemetery was buried beneath a mine dump which resulted in macroscopically stained and poorly preserved bones. Histological assessments were conducted to understand the postmortem treatment of the remains, determine the extent of bone degradation, and understand how this environment affected the bone's microstructure. Various diagenetic alterations and the general histological index were assessed using normal and polarized light microscopy of thin anterior midshaft femur sections (n = 50). Degradation was identified in the periosteal and endosteal regions, while the intra-cortical region remained well-preserved. Bacterial bioerosion, microcracks, infiltrations, inclusions, and staining were found throughout the sample. Numerous non-Wedl micro-foci of destruction were observed, filled with exogenous material. The degradation suggested that the remains were buried in neutral soil that was subsequently covered by acidic mine dumps which resulted in a corrosive environment. Although the skeletons were poorly preserved, their histological integrity was more promising, especially the intra-cortical area. This is important for future investigations of archaeological bone, as this area can lead to more accurate descriptions of skeletal assemblages. Targeted sampling of this region could produce promising estimates of age, descriptions of pathology, and biomolecular results, which require further study.

Mechanical and Hydration Characteristics of Stabilized Gold Mine Tailings Using a Sustainable Industrial Waste-Based Binder.

Sustainable resource utilization of tailings is a long-term challenge. Therefore, a novel waste-based binder is proposed in this study to stabilize/solidify gold mine tailings (GMTs). This binder is composed of fly ash (FA), ground blast furnace slag (GBFS), and metakaolin (MK) activated with mixed calcium carbide residue (CCR) as well as pure reagent grade chemical, sodium hydroxide (SH, NaOH), and plaster gypsum (PG, CaSO4·2H2O). The mechanical properties and hydration of stabilized tailings with curing period were investigated. Tests included triaxial compression test and nitrogen adsorption to evaluate the strength of the stabilized tailings and microstructure. The results show that the addition of the waste-based binder yields significant improvement in shear strength. Strain softening occurred for all cured samples, and a local shear band can be observed in all failed stabilized samples. Based on the relationship between strength and curing period, it can be speculated that the hydration reaction of the sample ends after around 40 days of curing. A bimodal pore-size distribution was observed in all solidified/stabilized samples. FTIR and 27Al MAS-NMR were used to analyze hydration products. The strength improvement of stabilized tailings was mainly attributed to the formation of ettringite and C-S-H gels after various polymerization reactions. These new hydrates bind tailings particles and fill the pores to form a more stable structure, which supplied superior mechanical properties. This paper can provide a theoretical basis for exploring the application of the industrial waste-based binder to modify the mechanical properties of gold tailings.

Mining tailings and alkali activation: a comprehensive bibliometric review.

Significant amounts of mining tailings are generated and disposed of every year in dams, leading to potentially serious environmental and safety problems. To identify alternatives for the disposal of these wastes, research works involving their potential application as precursors in the development of alkaline-activated materials have been published in recent years. In this context, the objective of this paper is to present an overview of the main contributions already made on the subject, identified through a bibliometric review and content analysis in the Scopus and Web of Science databases. There was an exponential growth of interest in the subject in the period 2019-2021, when more than 50% of the papers were published. The most used tailings and sub-areas of research were also identified.

Potential Health Effects of Heavy Metals and Carcinogenic Health Risk Estimation of Pb and Cd Contaminated Eggs from a Closed Gold Mine Area in Northern Thailand.

Gold-mining activities have been demonstrated to result in significant environmental pollution by Hg, Pb, and Mn, causing serious concerns regarding the potential threat to the public health of neighboring populations around the world. The present study focused on heavy-metal contamination in the eggs, blood, feed, soil, and drinking water on chicken farms, duck farms, and free-grazing duck farms located in areas < 25 km and > 25 km away from a gold mine in northern Thailand. In an area < 25 km away, Hg, Pb, and Mn concentrations in the eggs of free-grazing ducks were significantly higher than > 25 km away (p < 0.05). In blood, Hg concentration in free-grazing ducks was also significantly higher than those in an area > 25 km away (p < 0.05). Furthermore, the Pb concentration in the blood of farm ducks was significantly higher than in an area > 25 km away (p < 0.05). The concentration of Cd in drinking water on chicken farms was significantly higher for farms located within 25 km of the gold mine (p < 0.05). Furthermore, a high correlation was shown between the Pb (r2 = 0.84) and Cd (r2 = 0.42) found between drinking water and blood in free-grazing ducks in the area < 25 km away. Therefore, health risk from heavy-metal contamination was inevitably avoided in free-grazing activity near the gold mine. The incremental lifetime cancer risk (ILCR) in the population of both Pb and Cd exceeded the cancer limit (10−4) for all age groups in both areas, which was particularly high in the area < 25 km for chicken-egg consumption, especially among people aged 13−18 and 18−35 years old. Based on these findings, long-term surveillance regarding human and animal health risk must be strictly operated through food chains and an appropriate control plan for poultry businesses roaming around the gold mine.

