Watershed-scale assessment of environmental background values of soil potential toxic elements from the Caatinga and Atlantic forest ecotone in Brazil.

The evaluation of the concentration of a potentially toxic element (PTE) in soils under native vegetation is the base study to obtain the quality reference values (QRVs), and the watershed is the strategic planning unit for decision making. The objective of this study was to determine the natural concentrations of As, Cd, Co, Cr, Cu, Fe, Mn, Ni, Pb and Zn and to establish QRVs for the Verruga river basin. Soils with no or minimal anthropic intervention from the surface layer (0.0-0.2 m) were collected and processed, and PTEs were extracted according to the USEPA 3051A method and determined by ICP‒OES. The quality of the analyses was checked by blank tests and soil samples certified SRM 2709 - San Joaquin Soil. The data set was subjected to exploratory analysis and multivariate statistics. The mean background concentrations of PTEs in soils showed high variability compared to other locations in Brazil and in the world and were (mg kg-1) Fe (24,300) > Mn (211.10) > Cr (40.98) > Zn (28.28) > Cu (10.68) > Ni (9.44) > Pb (4.95) > Co (4.08) > As (3.48) > Cd (0.09). The QRVs for the PTEs were established based on the 75th percentile, where (mg kg-1) Mn (124.59) > Cr (54.51) > Zn (31.66) > Cu (7.89) > Ni (7.20) > Pb (5.98) > As (4.05) > Co (3.40) > Cd (0.10). The chemical attributes and topography variation along the watershed are very heterogeneous and influence the dynamics of the PTEs. This survey will support future research on the impact of human activities on soil contamination in the watershed. This survey will support future research on environmental monitoring and the impacts caused by increased human activities on soil contamination in the Verruga river watershed, in the state of Bahia, Brazil.

Baseline values and environmental assessment for metal(loid)s in soils under a tropical rainy climate in a Colombian region.

The baseline values for metal(loid)s in soils are known as a tool for the evaluation, prevention, and monitoring of the environmental quality of the soil. The main aim is to propose baseline values for metal(loid)s through the analysis of the concentrations in soils within natural areas; additionally, this study attempts to assess the environmental quality of soils in agricultural areas. The study was developed in the Piedemonte Llanero from Colombia a region with more than 5000 mm year-1 of pluviometry. A total of 90 soil samples were collected in agricultural and natural areas. Chemical analysis was conducted by acid digestion following the method EPA 3050B and determined the metal(loid)s (Al, As, Fe, Cd, Cr, Cu, Mg, Mn, Ni, Pb, and Zn) through ICP-OES. This is the first time that baseline values are proposed for a region in Colombia. The values proposed (expressed in mg kg-1) are Cd (0.3), As (2.8), Cu (9.9), Ni (10.2), Pb (11.3), Cr (21.1), Zn (28.2), Mn (83.8), Mg (348), Fe (22,775), and Al (28,975). These values are comparatively lower than those reported for other regions in Latin America and the rest of the world. Also, agricultural soils are not contaminated. The possible explanation is as a consequence of the intense washing caused by the intense rainfall of the place. The results also demonstrated that the soils in this region are not contaminated. Finally, these advances will allow public and private organizations to establish criteria for the environmental and sustainable management of soils, especially on agricultural activities.

Use of blood residue as alternative source of phosphorus in sunflower (Helianthus annuus L. ) cultivation / [Utilização de resíduo de sangue como fonte alternativa de fósforo no cultivo de girassol (Helianthus annuus L. )]

The aim of this work was to increase the aerial part, biometry, and yield of achenes from sunflower plants on the effect of increasing doses of blood residue, as an alternative source of phosphorus (P), in a clayey-textured red Oxisol. The experimental design used was randomized blocks, with six treatments and four replications. The treatments consisted of five doses of blood residue (0, 6, 12, 24 and 48m3 ha-1) and a control treatment that received phosphate chemical fertilization, 80kg ha-1 of P2O5. The increasing doses of blood residue and chemical fertilization do not show disproportionality for P concentration in soil, leaf, plant height (PH), stem diameter (SD), chapter diameter (CD) and achene production. The analysis of the principal component (PC) revealed that the first PC presents the greatest accumulated variation (74%). Based on the first PC, the dose of 12m-3 ha-1 has greater influence for PH, SC, and CD. Due to the greater influence on the biometric characteristics of sunflower plants, the blood residue (12m-3 ha-1 = 98.4kg P ha-1), can be used as an alternative source of phosphorus for the cultivation of sunflower in clayey oxisols.

