Blunt force trauma and blast injuries to head and chest caused by a potent pyrotechnic device: a case report.

In times of peace and except for terrorist attacks, fatalities by explosions are rare. Fireworks have deadly potential, especially self-made or illegally acquired devices. The use of professional pyrotechnics by untrained persons poses a life-threatening hazard. We present a case of devastating blunt force and blast injuries to the head and chest of a young man. After ignition of a display shell (syn. a real shell or mortar shell) without the use of a launching pipe, the device hit the man's face, nearly simultaneously followed by the explosion of the burst charge. The autopsy revealed injuries to the face and forehead as well as extensive tissue structure damage and a massive contusion with a bloody edema of the lungs. Autopsy results are supplemented with CT imaging and 3D reconstruction of the fractured mid face, as well as histological and toxicological examinations. This case of a misused display shell demonstrates both its devastating destructive potential and the corresponding and rarely observed injury pattern.

Pyrotechnic Delay Compositions Based on BaO2: Not as "Green" as Expected.

The aims of this study were to investigate the potential of using barium peroxide as an environmentally friendly oxidising agent, to evaluate the composition of the combustion products of the developed pyrotechnic delay compositions (PDCs) and to provide information about the impact of the utilised metallic fuel (Mg, Al, Fe or Cu) on the properties of those PDCs. The PDCs exhibited acceptable friction and impact sensitivity values. This allowed conducting further experiments, e.g., determining the linear combustion velocity of the PDCs as a function of oxygen balance (OB). Based on the composition of the post-combustion residues, determined by Raman spectroscopy and SEM-EDS, an initial mechanism for the combustion of the developed PDCs was proposed.

Evaluation and testing of emission on Sargassum wightii-based flash powder composition.

Fireworks that are used in our day-to-day life are also becoming a part of greenhouse emission in the environment. Hence, it becomes the need of the hour to act immediately to reduce environmental pollution so that the future becomes safer. The objective of the current research work focuses on the reduction of pollution caused due to the emission from burning fireworks and this work is intended to reduce the sulphur emissions from crackers. One of the important ingredients used in pyrotechnics is flash powder. The traditional flash powder composition contains aluminium powder as fuel, potassium nitrate as an oxidizer and sulphur as an igniter at defined levels. To reduce the impact of sulphur emissions in flash powder, an organic compound like Sargassum wightii brown seaweed powder is used as a replacement at prescribed levels and the experimentation is carried out. It is found that the sulphur weightage in the flash powder composition can be replaced up to 50% with the Sargassum wightii brown seaweed powder without affecting the traditional performance of the flash powder. To study the emissions taking place in the flash powder composition, a specially designed flash powder emission testing chamber has been developed. Three different compositions of flash powder compositions were made and they are named SP (no seaweed powder), SP5 (5% seaweed powder) and SP10 (10% seaweed powder) respectively as per the use of Sargassum wightii seaweed powder in the traditional flash powder composition. During testing, it has been found that the emission of sulphur has been reduced up to a maximum of 17% in SP% and 24% in SP10 flash powder composition. It is also evident that the flash powder composition with Sargassum wightii can result in a reduction in toxic sulphur emission by up to 21% on the modified flash powder. Furthermore, it has been found that the auto-ignition temperature of the existing and modified flash powder compositions was in the range of 353-359 °C, 357-363 °C and 361-365 °C for SP, SP5 and SP10 compositions respectively. FTIR analysis proved the presence of carbon, sulphur and nitro compounds in the Sargassum wightii seaweed powder.

From the laboratory to the field: Chemical analysis of colored smoke pyrotechnic formulations via mass spectrometry techniques.