The potential of using alkaline gold mine tailing as a cover material to mitigate AMD formation from acidic gold mine tailing pile at Sabie-Pilgrim's Rest Goldfields, South Africa.

Acid mine drainage (AMD) caused by the oxidation of sulphide minerals found in mine waste is a global environmental concern, especially in water-restricted countries with heavy mining industries. Implementing AMD treatment and prevention programs can be extremely expensive, hence the need to identify environmentally sustainable treatment and preventative techniques to mitigate the potential of AMD formation. Soil covers and blends have been identified as an attractive approach. However, prior studies on the characteristics of the soils concerned and the acid-neutralisation rate should be carried out before considering the implementation of a soil cover or blending system to mitigate AMD formation. This study evaluated the acid generation capabilities of acidic gold mine tailings (AG), alkaline gold mine tailings (AN) and blends (MIX25, MIX50). Acid-base accounting (ABA), net acid generation (NAG) and acid-buffering characteristic curve (ABCC) test methods were used to evaluate the acid-generating and acid-neutralising capabilities of AG, AN, MIX25 and MIX50 samples. Leach column tests were conducted using alkaline gold mine tailings (AN) as the top pH neutralising cover (COV25) to determine the potential of the alkaline gold mine tailing to serve as a pH neutralising cover material to prevent and treat AMD generated by the acidic gold mine tailings. The ABA, NAG and ABCC results showed that AN has a high acid-neutralising capacity while AG has the potential to generate acid. The results further indicated that the AN to AG blend ratio of 1:3 by weight (MIX25) would neutralise the acid generated by AG. Leach column experiment (COV25) found that using AN as a pH neutralising cover would be a feasible option.

Paleoecotoxicology: Developing methods to assess the toxicity of lake sediment records influenced by legacy gold mining.

The contamination of lakes by industrial emissions is an issue of international concern. Traditional paleolimnology examines sedimentary micro-fossils to infer the biological response to natural and anthropogenic stressors over time. Here, we calculate a theoretical biological effect for historic sediment sections using Probable Effect Concentration Quotient (PEC-Q) and arsenic specific quotient methods and develop novel time-constrained sediment toxicity test methods using a cultured Daphnia sp. combined with a whole cell microbial biosensor to assess the toxicity of past industrial contamination with modern testing methods. These methods were developed using sediments collected from Pocket Lake (Northwest Territories, Canada), a lake known to have exhibited a significant ecological shift following input from nearby gold smelter emissions during the mid 20th century. We then applied these methods to near-, mid-, and far-field sites to assess the response of Daphnia sp. to varying contaminant load. Daphnia sp. mortality exposed to dated sediments indicated a strong concordance with the timing of mining activities, and a strong concordance with PEC-Q and arsenic specific toxicity quotients. In contrast, a decrease in Daphnia mortality was observed during pre-, and post-mining periods when the contaminant burden was lower. Initial assessments of bioavailability using a microbial biosensor indicated that arsenic in porewater is 72-96% bioavailable, and limited evidence that oxidative stress may contribute to the Daphnia sp. toxic response. These results indicate that lake sediment archives can be used to infer missing biomonitoring data in sites of legacy anthropogenic influence, which will be useful for those seeking to conduct cost-effective and efficient preliminary environmental risk assessments.

Heavy metal(loid)s shape the soil bacterial community and functional genes of desert grassland in a gold mining area in the semi-arid region.

Gold mining can create serious environmental problems, such as soil pollution by heavy metal (loid)s. In this study, we assessed the ecological risk of Hatu gold mining activities and synchronously investigated the bacterial community structure, distribution of soil nutrient-element cycling genes (CNPS) and heavy metal resistance genes (MRG) in adjacent desert grassland soil. The study area was above the moderate risk level, with the ecological risk index (RI) of each sampling site greater than 150. Arsenic, mercury and copper were the main pollutants. Proteobacteria, Actinobacteria and Firmicutes dominated the phyla of the bacterial communities. Species turnover rather than nestedness accounted for the significant differences in community structure among various regions in the mining area. In addition, the bioavailable heavy metal (loid)s (AHM) content had a strong correlation with beta diversity and species turnover of the bacterial community (p < 0.05). No clear difference was found in the total abundance of CNPS genes among various functional regions, but eight specific functional genes were identified from downwind grasslands with lower pollution levels. Among the MRGs, Hg MRG had the highest average total relative abundance, followed by Cu, Co/Zn/Cd and As. The mercury resistance gene subtype hgcAB was positively related to the diversity of the bacterial community, and the bacterial community of grassland soil showed congruency with the MRGs in the Hatu mining area. Total Hg (THg) showed the highest influence affecting the bacterial community, while NH4+-N had the greatest effect on CNPS genes and MRGs. These results highlighted the role of heavy metal (loid)s in shaping the bacterial community and functional genes in arid and semiarid desert grassland soil in gold mining regions.