Objetivou-se com este trabalho verificar biometria de parte aérea, rendimento de aquênios de plantas de girassol sobre o efeito de doses crescentes de resíduo de sangue, como fonte alternativa de fósforo (P), em um Latossolo vermelho de textura argilosa. O delineamento experimento utilizado foi o de blocos casualizados, com seis tratamentos e quatro repetições. Os tratamentos foram constituídos por cinco doses de resíduo de sangue (0, 6, 12, 24 e 48m3 ha-1) e um tratamento que recebeu a adubação fosfatada química, 80kg ha-1 de P2O5. As doses crescentes de resíduo de sangue e adubação química não demostram desproporcionalidade para a concentração de P no solo, folha, altura de planta (AP), diâmetro de caule (DC), diâmetro de capítulo (DCP) e produção de aquênios. A análise de componentes (CP) principais revelou que o primeiro CP apresenta maior variação acumulada (74%). Baseado no primeiro CP, a dose de 12 m-3 ha-1exibe maior influência para AP, DC e DCP. Devido a maior influência sobre as características biométricas em plantas de girassol, o resíduo de sangue (12m-3 ha-1 = 98,4kg P ha-1), pode ser utilizado como fonte alternativa de fósforo para o cultivo de girassol em Latossolos de textura argilosa.

Quality reference values for rare earth elements in soils from one of the last agricultural frontiers in Brazil

Environmental impacts caused by the addition of rare earth elements (REEs) to agricultural soils are a growing concern. The sedimentary basin of the Gurguéia River is located in one of the last agricultural frontiers in Brazil; nevertheless, data regarding quality reference values (QRVs) for REEs in soils are still scarce. The objective of this study was therefore to determine the natural concentration and establish the QRVs of REEs in soils of Gurguéia watershed, Brazil. Fifty-five composite soil samples were collected at sites under no or minimal anthropic interference. The average REE natural concentrations in soils from the Gurguéia watershed were lower than those found in other regions of Brazil and worldwide, following the order (mg kg−1): Ce (14.01) > Nd (6.19) > La (5.52) > Pr (2.51) > Sm (1.45) > Gd (0.93) > Dy (0.63) > Er (0.42) > Yb (0.39) > Tb (0.28) > Eu (0.26) > Lu (0.20). The parent material was the main factor that controlled the distribution of REEs in soils. The QRVs in soils followed the order (mg kg−1): Ce (18.8) > Nd (7.92) > La (6.32) > Pr (3.3) > Sm (1.97) > Gd (1.35) > Dy (0.85) > Er (0.55) > Yb (0.47) > Tb (0.37) > Lu (0.25). These values serve as a basis to assist the development of legislation, including REE thresholds for Brazilian soils.(AU)

Quality reference values for rare earth elements in soils from one of the last agricultural frontiers in Brazil

ABSTRACT: Environmental impacts caused by the addition of rare earth elements (REEs) to agricultural soils are a growing concern. The sedimentary basin of the Gurguéia River is located in one of the last agricultural frontiers in Brazil; nevertheless, data regarding quality reference values (QRVs) for REEs in soils are still scarce. The objective of this study was therefore to determine the natural concentration and establish the QRVs of REEs in soils of Gurguéia watershed, Brazil. Fifty-five composite soil samples were collected at sites under no or minimal anthropic interference. The average REE natural concentrations in soils from the Gurguéia watershed were lower than those found in other regions of Brazil and worldwide, following the order (mg kg1): Ce (14.01) > Nd (6.19) > La (5.52) > Pr (2.51) > Sm (1.45) > Gd (0.93) > Dy (0.63) > Er (0.42) > Yb (0.39) > Tb (0.28) > Eu (0.26) > Lu (0.20). The parent material was the main factor that controlled the distribution of REEs in soils. The QRVs in soils followed the order (mg kg1): Ce (18.8) > Nd (7.92) > La (6.32) > Pr (3.3) > Sm (1.97) > Gd (1.35) > Dy (0.85) > Er (0.55) > Yb (0.47) > Tb (0.37) > Lu (0.25). These values serve as a basis to assist the development of legislation, including REE thresholds for Brazilian soils.

Quality reference values for rare earth elements in soils from one of the last agricultural frontiers in Brazil

Environmental impacts caused by the addition of rare earth elements (REEs) to agricultural soils are a growing concern. The sedimentary basin of the Gurguéia River is located in one of the last agricultural frontiers in Brazil; nevertheless, data regarding quality reference values (QRVs) for REEs in soils are still scarce. The objective of this study was therefore to determine the natural concentration and establish the QRVs of REEs in soils of Gurguéia watershed, Brazil. Fifty-five composite soil samples were collected at sites under no or minimal anthropic interference. The average REE natural concentrations in soils from the Gurguéia watershed were lower than those found in other regions of Brazil and worldwide, following the order (mg kg−1): Ce (14.01) > Nd (6.19) > La (5.52) > Pr (2.51) > Sm (1.45) > Gd (0.93) > Dy (0.63) > Er (0.42) > Yb (0.39) > Tb (0.28) > Eu (0.26) > Lu (0.20). The parent material was the main factor that controlled the distribution of REEs in soils. The QRVs in soils followed the order (mg kg−1): Ce (18.8) > Nd (7.92) > La (6.32) > Pr (3.3) > Sm (1.97) > Gd (1.35) > Dy (0.85) > Er (0.55) > Yb (0.47) > Tb (0.37) > Lu (0.25). These values serve as a basis to assist the development of legislation, including REE thresholds for Brazilian soils.