Smoke dyes are complex molecular systems that have the potential to form many molecular derivatives and fragments when deployed. The chemical analysis of smoke samples is challenging due to the adiabatic temperature of the pyrotechnic combustion and the molecular complexity of the physically dispersed reaction products. Presented here is the characterization of the reaction byproducts of a simulant Mk124 smoke signal on a multigram scale, which contain the dye disperse red 9 (1-(methylamino)anthraquinone), by ambient ionization mass spectrometry. Our previous work has examined the thermal decomposition of a simplified smoke system consisting of disperse red 9, potassium chlorate, and sucrose by anaerobic pyrolysis gas chromatography mass spectrometry performed at the laboratory milligram scale. The results from the lab scale test were compared with a fully functioned Mk124 in the field. To achieve this, Mk124 smokes were functioned in the presence of sampling swabs that collected byproduct residues from the smoke plume in the ambient environment. These swabs were then analyzed using ambient ionization mass spectrometry to identify the expended pyrotechnic residues, with particular interest in halogenated species. Previous work determined the toxicity of unforeseen byproducts identified on the laboratory scale, which were also detected in the field demonstrating the correlation of the laboratory testing to the fielded systems. By understanding the chemical composition of smokes and their reaction products, potential toxicity effects can be easily assessed, leading to safer formulations with improved performance. These results can help assess how smoke byproducts may impact Warfighter performance, personnel health, and the environment.

[Pandemic-related sales ban of fireworks in Germany leads to a significant reduction of firework-related eye injuries]. / Pandemiebedingtes Verkaufsverbot von Feuerwerkskörpern in Deutschland führt zu einer deutlichen Abnahme der Augenverletzungen.

BACKGROUND AND AIM: The continuous recording of eye injuries caused by fireworks around New Year's Eve over 6 years allows us to investigate injury numbers, injury patterns, and accident histories in a year to year comparison. In order to relieve the burden on hospitals during the COVID-19 pandemic, a ban on the sale of firework articles was implemented in Germany for 2020/2021 and 2021/2022. We investigate the impact of these measures on the number of fireworks-related eye injuries and analyze whether this led to an increase in serious injuries and an association with increased use of homemade pyrotechnics or pyrotechnics potentially not approved in Germany. METHODS: We used our online questionnaire to collect anonymized data on patients, accident history, and, since 2017/2018 information on the acquisition of firework articles. RESULTS: Our analysis included data from 2151 affected individuals. While data of about 500 injured were entered per year before the pandemic, this number decreased to 79 in 2020/2021 and 193 in 2021/2022. The proportion of severe eye injuries requiring inpatient care ranged from 21% to 26% in the years before the pandemic but ranged from 27% to 34% in the pandemic years. At the same time, under the sales ban the proportion of fireworks that were homemade or unofficially purchased increased from 3% to nearly 10%. In terms of absolute numbers, however, there were 67 accidents involving unofficially purchased pyrotechnics compared with 1675 incidents involving officially purchased or unidentified fireworks, which can be explained by the high proportion (about 50%) of injured bystanders. CONCLUSION: The absolute number of patients with eye injuries caused by pyrotechnics decreased under the pandemic conditions from about 500 to 79 or 193. The use of fireworks designated as unofficially purchased was proportionally low even under the sales ban, and plays a minor role compared to injuries with officially purchased fireworks articles.

Design of a Double-Layer Electrothermal MEMS Safety and Arming Device with a Bistable Mechanism.

Considering the safety of ammunition, safety and arming (S&A) devices are usually designed in pyrotechnics to control energy transfer through a movable barrier mechanism. To achieve both intelligence and miniaturization, electrothermal actuators are used in MEMS S&A devices, which can drive the barrier to an arming position actively. However, only when the actuators' energy input is continuous can the barrier be stably kept in the arming position to wait for ignition. Here, we propose the design and characterization of a double-layer electrothermal MEMS S&A Device with a bistable mechanism. The S&A device has a double-layer structure and four groups of bistable mechanisms. Each bistable mechanism consists of two V-shape electrothermal actuators to drive a semi-circular barrier and a pawl, respectively, and control their engagement according to a specific operation sequence. Then, the barrier can be kept in the safety or the arming position without energy input. To improve the device's reliability, the four groups of bistable mechanisms are axisymmetrically placed in two layers to constitute a double-layer barrier structure. The test results show that the S&A device can use constant-voltage driving or the capacitor-discharge driving to drive the double-layer barrier to the safety or the arming position and keep it on the position passively by the bistable mechanism.

