ABSTRACT
A rapid and highly sensitive method for the quantification of 34 restricted dyes (including acid, basic, disperse, direct, and azo dyes) in solid textile raw material wastes was developed by employing ultrasonic extraction coupled with ultra-high performance liquid chromatography-tandem mass spectrometry(UHPLC-MS/MS). More specifically, the proposed method employed methanol as the extraction solvent, while the mobile phases consisted of acetonitrile and 10 mmol/L ammonium acetate + 0.05% ammonia. A good linearity was achieved over the concentration range of 0.01-200 ng/mL with correlation coefficients (R) between 0.991-0.999, limits of detection (LODs) of 0.25-40.0 µg/kg (S/N = 3) and limits of quantification (LOQs) of 0.84-133.4 µg/kg (S/N = 10). 34 dyes were recovered at three levels ranging from 84.5 to 106.9% with relative standard deviation (RSDs) ranging from 0.59% to 10.61%. Further, the method was applied for the accurate analysis of 32 counts of cotton yarn, waste cotton, and printed fabrics within 15 min. The dyestuffs accurately quantified by this rapid chromatographic procedure covered a wide range of carcinogenic and allergenic dyestuffs listed in the Oeko-Tex Standard 100 (version 02.2023) colourants. The ultrasound technique combined with the ultra-high performance liquid chromatography-tandem mass spectrometry method proposed in this work is thus suitable for the rapid screening, confirmation, and quantitative detection of industrial synthetic dyes within solid waste originating from textile raw materials.
Subject(s)
Coloring Agents , Tandem Mass Spectrometry , Chromatography, High Pressure Liquid/methods , Coloring Agents/analysis , Tandem Mass Spectrometry/methods , Solid Waste/analysis , Textiles/analysis , Solid Phase ExtractionABSTRACT
Este trabalho teve por objetivo a proposição de cenários para o equacionamento da disposição de resíduos sólidos gerados por áreas urbanas da região do Baixo Ribeira de Iguape, localizado no estado de São Paulo. Utilizou-se a análise multicritério, que requer a identificação de critérios que podem ser restrições e fatores. Como critérios de agregação optou-se pela Combinação Linear Ponderada e pela Média Ponderada Ordenada. Para cada um dos municípios calculou-se a área necessária para a disposição final de seus resíduos sólidos. Os resultados mostraram que a melhor área para o município de Cajati está localizada a aproximadamente 3,0km da sede do mesmo, para Jacupiranga a 2,7km e para Pariqüera-Açu a 2,4km. A metodologia mostrou-se adequada ao propósito em questão, levando-se em consideração 18 fatores e restrições influentes no processo de decisão.
This paper addresses the proposition of scenarios for the equation of the disposal of solid residues generated by urban areas of the region of the Baixo Ribeira de Iguape, located in the São Paulo State, Brazil. Multicriterion analysis requiring identification of criteria that can play restrictions and factors roles were used. Aggregation Criteria was represented by the Weighed Linear Combination and the Ordered Weighed Mean. For each one of the selected cities it was calculated the required area for the final disposal of its solid residues. The results had shown that the best area for the city of Cajati is located approximately 3,0 km of its headquarters, for Jacupiranga 2,7 km and for Pariqüera-Açu 2,4 km. The applied methodology revealed adequate to the objective of this research, taking into account 18 influential factors and restrictions in the decision process.