Can soil phosphorus availability in tropical forest systems be increased by nitrogen-fixing leguminous trees?

Understanding the role of N-fixing leguminous trees for phosphorus (P) cycling in highly weathered tropical soils is relevant for the conservation of natural forests as well as the sustainable management of agroforests and forest plantations with low P input in the Brazilian Atlantic Forest region. We hypothesized that N-fixing leguminous trees can increase the availability of soil P by exploiting different P sources without causing a depletion of soil organic P due to efficient biogeochemical cycling, but empirical evidence remains scarce. For this purpose, 31P nuclear magnetic resonance spectroscopy (31P NMR) was used for quantifying soil P forms and the Hedley sequential extraction to determine soil P fractions. The studied sites were forestry systems with leguminous trees: mixed forest plantations with different proportions of fast-growing N-fixing leguminous trees; pure plantations, and agroforestry systems with leguminous trees. The results show that all N-fixing leguminous trees and N mineral fertilization positively affected the concentrations of available soil P in relation to the control treatments. There were increases of all P fractions through cycling in all forest sites. 31P NMR spectra clearly identified and quantified that a large amount of phosphomonoesters followed by phosphodiesters in the form of DNA, as well as high reserves of Pi species (ortho-P and pyrophosphate) in the first eleven years of growth at pure plantations, mixed plantations or agroforests. The relations between both ortho-P and DNA with the resin-Pi, NaHCO3-Pi and NaOH-Pi fractions suggest that both analysis methods provide complementary information about the soil P transformations. Thus, the paper highlights the importance of the use of different N-fixing leguminous tree species under different environmental conditions, production systems and management practices for recovering heavily degraded areas, which may be a suitable strategy through efficient management of P in highly weathered tropical soils in the Brazilian Atlantic Forest biome.

Mineralogia da argila e propriedades químicas de solos do Planalto Norte Catarinense / Clay mineralogy and chemical properties of soils in the north plateau of Santa Catarina state

No Planalto Norte Catarinense são escassas as informações sobre a composição mineralógica dos solos e há poucos perfis de solo descritos e caracterizados para a região. O mapa de solos de Santa Catarina indica predominância de Cambissolos, Neossolos Litólicos e Latossolos, com Gleissolos ocupando áreas de várzeas. Esses solos ocorrem em relevo desde plano até forte ondulado, onde pequenos e médios proprietários rurais desenvolvem cultivos diversificados, com áreas expressivas de reflorestamentos com pinus. Este trabalho objetivou aprofundar o conhecimento sobre a mineralogia e as propriedades químicas de alguns desses solos, desenvolvidos de rochas sedimentares de distintas formações geológicas. Foram descritos e amostrados 5 (cinco) perfis de solo, sendo um Latossolo e quatro Cambissolos.  Na TFSA, foram feitas análises físicas (areia, silte, argila) e químicas de caracterização básica ( pH em água e sal, carbono orgânico, Ca, Mg, K, Na, Al, H+Al) e com base nesses parâmetros foi calculada a CTC efetiva, CTC pH7, Soma e Saturação por Bases. Análises mineralógicas foram conduzidas na fração argila do horizonte B de cada solo, utilizando-se difratometria de raios X. Todos os solos apresentaram reação muito ácida, com baixa soma e saturação por bases e teores elevados de carbono orgânico e Al trocável. A mineralogia da fração argila revelou predomínio de caulinitas em todos os solos, com quantidades consideráveis de illita, gibbsita e vermiculita com hidroxi-Al entrecamadas.(AU)

In the North Plateau of Santa Catarina state, Brazil, there is little information about the mineralogical composition of the soils and a few soil profiles were described and characterized in the region. The two generalized soil maps of Santa Catarina indicate predominance of Inceptisols, Entisols and Oxisols, with hydromorphic soils occupying areas of floodplains. These soils occur in relief from plane to strong wavy, where small and medium rural farmers develop diversified crops, with significant areas with pine reforestation. This work aimed to increase the knowledge of the mineralogical and chemical properties of some of these soils developed from sedimentary rocks of different geological formations. Five soil profiles were described and sampled, included one oxisol and four Inceptisols. In fine earth, physical (sand, silt, clay) and chemical analyzes were performed (pH in water, organic carbon, Ca2+, Mg, K, Na, Al, H + Al) and based on these attributes was calculated effective CEC, CEC at pH7, sum of bases and base saturation. Mineralogical analyzes were conducted in the clay fraction of the B horizon of each soil, using X-ray diffraction techniques. All soils showed very acid reaction, with low sum of bases and base saturation and high levels of organic carbon and exchangeable Al. The clay mineralogy revealed predominance of kaolinite in all soils, with considerable amounts of gibbsite, and vermiculite with hydroxy-Al interlayered.(AU)