Access to Green Pyrotechnic Compositions via Constructing Coordination Polymers: A New Approach to the Application of 3,4-Dinitropyrazole.

Alkali and alkaline-earth metal salts with 3,4-dinitropyrazole (DNP) were synthesized by the reaction of DNP with stoichiometric amounts of the corresponding metal hydroxide-, oxide-, or carbonate-based highly pure salts, and products were fully characterized. Determination of single-crystal structures of all new complexes except for the lithium and strontium salts was performed by X-ray diffraction techniques. The cesium salt crystallized no water among them. Differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA) manifested that these salts have satisfactory thermal stabilities with decomposition temperatures above 210 °C. They also showed that there exists strong bonding of crystallized water among lattices, which disappeared at temperatures equal to or above 115 °C except for salts MES-3, MES-4, and MES-9. In addition, the percentage of water contents was confirmed by using DSC and TGA methods. The constant-volume combustion heats of these metal salts containing DNP anions were measured using an oxygen bomb calorimeter due to their expectant interest in energetic materials, and their standard molar formation enthalpies were obtained. The investigated salts were found to be insensitive toward friction and impact. Findings of burning tests performed with experimental formulations using MES-1, MES-7, MES-8, and MES-9 certify that these four salts might be more promising candidates for application in green pyrotechnics.

Thermite reaction driven pyrotechnic formulation with promising functional performance and reduced emissions.

Green pyrotechnics/firecrackers reported herein are driven by thermite reactions for self-contained and self-sustained exothermic chemical reactions to make heat and sound by the usage of minimal fuel (aluminum), oxidizer (potassium nitrate), and Sulfur. These firecrackers have the potential for generating less emissions (70%) compared to commercial firecracker-based counterparts due to the presence of additives and are therefore designated as "Green firecrackers" or reduced emissions firecrackers. The functional performance and long-term stability of the composition was investigated through sound measurement and different tests, including ageing, thermal stability, and moisture test. The thermodynamics of the facilitated thermite reaction was cross-checked with experimental and theoretical methods. Prevalent mechanism for a substantial reduction in emissions to the tune of about 70% has been discussed. Cost of the green firecrackers is at par with the commercial firecrackers as cost of raw materials being used to prepare the formulation is comparable to the relatively toxic oxidizer substituted. "Green firecrackers" developed and reported here are environmentally benign in nature with higher business potential as far as a green chemistry-based sustainable solution for the society is required.

Guanidinium 5,5'-Azotetrazolate: A Colorful Chameleon for Halogen-Free Smoke Signals.

A progressive halogen-free multicolored smoke system to obtain white, red, violet, yellow, green, and blue smoke color is presented. The nitrogen-rich salt guanidinium 5,5'-azotetrazolate (GZT), which is usually applied as a gas generator or propellant ingredient, was combined with different smoke dyes (Solvent Red 1, Solvent Violet 47, Solvent Green 3, Solvent Yellow 33). These two-component smoke mixtures offer a convenient and safe multicolor approach without the need for potassium chlorate or any other hazardous material. The common smoke characteristics with respect to burn time/burn rate, yield factor, transfer rate, as well as energetic properties were determined and compared with classic chlorate-based formulations currently used. To the best of our knowledge, nothing comparable is known in the literature and a completely new research area in modern pyrotechnics is opened.

Emerging techniques for the detection of pyrotechnic residues from seized postal packages containing fireworks.