Synthesis of silver nanoparticles with high efficiency and stability by culture supernatant of Bacillus ROM6 isolated from Zarshouran gold mine and evaluating its antibacterial effects.

BACKGROUND: The use of bacteria to synthesize nanoparticles as an environment-friendly method has recently been considered by researchers. Bacteria residing in different mines have shown high potential in the synthesis of metal nanoparticles due to their compatibility with the environment. The aim of this study was to evaluate the ability of Zarshouran gold mine bacteria to synthesize silver nanoparticles and their antibacterial activity. METHODS: After isolation of mine bacteria and several screening steps, silver ion tolerant bacteria that were able to synthesize extracellular silver nanoparticles were isolated and the most suitable isolate was selected and sequenced. The characteristics, stability, and production efficiency of silver nanoparticles were evaluated using UV-vis spectrophotometry, DLS, TEM, FTIR, and X-ray diffraction analysis. Finally, the antibacterial effect of silver nanoparticles against pathogenic bacteria was investigated. RESULTS: Among the eight silver-tolerant bacteria, isolate No. 6 had high antibacterial activity and high potential in the synthesis and stabilization of silver nanoparticles. Therefore, this isolate was selected for the next experiments. The results of 16S rDNA sequencing showed that this isolate is related to Bacillus pumilus. We registered in the NCBI Bank called ROM6 with access number MW440543. The DLS and TEM analysis showed that silver nanoparticles produced by this isolate were most spherical with a size of less than 25 nm and were stable for at least 180 days. The efficiency at concentrations less than 0.9 g/l silver nitrate was over 90% and the minimum inhibition concentration of nanoparticles was determined against S. aureus, E. coli, P. aeruginosa, and A. baumannii ranging from 1.4 to 5.6 µg/ml. CONCLUSION: We found that the bacteria residing in the gold mine have a high capacity for the synthesis of spherical and high stable silver nanoparticles with a strong antibacterial effect.

Tracing the pollution and human risks of potentially toxic elements in agricultural area nearby the cyanide baths from an active private gold mine in Hainan Province, China.

Mining activities are well-known sources of potentially toxic elements (PTEs) pollution, which often jeopardize the biosphere, pedosphere, and hydrosphere. However, the soil and groundwater pollution caused by active private mining activities has long been neglected. This study investigated the occurrence of PTEs and cyanide (CN) in agricultural soils, mine tailings, and groundwater nearby the cyanide baths from a private gold mine in Hainan Province, southern China. Results indicated that concentrations of Pb, As, Cd, Hg, and CN in different soil depths and mine tailings were up to ten thousand mg/kg, and relatively higher content of As and Pb was detected in groundwater. The chemical forms of Cd, Pb, As, and Hg varied greatly in different soil depths; over 80% of Cd distributed in the water-soluble fraction, suggesting its higher mobility in soils, while approximately 60-90% of Pb, As, and Hg distributed in other chemical fractions, indicating relatively lower mobility in soils. The pollution indices also revealed the serious pollution and deterioration of site quality in this area. Human risk assessments also reflected a high non-carcinogenic/carcinogenic health risk in this area. The framework of integrated management strategies for private metal mines was proposed to mitigate PTEs pollution and reduce health risks.

Environmental challenges related to cyanidation in Central American gold mining; the Remance mine (Panama).

Mine tailings are a potential source of environmental pollution because they typically contain potentially toxic elements (PTEs) and the residue of chemical compounds used during extraction processes. The Remance gold mine (NW Panama) is a decommissioned mine with mining activity records dating from the 1800s and several periods of abandonment. Very little remediation work has been performed, and waste is exposed to climatic conditions. This study aimed to evaluate the PTEs and cyanide contents in mine waste after mining operations ceased some 20 years ago, and to evaluate the degree of pollution and the environmental risks they pose with the use of the Pollution Load Index (PLI) and the Ecological Risk Index (RI). Although the total cyanide (T-CN) concentration (1.4-1.9 mg kg-1) found in most of the study area falls within the limits of gold mining tailing values for American sites (1.5-23 mg kg-1), it is worth noting that the values of the tailings of the last used mining operation exceed it (25.2-518 mg kg-1) and persist at the site. The PLI and RI suggest that the tailings from the mine and mine gallery sediments represent a source of pollution for soils and surrounding areas given their high content of PTEs (As, Cu, Sb, Hg) and T-CN, which pose serious ecological risks for biota. Therefore, it is necessary to draw up a remediation plan for this area.