Mineralogia da argila e propriedades químicas de solos do Planalto Norte Catarinense / Clay mineralogy and chemical properties of soils in the north plateau of Santa Catarina state

No Planalto Norte Catarinense são escassas as informações sobre a composição mineralógica dos solos e há poucos perfis de solo descritos e caracterizados para a região. O mapa de solos de Santa Catarina indica predominância de Cambissolos, Neossolos Litólicos e Latossolos, com Gleissolos ocupando áreas de várzeas. Esses solos ocorrem em relevo desde plano até forte ondulado, onde pequenos e médios proprietários rurais desenvolvem cultivos diversificados, com áreas expressivas de reflorestamentos com pinus. Este trabalho objetivou aprofundar o conhecimento sobre a mineralogia e as propriedades químicas de alguns desses solos, desenvolvidos de rochas sedimentares de distintas formações geológicas. Foram descritos e amostrados 5 (cinco) perfis de solo, sendo um Latossolo e quatro Cambissolos.  Na TFSA, foram feitas análises físicas (areia, silte, argila) e químicas de caracterização básica ( pH em água e sal, carbono orgânico, Ca, Mg, K, Na, Al, H+Al) e com base nesses parâmetros foi calculada a CTC efetiva, CTC pH7, Soma e Saturação por Bases. Análises mineralógicas foram conduzidas na fração argila do horizonte B de cada solo, utilizando-se difratometria de raios X. Todos os solos apresentaram reação muito ácida, com baixa soma e saturação por bases e teores elevados de carbono orgânico e Al trocável. A mineralogia da fração argila revelou predomínio de caulinitas em todos os solos, com quantidades consideráveis de illita, gibbsita e vermiculita com hidroxi-Al entrecamadas.

In the North Plateau of Santa Catarina state, Brazil, there is little information about the mineralogical composition of the soils and a few soil profiles were described and characterized in the region. The two generalized soil maps of Santa Catarina indicate predominance of Inceptisols, Entisols and Oxisols, with hydromorphic soils occupying areas of floodplains. These soils occur in relief from plane to strong wavy, where small and medium rural farmers develop diversified crops, with significant areas with pine reforestation. This work aimed to increase the knowledge of the mineralogical and chemical properties of some of these soils developed from sedimentary rocks of different geological formations. Five soil profiles were described and sampled, included one oxisol and four Inceptisols. In fine earth, physical (sand, silt, clay) and chemical analyzes were performed (pH in water, organic carbon, Ca2+, Mg, K, Na, Al, H + Al) and based on these attributes was calculated effective CEC, CEC at pH7, sum of bases and base saturation. Mineralogical analyzes were conducted in the clay fraction of the B horizon of each soil, using X-ray diffraction techniques. All soils showed very acid reaction, with low sum of bases and base saturation and high levels of organic carbon and exchangeable Al. The clay mineralogy revealed predominance of kaolinite in all soils, with considerable amounts of gibbsite, and vermiculite with hydroxy-Al interlayered.

High genetic diversity among and within bitter manioc varieties cultivated in different soil types in Central Amazonia

Abstract Although manioc is well adapted to nutrient-poor Oxisols of Amazonia, ethnobotanical observations show that bitter manioc is also frequently cultivated in the highly fertile soils of the floodplains and Amazonian dark earths (ADE) along the middle Madeira River. Because different sets of varieties are grown in each soil type, and there are agronomic similarities between ADE and floodplain varieties, it was hypothesized that varieties grown in ADE and floodplain were more closely related to each other than either is to varieties grown in Oxisols. We tested this hypothesis evaluating the intra-varietal genetic diversity and the genetic relationships among manioc varieties commonly cultivated in Oxisols, ADE and floodplain soils. Genetic results did not agree with ethnobotanical expectation, since the relationships between varieties were variable and most individuals of varieties with the same vernacular name, but grown in ADE and floodplain, were distinct. Although the same vernacular name could not always be associated with genetic similarities, there is still a great amount of variation among the varieties. Many ecological and genetic processes may explain the high genetic diversity and differentiation found for bitter manioc varieties, but all contribute to the maintenance and amplification of genetic diversity within the manioc in Central Amazonia.

Effect of Soil Water Content on the Distribution of Diuron into Organomineral Aggregates of Highly Weathered Tropical Soils.

We evaluated the effects of soil water content on the retention of diuron and its residual distribution into organomineral aggregates in four Brazilian oxisols. (14)C-Diuron was incubated for days at 25, 50, and 75% of maximum water-holding capacity for each soil. After 42 days, the physical fractionation method was used to obtain >150, 53-150, 20-53, 2-20, and <2 µm aggregate sizes. Diuron retention increased with increasing soil water content for all soils. At lower soil water content, diuron's retention was higher in the sandier soil. It was mostly retained in the fine (<20 µm) aggregates of sandier soil, and for clayed soils, retention was higher in the coarse aggregates (>53 µm). The sorption coefficients (Kd and Koc) generated by batch studies should be carefully used because they do not provide information about aggregation and diffusion effects on pesticides soil sorption.