High volume screening of parcels with the aim to trace the illegal distribution and selling of fireworks using postal services is challenging. Inspection services have limited manpower and means to perform extensive visual inspection. In this study, the presence of solid pyrotechnic residues collected from cardboard shipping parcels containing fireworks was investigated for direct in-field chemical detection. Two emerging trace detection techniques, i.e., capillary electrophoresis (CE)-based inorganic oxidizer detector and infrared thermal desorption (IRTD) coupled with direct analysis in real time mass spectrometry (DART-MS), were investigated for their potential as screening tools. Detection of non-visible pyrotechnic trace residues from real-case seized parcels was demonstrated using both screening techniques. However, the high nitrate background in the commercial CE system complicated its screening for black powder traces. IRTD-DART-MS allowed differentiation between flash and black powder by identification of the molecular inorganic ions. Compared to the portable CE instrument, rapid screening using IRTD-DART-MS is currently limited to laboratory settings. The capabilities of these emerging techniques established solid particle and trace residue chemical detection as interesting options for parcel screening in a logistic setting.

Trace Detection and Chemical Analysis of Homemade Fuel-Oxidizer Mixture Explosives: Emerging Challenges and Perspectives.

The chemical analysis of homemade explosives (HMEs) and improvised explosive devices (IEDs) remains challenging for fieldable analytical instrumentation and sensors. Complex explosive fuel-oxidizer mixtures, black and smokeless powders, flash powders, and pyrotechnics often include an array of potential organic and inorganic components that present unique interference and matrix effect difficulties. The widely varying physicochemical properties of these components as well as external environmental interferents and background challenge many sampling and sensing modalities. This review provides perspective on these emerging challenges, critically discusses developments in sampling, sensors, and instrumentation, and showcases advancements for the trace detection of inorganic-based explosives.

Thermal and Sensitiveness Determination of Cubanes: Towards Cubane-Based Fuels for Infrared Countermeasures.

As infrared seeking technology evolves, threats are better able to distinguish defensive infrared (IR) flares from true targets. Spectrally matched flares, which generally employ carbon-based fuels, are better able to decoy some advanced missiles by more closely mimicking the IR emission of the target. Cubane is a high-energy carbon-based scaffold which may be suitable for use as a fuel in spectrally matched flares. The enthalpy of formation and strain energy of a series of cubanes was predicted in silico, and their thermal and impact stability examined. All were found to undergo highly exothermic decomposition in sealed cell differential scanning calorimetry, and two cubanes subsequently underwent quantitative sensitiveness testing. Despite their F of I values being in the secondary explosive range, cubane-1,4-dicarboxylic acid (F of I=70) and 4-carbamoylcubane-1-carboxylic acid (F of I=90) were identified as potentially useful fuels for pyrotechnic infrared countermeasure flare formulations.

Development of Pyro-Drive Jet Injector With Controllable Jet Pressure.

Various jet injectors have been developed and used for the effective and efficient administration of drugs. Jet injections overcome the limitations of other drug delivery methods, such as ablation, iontophoresis, electroporation, sonophoresis, and microneedles, because jet injection is not limited by the diffusion rates of different drugs. However, controlling the jet pressure during drug delivery is difficult with most conventional jet injectors. Efficacy evaluation of such devices on laboratory animals is strongly required before initiating human clinical trials, but minimal research has been performed for the device developments. Therefore, we developed jet injector devices based on pyrotechnics using 2 types of explosives with different burning rates; we call these pyro-drive jet injectors. The liquid jet pressure profile suggests that the penetration depth and injection volume for soft materials and skin tissue are controllable. Here, we propose the pyro-drive jet injectors as another candidate well-controlled jet injector for laboratory animals in drug discovery testing as well as human clinical use.

Multicomponent characterization and differentiation of flash bangers - Part I: Sample collection and visual examination.

To continue to assist law enforcement agencies in counteracting the illegal use of fireworks new forensic methods have to be developed. In the Netherlands, many incidents involve powerful flash bangers mainly due to irresponsible behavior and misuse for criminal activities. Obtaining tactical information for differentiation of these flash bangers is of high priority in forensic casework. A representative sample set of a certain type of flash bangers, confiscated by the Dutch police, has been collected in a time period of one year and initial characterization has been performed based on visual examination. The individual components of the flash bangers already allow for a high degree of differentiation. Ultimately, combining all visual characteristics of pyrotechnic charges, labels, fuses and caps resulted in the classification into 24 groups out of 30 seized sets of flash bangers. In addition to visual examination, this unique sample set offers a wide variety of research opportunities that could be further explored and that might prove essential in case scenarios where visual characteristics are more difficult to assess or are completely absent.