Effects of soil attributes and straw accumulation on the sorption of hexazinone and tebuthiuron in tropical soils cultivated with sugarcane.

Brazil is the largest sugarcane producer in the world in which hexazinone (3-cyclohexyl-6-dimethylamino-1-methyl-1,3,5-triazine-2,4-dione) and tebuthiuron (1-(5-tert-butyl-1,3,4-thiadiazol-2-yl)-1,3-dimethylurea) are heavily used. Sugarcane harvesting is changing from the manual system with previous straw burning to the mechanized system without straw burning. The lack of burning results in soil organic carbon accumulation mainly in clayey soils, which should affect herbicides availability and fate. Therefore, we evaluated sorption of these herbicides in soil samples with and without straw burning. Both herbicides presented low apparent sorption coefficients (mean K(d,app)= 0.6 and 2.4 L kg(-1) for hexazinone and tebuthiuron, respectively), suggesting that they may leach to groundwater. Moreover, their sorption correlated primarily with soil organic carbon (SOC), but iron oxide contents extracted with ammonium oxalate (Fe2O3(AOX)) also affected it (K(d,app) = -0.228 + 0.0397 SOC + 0.117 Fe2O3(AOX) for hexazinone and K(d,app) = -1.407 + 0.201 SOC + 0.348 Fe2O3(AOX) for tebuthiuron). Soil organic carbon accumulation due to straw maintenance in the field positively affected sorption of both herbicides, but its effects were not enough to classify them as "non-leachers."

Eficiência de malhas amostrais utilizadas na caracterização da variabilidade espacial de fósforo e potássio / Efficiency of sampling grids used in the characterization of phosphorus and potassium

O objetivo do trabalho foi estudar a eficiência das malhas amostrais, utilizadas nas áreas manejadas com agricultura de precisão, para a caracterização da variabilidade espacial dos teores de fósforo (P) e potássio (K). O estudo foi conduzido em 30 áreas agrícolas, localizadas no Rio Grande do Sul, cujos solos foram classificados como Latossolos Vermelhos. As dimensões das malhas amostrais estudadas foram: 100x100m (10 áreas), 142x142m (10 áreas) e 173x173m (10 áreas). Foram analisados os teores de P e K na profundidade de 0,00-0,10m. Os dados foram submetidos à análise estatística descritiva e a análise geoestatística. De modo geral, as áreas estudadas apresentaram teores médios de P e K adequados ao desenvolvimento das culturas. Entretanto, observaram-se locais com baixos teores de P, justificando fertilizações em sítio-específico. Com base em parâmetros geoestatísticos, as dimensões de malhas amostrais utilizadas são eficientes em captar as diferentes escalas da variabilidade espacial de P e K, porém, recomenda-se o uso de malhas amostrais menores, que considerem a variabilidade espacial a curtas distâncias.(AU)

The objective of the research was to evaluate the efficiency of the sampling grids, used in areas managed with precision agriculture, for the characterization of spatial variability levels of phosphorus (P) and potassium (K). The study was conducted in 30 agricultural areas, located in Rio Grande do Sul state, presenting soils classified as Oxisols. The sizes of the sampling grids studied were: 100x100m (10 areas), 142x142m (10 areas) and 173x173m (10 areas).Were analyzed the levels of P and K, in depth of sampling from 0.00-0.10m. The data were subjected to descriptive statistical analysis and geostatistical analysis. In, general, the areas showed average levels of P and K suitable for crops development. However, were observed subareas with low levels of P, justifying fertilization on site-specific. Based on geostatistical parameters, sizes of the sampling grids used are efficient to capture the different scales of spatial variability of P and K, however, it is indicated smaller sampling grids to consider the spatial variability over short distances.(AU)

Eficiência de malhas amostrais utilizadas na caracterização da variabilidade espacial de fósforo e potássio / Efficiency of sampling grids used in the characterization of phosphorus and potassium

O objetivo do trabalho foi estudar a eficiência das malhas amostrais, utilizadas nas áreas manejadas com agricultura de precisão, para a caracterização da variabilidade espacial dos teores de fósforo (P) e potássio (K). O estudo foi conduzido em 30 áreas agrícolas, localizadas no Rio Grande do Sul, cujos solos foram classificados como Latossolos Vermelhos. As dimensões das malhas amostrais estudadas foram: 100x100m (10 áreas), 142x142m (10 áreas) e 173x173m (10 áreas). Foram analisados os teores de P e K na profundidade de 0,00-0,10m. Os dados foram submetidos à análise estatística descritiva e a análise geoestatística. De modo geral, as áreas estudadas apresentaram teores médios de P e K adequados ao desenvolvimento das culturas. Entretanto, observaram-se locais com baixos teores de P, justificando fertilizações em sítio-específico. Com base em parâmetros geoestatísticos, as dimensões de malhas amostrais utilizadas são eficientes em captar as diferentes escalas da variabilidade espacial de P e K, porém, recomenda-se o uso de malhas amostrais menores, que considerem a variabilidade espacial a curtas distâncias.

The objective of the research was to evaluate the efficiency of the sampling grids, used in areas managed with precision agriculture, for the characterization of spatial variability levels of phosphorus (P) and potassium (K). The study was conducted in 30 agricultural areas, located in Rio Grande do Sul state, presenting soils classified as Oxisols. The sizes of the sampling grids studied were: 100x100m (10 areas), 142x142m (10 areas) and 173x173m (10 areas).Were analyzed the levels of P and K, in depth of sampling from 0.00-0.10m. The data were subjected to descriptive statistical analysis and geostatistical analysis. In, general, the areas showed average levels of P and K suitable for crops development. However, were observed subareas with low levels of P, justifying fertilization on site-specific. Based on geostatistical parameters, sizes of the sampling grids used are efficient to capture the different scales of spatial variability of P and K, however, it is indicated smaller sampling grids to consider the spatial variability over short distances.

Soybean yield in response to application of phosphate rock associated with triple superphosphate

Soybean (Glycine max L. Merrill) crop started to be planted in the Brazilian Cerrado in the 1970's, and this region currently contributes with 57% of total soybean production in Brazil. Under natural conditions in this region, the soils present chemical limitations such as low pH, low Cation Exchange Capacity, low nutrient availability, and moreover, clayey soils have a high P fixation capacity mainly due to high contents of Fe/Al oxides. Since P is the most limiting nutrient is this region, a study was performed in the state of Maranhão, Brazil, in a Typic Hapludox, with clayey texture and low available P (extracted by resin). Treatments were defined to evaluate soybean response to broadcast Arad phosphate rock (PR) plus banded triple superphosphate (TSP) and to evaluate the soybean response to three proportions of PR and TSP. The experiment was established in October 2004 and was carried out for three consecutive crop years (2004/05 to 2006/07). The associated use of PR and TSP, in several situations, resulted in yields at least similar to that obtained with the use of the water soluble P source and, in some cases, even using lower P rates. Regarding the "mixtures", a linear response was observed when they were banded; however, when they were broadcasted, no increase in yield was observed above 50% of relative solubility. In conclusion, the association of sources differing in solubility may be a feasible agronomic option for P fertilizer management of soybeans.

O cultivo de soja (Glycine max L. Merrill) na região do Cerrado iniciou-se na década de 1970 e, atualmente, representa aproximadamente 57% da produção total do Brasil. Sob condições naturais, os solos dessa região apresentam limitações químicas, como baixos valores de pH, de Capacidade de Troca de Cátions, de disponibilidade de nutrientes, bem como elevada capacidade de fixação de P nos solos de textura argilosa, principalmente pelos altos teores de óxidos de Fe/Al. Levando-se em conta que o P é o nutriente mais limitante à produção nessa região, foi instalado um experimento no estado do Maranhão, em Latossolo Vermelho-Amarelo distrófico argiloso e com baixo teor disponível de P (extraído com resina). Objetivou-se verificar a resposta da cultura à aplicação do fosfato de rocha Arad (FR) em área total mais superfosfato triplo (SFT) em aplicação localizada; e verificar a resposta da cultura a três proporções de FR e SFT. O experimento foi instalado em outubro de 2004 e conduzido por três safras consecutivas (2004/05 a 2006/07). A utilização associada de FR e SFT, em várias condições, resultou em produtividades no mínimo semelhantes à obtida com a fonte solúvel e, em alguns casos, até utilizando menores quantidades de P. Quanto às "misturas", verificou-se resposta linear para a aplicação localizada; entretanto, para a aplicação a lanço, não houve aumento na produtividade a partir de 50% de solubilidade relativa. Logo, a associação de fontes com solubilidades distintas pode ser uma opção agronomicamente viável para o manejo da adubação fosfatada da soja.

Iron and aluminum forms and their relationship with texture, mineralogy and organic carbon in the Cerrado Oxisol / Formas de ferro e alumínio e suas relações com textura, mineralogia e carbono orgânico em Latossolos do Cerrado

The Oxisols of the Cerrado region have a simple mineralogy, and are composed mainly of kaolinite and iron and aluminium oxides. The aim of this work was to perform a sequential extraction of iron and aluminium and to relate them to texture, mineralogy and organic carbon in Oxisols of the Cerrado region. The soil samples, 35 in total, were taken from the 020 cm layer in Oxisols under pasture located in the Brazilian Cerrado Region. The levels of iron and aluminum extracted by full attack, dithionite-citrate-bicarbonate, ammonium oxalate and sodium pyrophosphate were analyzed according to the textural classes using the Kruskal-Wallis nonparametric test. Then these data were related to the mineralogy and organic carbon through a principal component analysis. Whatever the textures, iron oxides of high degree of crystallinity were the main form of iron and are positively correlated with the iron total content. The aluminum oxides have a high affinity to organic carbon than iron oxides. The levels of iron and aluminum extracted by sodium pyrophosphate were closely related to soil pH.