A Strontium- and Chlorine-Free Pyrotechnic Illuminant of High Color Purity.

The development of a red-light-emitting pyrotechnic illuminant has garnered interest from the pyrotechnics community owing to potential regulations by the United States Environmental Protection Agency (U.S. EPA) regarding the use of strontium and chlorinated organic materials. To address these environmental regulatory concerns, the development of lithium-based red-light-emitting pyrotechnic compositions of high purity and color quality is described. These formulations do not contain strontium or chlorinated organic materials. Rather, the disclosed formulations are based on a non-hygroscopic dilithium nitrogen-rich salt that serves as both oxidizer and red colorant. These formulations are likely to draw interest from the civilian fireworks and military pyrotechnics communities for further development as they both have a vested interest in the development of environmentally conscious formulations.

Pirotecnia: lesiones graves de mano asociadas a explosión de un tipo de dispositivo (megapetardo/superbomba) / Pyrotechnics: severe hand lesions associated to the explosion of a certain device (megafirecrackers/superbombs)

Resumen Introducción: el uso de fuegos artificiales y dispositivos de pirotecnia forma parte de celebraciones y espectáculos públicos en todo el mundo. En Uruguay, su uso se encuentra concentrado en los meses estivales en eventos públicos y privados. Hay normativas para su uso, la importación y venta está regulada. En el verano de 2014-2015 hubo cuatro niños con lesiones graves de mano producidas por explosivos. Todas en circunstancias similares, compartieron el mismo mecanismo lesional y vinculados a un único dispositivo. En el año 2016 hubo más niños con iguales injurias. Objetivo: comunicar una serie de niños con injurias provocadas por un tipo de explosivo de pirotecnia con un patrón diferente al conocido previamente. Resultados: n=6. Todos varones, cinco adolescentes. Los seis presentaron lesiones severas en manos con amputación de uno o varios dedos, determinando secuelas estéticas y funcionales. Discusión: se identifica los dispositivos con alto contenido en pólvora y el mal uso de los mismos como factores asociados a las lesiones graves de mano. Se realizó una campaña desde la Sociedad Uruguaya de Pediatría, el Departamento de Emergencia Pediátrica, el Ministerio de Salud y otras autoridades para abordar este problema. Se prohíbe la venta de ese dispositivo. Conclusiones: la utilización de dispositivos de pirotecnia con alto contenido de pólvora como el megapetardo o superbomba puede determinar lesiones graves de mano, mutilantes y secuelas permanentes. No se recomienda la manipulación de fuegos artificiales por parte de los niños. El cumplimiento de las normativas vigentes y el correcto uso de los mismos podrían contribuir a disminuir estas injurias.

Summary Introduction: the use of fireworks and pyrotechnic devices are ways of public entertainment and celebration around the world. In Uruguay, they are more frequently used during summer-time in public and private events. Usage, import and sales are regulated by law. In summer 2014-2015 four children presented severe hand injuries caused by blasts, all of which occurred under similar conditions, shared the same injury mechanism and were linked to a specific device. In 2016 there were more children with similar lesions. Objective: to report a series of children with hand lesions caused by a certain type of pyrotechnic device with a pattern that was different from the one previously known. Results: n=6. All of them males 5 adolescents. The 6 children studied presented severe lesions in hands with amputation of 1 or several fingers, which resulted in aesthetic and functional sequelae. Discussion: devices with a high dose of gunpowder and their incorrect use are identified as factors associated to severe lesions. The Uruguayan Society of Pediatrics, the Pediatrics Emergency Department and the Ministry of Health, among other authorities, conducted a campaign to address this issue. The sale of this device is prohibited. Conclusions: the use of pyrotechnic devices with a high dose of gunpowder such as mega firecrackers or superbombs can result in severe hand lesions, mutilation and permanent sequelae. The handling of fireworks by children is not recommended. Fulfillment of updated regulations and the correct use of fireworks might contribute to diminishing these injuries.