Os Latossolos da região do Cerrado apresentam mineralogia da fração argila relativamente simples, sendo constituídos principalmente por caulinita e óxidos de ferro e de alumínio. O objetivo deste trabalho foi realizar extrações sequênciais de ferro e de alumínio e relacioná-los à mineralogia, textura e teores de carbono orgânico em Latossolos da região do Cerrado. Coletaram-se 35 amostras na camada de 0-20 cm de Latossolos sob pastagem da Região do Cerrado. Os teores de ferro e de alumínio extraídos pelo ataque total, ditionito-citrato-bicarbonato de sódio, oxalato ácido de amônia e pirofosfato de sódio foram analisados de acordo com a classe textural através do teste não paramétrico de Kruskal-Wallis. Em seguida estes dados foram relacionados com a mineralogia e o carbono orgânico por meio de uma análise de componentes principais. Independentemente da classe textural, os óxidos de ferro de alto grau de cristalinidade representaram a principal forma de ferro e se correlacionam positivamente com os teores totais de ferro. Os óxidos de alumínio apresentaram maior afinidade ao carbono orgânico do que os óxidos de ferro. Os teores de ferro e alumínio extraídos pelo pirofosfato foram estreitamente relacionados ao pH dos solos.

Soybean yield in response to application of phosphate rock associated with triple superphosphate

Soybean (Glycine max L. Merrill) crop started to be planted in the Brazilian Cerrado in the 1970's, and this region currently contributes with 57% of total soybean production in Brazil. Under natural conditions in this region, the soils present chemical limitations such as low pH, low Cation Exchange Capacity, low nutrient availability, and moreover, clayey soils have a high P fixation capacity mainly due to high contents of Fe/Al oxides. Since P is the most limiting nutrient is this region, a study was performed in the state of Maranhão, Brazil, in a Typic Hapludox, with clayey texture and low available P (extracted by resin). Treatments were defined to evaluate soybean response to broadcast Arad phosphate rock (PR) plus banded triple superphosphate (TSP) and to evaluate the soybean response to three proportions of PR and TSP. The experiment was established in October 2004 and was carried out for three consecutive crop years (2004/05 to 2006/07). The associated use of PR and TSP, in several situations, resulted in yields at least similar to that obtained with the use of the water soluble P source and, in some cases, even using lower P rates. Regarding the "mixtures", a linear response was observed when they were banded; however, when they were broadcasted, no increase in yield was observed above 50% of relative solubility. In conclusion, the association of sources differing in solubility may be a feasible agronomic option for P fertilizer management of soybeans.

O cultivo de soja (Glycine max L. Merrill) na região do Cerrado iniciou-se na década de 1970 e, atualmente, representa aproximadamente 57% da produção total do Brasil. Sob condições naturais, os solos dessa região apresentam limitações químicas, como baixos valores de pH, de Capacidade de Troca de Cátions, de disponibilidade de nutrientes, bem como elevada capacidade de fixação de P nos solos de textura argilosa, principalmente pelos altos teores de óxidos de Fe/Al. Levando-se em conta que o P é o nutriente mais limitante à produção nessa região, foi instalado um experimento no estado do Maranhão, em Latossolo Vermelho-Amarelo distrófico argiloso e com baixo teor disponível de P (extraído com resina). Objetivou-se verificar a resposta da cultura à aplicação do fosfato de rocha Arad (FR) em área total mais superfosfato triplo (SFT) em aplicação localizada; e verificar a resposta da cultura a três proporções de FR e SFT. O experimento foi instalado em outubro de 2004 e conduzido por três safras consecutivas (2004/05 a 2006/07). A utilização associada de FR e SFT, em várias condições, resultou em produtividades no mínimo semelhantes à obtida com a fonte solúvel e, em alguns casos, até utilizando menores quantidades de P. Quanto às "misturas", verificou-se resposta linear para a aplicação localizada; entretanto, para a aplicação a lanço, não houve aumento na produtividade a partir de 50% de solubilidade relativa. Logo, a associação de fontes com solubilidades distintas pode ser uma opção agronomicamente viável para o manejo da adubação fosfatada da soja.

Iron and aluminum forms and their relationship with texture, mineralogy and organic carbon in the Cerrado Oxisol / Formas de ferro e alumínio e suas relações com textura, mineralogia e carbono orgânico em Latossolos do Cerrado

The Oxisols of the Cerrado region have a simple mineralogy, and are composed mainly of kaolinite and iron and aluminium oxides. The aim of this work was to perform a sequential extraction of iron and aluminium and to relate them to texture, mineralogy and organic carbon in Oxisols of the Cerrado region. The soil samples, 35 in total, were taken from the 020 cm layer in Oxisols under pasture located in the Brazilian Cerrado Region. The levels of iron and aluminum extracted by full attack, dithionite-citrate-bicarbonate, ammonium oxalate and sodium pyrophosphate were analyzed according to the textural classes using the Kruskal-Wallis nonparametric test. Then these data were related to the mineralogy and organic carbon through a principal component analysis. Whatever the textures, iron oxides of high degree of crystallinity were the main form of iron and are positively correlated with the iron total content. The aluminum oxides have a high affinity to organic carbon than iron oxides. The levels of iron and aluminum extracted by sodium pyrophosphate were closely related to soil pH.

Os Latossolos da região do Cerrado apresentam mineralogia da fração argila relativamente simples, sendo constituídos principalmente por caulinita e óxidos de ferro e de alumínio. O objetivo deste trabalho foi realizar extrações sequênciais de ferro e de alumínio e relacioná-los à mineralogia, textura e teores de carbono orgânico em Latossolos da região do Cerrado. Coletaram-se 35 amostras na camada de 0-20 cm de Latossolos sob pastagem da Região do Cerrado. Os teores de ferro e de alumínio extraídos pelo ataque total, ditionito-citrato-bicarbonato de sódio, oxalato ácido de amônia e pirofosfato de sódio foram analisados de acordo com a classe textural através do teste não paramétrico de Kruskal-Wallis. Em seguida estes dados foram relacionados com a mineralogia e o carbono orgânico por meio de uma análise de componentes principais. Independentemente da classe textural, os óxidos de ferro de alto grau de cristalinidade representaram a principal forma de ferro e se correlacionam positivamente com os teores totais de ferro. Os óxidos de alumínio apresentaram maior afinidade ao carbono orgânico do que os óxidos de ferro. Os teores de ferro e alumínio extraídos pelo pirofosfato foram estreitamente relacionados ao pH dos solos.

Soils and agriculture in central-west and north Brazil

Modern soil science, spearheaded by research in Brazil has facilitated the utilization of vast areas of previously uncultivated soil long considered unsuitable for human food production into highly productive agricultural land. Naturally acid soils with high contents of aluminum and iron oxides and low CEC values and organic matter contents long considered insurmountable obstacles to crop production in tropical latitudes could be extremely productive. With continued development of the infrastructure needed by commercial agriculture Brazil has the potential to lead the world in its quest to provide food for growing human populations.

A moderna ciência de solo, liderada pelas suas pesquisas no Brasil, tem possibilitado a utilização de vastas áreas de solos, durante muito tempo não cultivados por serem avaliados como inaptos para uma intensiva produção de alimentos. Hoje, ao contrário, constata-se que essas terras são altamente produtivas para a agricultura. Estas pesquisas vêm mostrando que alguns atributos naturais destes solos, como acidez, baixos teores de matéria orgânica, baixa capacidade de troca de cátions, além de altos teores de óxidos de ferro e/ou de alumínio - considerados como obstáculos à produção de boas colheitas em latitudes tropicais - podem ser superados. Com a continuação do desenvolvimento das infra-estruturas necessárias para alavancar ainda mais a agricultura comercial, o Brasil tem potencial para, em breve, liderar o mundo no que tange ao fornecimento de alimentos para as crescentes populações humanas.

Soils and agriculture in central-west and north Brazil

Modern soil science, spearheaded by research in Brazil has facilitated the utilization of vast areas of previously uncultivated soil long considered unsuitable for human food production into highly productive agricultural land. Naturally acid soils with high contents of aluminum and iron oxides and low CEC values and organic matter contents long considered insurmountable obstacles to crop production in tropical latitudes could be extremely productive. With continued development of the infrastructure needed by commercial agriculture Brazil has the potential to lead the world in its quest to provide food for growing human populations.

A moderna ciência de solo, liderada pelas suas pesquisas no Brasil, tem possibilitado a utilização de vastas áreas de solos, durante muito tempo não cultivados por serem avaliados como inaptos para uma intensiva produção de alimentos. Hoje, ao contrário, constata-se que essas terras são altamente produtivas para a agricultura. Estas pesquisas vêm mostrando que alguns atributos naturais destes solos, como acidez, baixos teores de matéria orgânica, baixa capacidade de troca de cátions, além de altos teores de óxidos de ferro e/ou de alumínio - considerados como obstáculos à produção de boas colheitas em latitudes tropicais - podem ser superados. Com a continuação do desenvolvimento das infra-estruturas necessárias para alavancar ainda mais a agricultura comercial, o Brasil tem potencial para, em breve, liderar o mundo no que tange ao fornecimento de alimentos para as crescentes populações humanas.