Study of Six Green Insensitive High Energetic Coordination Polymers Based on Alkali/Alkali-Earth Metals and 4,5-Bis(tetrazol-5-yl)-2 H-1,2,3-triazole.

Constructing insensitive high-performance energetic coordination polymers (ECPs) with alkali/alkali-earth metal ions and a nitrogen-rich organic backbone has been proved to be a feasible strategy in this work. Six diverse dimensional novel ECPs (compounds 1-6) were successfully synthesized from NaI , CsI , CaII , SrII , BaII ions and a nitrogen-rich triheterocyclic 4,5-bis(tetrazol-5-yl)-2 H-1,2,3-triazole (H3 BTT). All compounds show outstanding stability and low sensitivity, the thermal stability of these ECPs are significantly improved as the structural reinforcement increases from 1D to 3D, in which the decomposition temperature of 3D BaII based compound 6 is as high as 397 °C. Long-term storage experiments show that compounds 5 and 6 are stable enough at high temperature. Moreover, the six compounds hold considerable detonation performances, in which CaII based compound 5 possesses the detonation velocity of 9.12 km s-1 , along with the detonation pressure of 34.51 GPa, exceeding those of most energetic coordination polymers. Burn tests further certify that the six compounds can be versatile pyrotechnics.

Vibroacoustic Impact on the Architectonic Heritage When Using Replicas of 16th Century Weapons.

The recreation of historical battles next to old buildings, walls, churches, fortifications or historical facades belonging to the historical heritage of a city, has always been a source of controversy and discussion. In the absence of a clear legislation about how these buildings can be affected by the use of blunderbusses and pyrotechnics, it is necessary to carry out practical experiments to test the effect of these celebrations on these buildings. For this reason, this paper presents a set of practical experiments where the vibroacoustic effect of using weapons such as blunderbusses and harquebuses is analyzed. To gather these measurements, we have used several sound level meters and 3-axis accelerometers placed on the facade of an old building. The tests have been carried out at the Moors and Christians festival of Villajoyosa (Spain) which is internationally famous for this festival. In order to carry out the tests, six harquebusiers shot their firearms and the sensors placed along the facade of the building at different height collected the data. The results of these devices allow us to study the vibroacoustic impact on the facade depending on the height.

Safer Pyrotechnic Obscurants Based on Phosphorus(V) Nitride.

The potential of phosphorus(V) nitride, P3 N5 , as a replacement for red phosphorus, PR , in pyrotechnic obscurants has been theoretically and experimentally investigated. P3 N5 can be safely mixed with KNO3 and even KClO3 and KClO4 . The corresponding formulations are surprisingly insensitive to friction and only mildly impact-sensitive. P3 N5 /KNO3 pyrolants with ξ=20-80 wt % P3 N5 burn 200 times faster than the corresponding mixtures based on PR and generate a dense smoke. Hence obscurants based on P3 N5 /KNO3 have a figure of merit that by far exceeds that of current state-of-the-art PR -based obscurants. Furthermore, unlike PR , which slowly degrades in moist air to phosphoric acids and phosphine (PH3 ), P3 N5 is stable under these conditions and does not produce any acids or PH3 . P3 N5 is hence a safe, stable, and powerful replacement for PR for use in insensitive munitions.

Energetic Salts Based on Tetrazole N-Oxide.

Energetic materials (explosives, propellants, and pyrotechnics) are used extensively for both civilian and military applications and the development of such materials, particularly in the case of energetic salts, is subject to continuous research efforts all over the world. This Review concerns recent advances in the syntheses, properties, and potential applications of ionic salts based on tetrazole N-oxide. Most of these salts exhibit excellent characteristics and can be classified as a new family of highly energetic materials with increased density and performance, alongside decreased mechanical sensitivity. Additionally, novel tetrazole N-oxide salts are proposed based on a diverse array of functional groups and ions pairs, which may be promising candidates for new energetic materials.